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61.
Crystals ofN,N-(3,3-dipropylamine)bis(3-methoxysalicylideneiminato) oxovanadium(IV) dihydrate are monoclinic, space groupP21/n (No. 14) with four molecules in the unit cell of dimensionsa=8.667(4),b=20.617(4),c=12.744(3) Å,=91.48(3)°. The structure was solved by the heavy-atom method and refined by block diagonal least-squares calculations with anisotropic thermal parameters for nonhydrogen atoms.R=0.038 for 1457 reflections withI>3(I). This structure is the first reported for an oxovanadium(IV) complex involving complexation of a pentacoordinate Schiff-base ligand. The coordination polyhedron is based on a distorted octahedron. Three nitrogen and one oxygen atom from the ligand form an equatorial plane around vanadium with V-N(1) 2.096(4), V-N(2) 2.180(4), V-N(3) 2.088(4), V-O(2) 1.961(3) Å, and octahedral coordination is completed by the vanadyl oxygen [V-O(1) 1.617(3) Å] and the remaining ligand oxygen [V-O(3) 2,098(3) Å]. The relatively long V-O(1) distance correlates well with the low value ofv(V=O) of 919 cm–1. The molecules of the complex are linked by water molecules of crystallization to form infinite hydrogen-bonded chains parallel toa. 相似文献
62.
Dr. Elmer C. Rivera Joseph W. Taylor Dr. Rodney L. Summerscales Dr. Hyun J. Kwon 《ChemistryOpen》2021,10(8):842-847
Phenolic compounds such as vanillic and p-coumaric acids are pollutants of major concern in the agro-industrial processing, thereby their effective detection in the industrial environment is essential to reduce exposure. Herein, we present the quenching effect of these compounds on the electrochemiluminescence (ECL) of the Ru(bpy)32+/TPrA (TPrA=tri-n-propylamine) system at a disposable screen-printed carbon electrode. Transient ECL profiles are obtained from multiple video frames following 1.2 V application by a smartphone-based ECL sensor. A wide range of detection was achieved using the sensor with limit of detection of 0.26 μM and 0.68 μM for vanillic and p-coumaric acids, respectively. The estimated quenching constants determined that the quenching efficiency of vanillic acid is at least two-fold that of p-coumaric acid under the current detection conditions. The present ECL quenching approach provided an effective method to detect phenolic compounds using a low-cost, portable smartphone-based ECL sensor. 相似文献
63.
Guevara EA de Lourdes Barriviera M Hassón-Voloch A Louro SR 《Photochemistry and photobiology》2007,83(4):914-919
This work reports the results of ultraviolet irradiation on the interaction of the phototoxic antipsychotic drug chlorpromazine (CPZ) with the sodium pump Na+, K+-ATPase. The study was performed by monitoring the fluorescence modifications of CPZ itself and of the specific probe anthroylouabain (AO). CPZ association with Na+, K+-ATPase was found to modify the kinetics of CPZ-photodegradation. It was demonstrated that UV irradiation produces a stable fluorescent photoproduct of CPZ covalently bound to Na+, K+-ATPase. The fluorescent probe AO, which specifically binds to the extracellular ouabain site of the pump, was used to localize the CPZ binding site. UV-irradiation of AO-labeled Na+, K+-ATPase treated with CPZ at concentration about 20 microM produced dose-dependent modifications of the AO fluorescence, e.g. increased quantum yield and blue shift. The results demonstrated that CPZ binds near the ouabain site. The photo-induced reaction of CPZ with AO-labeled Na+, K+-ATPase protected the ouabain site from the aqueous environment. It was also found that UV irradiation of CPZ-treated enzyme obstructs the binding of AO, which suggested occlusion of the ouabain site. This effect can be evaluated for a potential use of CPZ in photochemotherapy. 相似文献
64.
Mark A. R. de Geus Elmer Maurits Alexi J. C. Sarris Thomas Hansen Max S. Kloet Kiki Kamphorst Dr. Wolter ten Hoeve Dr. Marc S. Robillard Dr. Andrea Pannwitz Dr. Sylvestre A. Bonnet Dr. Jeroen D. C. Codée Dr. Dmitri V. Filippov Prof. Herman S. Overkleeft Dr. Sander I. van Kasteren 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(44):9900-9904
The inverse electron demand Diels–Alder pyridazine elimination reaction between tetrazines and allylic substituted trans-cyclooctenes (TCOs) is a key player in bioorthogonal bond cleavage reactions. Determining the rate of elimination of alkylamine substrates has so far proven difficult. Here, we report a fluorogenic tool consisting of a TCO-linked EDANS fluorophore and a DABCYL quencher for accurate determination of both the click and release rate constants for any tetrazine at physiologically relevant concentrations. 相似文献
65.
John Malito Elmer C. Alyea 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):95-99
Abstract Electronic and steric effects in SeP(Ar), compounds are discussed with the assistance of 1J(77Se-31P) correlations with d(P—Se) values and the pKa of the arylphosphines. 相似文献
66.
67.
F. W. Traphagen W. D. Treadwell A. Fischer Hollard Bertiaux B. Woiciechowski Elmer List A. Classen A. Westerkamp Q. Sestini R. C. Benner W. H. Ross J. Köster R. Belasio H. Golblum Helene Gunther B. Pásztor J. Frazer R. Kremann E. P. Schoch D. J. Brown Franz Fischer E. Stecher F. C. Frary J. M. Knote W. R. Work Warmbrunn Quilitz & Co. O. Brunck F. A. Gooch W. L. Burdick P. Baumann A. Beyer und J. H. Hildebrand 《Fresenius' Journal of Analytical Chemistry》1913,52(3-4):201-212
Ohne Zusammenfassung 相似文献
68.
69.
Cefixime (H2cefixi) reacts with transition metal(II) ions to give [M(cefixi)(H2O)2] complexes (M = Mn, Co, Ni and Cd) and [Fe(cefixi)Cl(H2O)], which were characterized by physicochemical and spectroscopic methods, and an octahedral geometry is suggested for their
structure. The complexes are polymers with high temperature decomposition points and are insoluble in water and common organic
solvents. The complexes have been screened for antibacterial activity against several bacteria, and the results are compared
with the activity of cefixime. 相似文献
70.