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61.
Gaëtan Compère Emilie Marchandise Jean-François Remacle 《Journal of computational physics》2008,227(3):1923-1942
An anisotropic adaptation process is applied to a three-dimensional incompressible two-phase flow solver. The solver uses a level set/finite element method on unstructured tetrahedral meshes. We show how the level set function can be used to build an anisotropic mesh with good properties. Some computations with a strong transient character and large densities ratios (1/1000) are presented. We show that the efficiency of the computations can be deeply enhanced by mesh adaptations. 相似文献
62.
63.
Massold E 《Journal of chromatography. A》2007,1154(1-2):342-352
The identification of organic compounds by GC/MS is useful in various areas such as fuel, indoor and outdoor air and flavour and fragrance applications. Multi-compound mixtures often contain isomeric compounds which have similar mass spectra and sometimes cannot be unambiguously identified by library search alone. Retention indices can help with confirmation of identification if they are reproducible. Using perdeuterated n-alkanes as a reference series for calculation of retention indices in GC/MS has a clear benefit because of the distinctive ion trace of m/z 34. Thermal desorption is useful for analysis of volatile organic compounds (VOCs) in air after sampling on appropriate sorbent cartridges. Comparison of indices between three systems, consisting of a thermal desorption unit, a gas chromatograph and a mass spectrometer, showed good agreement for compounds with well-defined peaks, whereas retention times varied. 相似文献
64.
Emilie Dufresne 《Advances in Mathematics》2009,221(6):1979-1989
A separating algebra is, roughly speaking, a subalgebra of the ring of invariants whose elements distinguish between any two orbits that can be distinguished using invariants. In this paper, we introduce a geometric notion of separating algebra. This allows us to prove that only groups generated by reflections may have polynomial separating algebras, and only groups generated by bireflections may have complete intersection separating algebras. 相似文献
65.
66.
Laux S Lureau F Radier C Chalus O Caradec F Casagrande O Pourtal E Simon-Boisson C Soyer F Lebarny P 《Optics letters》2012,37(11):1913-1915
Transverse parasitic lasing is well known for limiting the signal gain and the pulse energy that can be extracted from Ti:sapphire petawatt amplifiers. We have developed a technique for suppressing these parasitic lasing modes based on perfect refractive index-matching liquid doped with a broad-bandwidth absorber to suppress the transverse lasing while ensuring proper heat removal from the Ti:sapphire crystal. The 800 nm laser output with a bandwidth of 41 nm (FWHM) and peak energy of 22.7 J at a repetition rate of 1 Hz is demonstrated. 相似文献
67.
A Echalier E Cot A Camasses E Hodimont F Hoh P Jay F Sheinerman L Krasinska D Fisher 《Chemistry & biology》2012,19(8):1028-1040
Highlights? Demonstration that Cdk2 is rate-limiting for DNA replication due to insufficient Cdk1 activity ? A simple bioinformatic approach to design inhibitor resistant mutations in kinases ? Demonstration of distinct binding modes and selectivity of Cdk inhibitors ? Identification of kinetic and structural mechanisms of inhibitor resistance 相似文献
68.
Emilie David-Guillou 《Journal of Functional Analysis》2006,238(2):734-750
We consider a family of real NA groups with rank two, and we prove that these groups have sub-Laplacians with differentiable Lp functional calculus for all p?1. 相似文献
69.
We report structure-activity trends among helix-forming beta-amino acid oligomers that are intended to mimic alpha-helical host-defense peptides. Parallel synthesis of two small, focused beta-peptide libraries allowed us to identify relatively short (11-residue) beta-peptides that display antimicrobial activity. These beta-peptides exhibit selectivity for bacteria relative to human red blood cells. A large hydrophobic helical surface is necessary for antimicrobial activity. Longer analogues (16 residues) of the most active library members were prepared and evaluated. Some of these longer beta-peptides showed very good antimicrobial activity, but none was more active than a previously reported beta-peptide [Porter, E. A.; Wang, X.; Lee, H.-S.; Weisblum, B.; Gellman, S. H. Nature 2000, 404, 565]. The extensive literature on alpha-helical host-defense peptides and related alpha-peptides indicates that such molecules are seldom active at concentrations below 1 microg/mL, and our results suggest that amphiphilic helical beta-peptides are subject to a comparable limit. 相似文献
70.
Jonathan M. Curtis Peter J. Derrick Andr Schnell Emilie Constantin Richard T. Gallagher John R. Chapman 《Journal of mass spectrometry : JMS》1992,27(11):1176-1180
Electrospray ionization on Ln(tfc)3 complexes (Ln = Eu, Yb; tfc = D -3-trifluoroacetylcamphorate) was performed with samples dissolved in methanol–water containing acetic acid. The spectra were obtained with a four-sector mass spectrometer. The mass spectra exhibit ions containing tfc ligand in addition to ions with acetato ligand. Electro-spray and tandem mass spectra are presented. 相似文献