全文获取类型
收费全文 | 582篇 |
免费 | 21篇 |
国内免费 | 15篇 |
专业分类
化学 | 319篇 |
晶体学 | 8篇 |
力学 | 28篇 |
数学 | 124篇 |
物理学 | 139篇 |
出版年
2023年 | 3篇 |
2022年 | 10篇 |
2021年 | 14篇 |
2020年 | 18篇 |
2019年 | 25篇 |
2018年 | 20篇 |
2017年 | 15篇 |
2016年 | 16篇 |
2015年 | 23篇 |
2014年 | 27篇 |
2013年 | 47篇 |
2012年 | 37篇 |
2011年 | 35篇 |
2010年 | 22篇 |
2009年 | 42篇 |
2008年 | 35篇 |
2007年 | 29篇 |
2006年 | 33篇 |
2005年 | 24篇 |
2004年 | 33篇 |
2003年 | 12篇 |
2002年 | 7篇 |
2001年 | 10篇 |
2000年 | 7篇 |
1999年 | 10篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1993年 | 3篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1972年 | 1篇 |
1967年 | 2篇 |
1939年 | 1篇 |
1935年 | 1篇 |
1934年 | 2篇 |
1933年 | 1篇 |
1931年 | 1篇 |
排序方式: 共有618条查询结果,搜索用时 15 毫秒
61.
Enthalpies (Δisom
H
(g)o), Gibbs free energies (Δisom
G
(g)o), and equilibrium constants (log K
isom) for the trans → cis isomerization of various 3,3′-, 4,4′-, and 5,5′- disubstituted 2,2′-diphenoquinones with a range of electron withdrawing
and releasing moieties (methyl, fluoro, chloro, bromo, trifluoromethyl, and amino) were calculated in the gas phase and in
the solvent phase (n-hexane, benzene, n-octanol, acetonitrile, and water). In the gas phase, the trans isomer of the parent and all substituted 2,2′-diphenoquinones is predicted to be more thermodynamically stable than the cis configuration, with log K
isom ranging from −2.8 to −7.0. For all compounds, increasing solvent polarity/proticity progressively favors shifting the cis/trans equilibrium towards greater contributions of the cis configuration and substantially increases the log K
isom by up to 5.1 units relative to the gas phase. In polar protic and polar aprotic solvents, the estimated log K
isom ranges as low as −0.4, indicating significant populations of the cis isomers should be present. The findings support the polar solvent phase mechanistic predictions for a cis configuration of 2,2′-diphenoquinones participating in the thermal transformation of trans-2,2′-diphenoquinones to oxepino[2,3-b]benzofurans. With limited exceptions for some amino derivatives, the cis-2,2′-diphenoquinone to oxepino[2,3-b]benzofuran isomerization is expected to be thermodynamically favorable for all substituents/phases
under consideration. The cis-2,2′-diphenoquinone to oxepino[2,3-b]benzofuran rearrangement is predicted to become less thermodynamically favored with
increasing solvent polarity/proticity. 相似文献
62.
Gümüşderelioğlu M Kaya FB Beşkardeş IG 《Journal of colloid and interface science》2011,358(2):444-453
In this study, the relationship between the cellular morphology and the material surface topography was investigated. Poly(ε-caprolactone) (PCL) membranes were prepared in a wide range of surface wettabilities by means of crystallinity-controlled solvent casting process. Membrane surfaces were characterized by atomic force microscope (AFM), scanning electron microscope (SEM), and static/dynamic water contact angle measurements. It was found that solvent evaporation and non-solvent (methanol) addition to the solvent (THF) are the most decisive parameters to change the surface topography. The non-solvent addition and the decrease in solvent evaporation temperature from room temperature to -20 °C caused increased polymeric chain mobility and crystallization time. Such changes in crystallization parameters led to the formation of micro/nano-sized features on the membrane. Cell culture studies indicated that in contrast to Madin Darby kidney (MDBK) epithelial cells, L929 mouse fibroblast preferred rough and porous surfaces. 相似文献
63.
Ercan Gürses 《Journal of the mechanics and physics of solids》2011,59(3):732-749
This paper presents a variational multi-scale constitutive model in the finite deformation regime capable of capturing the mechanical behavior of nanocrystalline (nc) fcc metals. The nc-material is modeled as a two-phase material consisting of a grain interior phase and a grain boundary effected zone (GBAZ). A rate-independent isotropic porous plasticity model is employed to describe the GBAZ, whereas a crystal-plasticity model which accounts for the transition from partial dislocation to full dislocation mediated plasticity is employed for the grain interior. The constitutive models of both phases are formulated in a small strain framework and extended to finite deformation by use of logarithmic and exponential mappings. Assuming the rule of mixtures, the overall behavior of a given grain is obtained via volume averaging. The scale transition from a single grain to a polycrystal is achieved by Taylor-type homogenization where a log-normal grain size distribution is assumed. It is shown that the proposed model is able to capture the inverse Hall-Petch effect, i.e., loss of strength with grain size refinement. Finally, the predictive capability of the model is validated against experimental results on nanocrystalline copper and nickel. 相似文献
64.
Numerical Algorithms - We show how to compute the optimal relative backward error for the numerical solution of the Dahlquist test problem by one-step methods. This is an example of a general... 相似文献
65.
66.
67.
SVL fluorescence spectra from principal bands in the S1 state of pyridine h5 and -d5 were measured. A large displacement of the normal coordinate origin of v6a and the Duschinskii rotation of v10a and v16a were established. 相似文献
68.
69.
70.