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41.
[structure: see text] Apoptolidin (1) exhibits potent and highly selective apoptosis inducing activity against sensitive cancer cell lines and is hypothesized to act by inhibition of mitochondrial F(0)F(1)-ATP synthase. A series of apoptolidin derivatives, including a new intermolecular Diels-Alder adduct, were analyzed for antiproliferative activity in E1A-transformed rat fibroblasts. Potent F(0)F(1)-ATPase inhibition was not a sufficient determinant of antiproliferative activity for several analogues, suggesting the existence of a secondary biological target or more complex mode of action for apoptolidin. 相似文献
42.
A particle method has been used to simulate the vorticity transport in a two-dimensional flow of an incompressible inviscid fluid. In this method, not only the location and the circulation of the particle are used but also the moments of the internal vorticity. The transport equation for these moments has been derived from the vorticity transport equation. The method has been compared to the usual particle method as well as to Teng's elliptic vortex model. The test case is that of the evolution of two circular patches of vorticity already used by Teng. To cite this article: A. Beaudoin et al., C. R. Mecanique 330 (2002) 51–56 相似文献
43.
Christel Roux Wladimir Gorecki Jean-Yves Sanchez Elie Belorizky 《Macromolecular Symposia》1997,114(1):211-216
High molecular weight polymers have been prepared by ring-opening polymerization of propylene oxide PO using a Vandenberg initiator. Polymer electrolytes based on this polymer and an imide salt LiTFSI have been investigated. We present the results concerning the synthesis of the polymer and the glass transition temperatures evolution of the complexes with respect to salt composition. Diffusion constants of 19F and 7Li nuclei are determined by NMR techniques and a value of the cationic transport number t+ = 0.1 is obtained. 相似文献
44.
45.
Fabien?Closa Elie?Raph?el Alexei D.?ChepelianskiiEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2014,87(8):190
An ultra-strong photovoltaic effect has recently been reported for electrons trapped on a liquid helium surface under a microwave excitation tuned at intersubband resonance [D. Konstantinov, A.D. Chepelianskii, K. Kono, J. Phys. Soc. Jpn 81, 093601 (2012)]. In this article, we analyze theoretically the redistribution of the electron density induced by an overheating of the surface electrons under irradiation, and obtain quantitative predictions for the photocurrent dependence on the effective electron temperature and confinement voltages. We show that the photo-current can change sign as a function of the parameters of the electrostatic confinement potential on the surface, while the photocurrent measurements reported so far have been performed only at a fixed confinement potential. The experimental observation of this sign reversal could provide a reliable estimation of the electron effective temperature in this new out of equilibrium state. Finally, we have also considered the effect of the temperature on the outcome of capacitive transport measurement techniques. These investigations led us to develop, numerical and analytical methods for solving the Poisson-Boltzmann equation in the limit of very low temperatures which could be useful for other systems. 相似文献
46.
In a reference frame rigidly bound to the complex, we consider two Hamiltonians possibly at the origin of the very fast electronic relaxation of the paramagnetic lanthanide Ln(3+) ions (Ln = Ce to Nd, Tb to Yb), namely the mean (static) ligand-field Hamiltonian and the transient ligand-field Hamiltonian. In the laboratory frame, the bombardment of the complex by solvent molecules causes its Brownian rotation and its vibration-distorsion dynamics governing the fluctuations of the static and transient terms, respectively. These fluctuations are at the origin of electronic relaxation. The electronic relaxation of a Ln(3+) ion is defined by the decays of the time correlation functions (TCFs) of the longitudinal and transverse components of the total angular momentum J of its ground multiplet. The Brownian rotation of the complex and its vibration-distorsion dynamics are simulated by random walks, which enable us to compute the TCFs from first principles. It is shown that the electronic relaxation is governed mainly by the magnitude of the transient ligand-field, and not by its particular expression. The range of expected values of this ligand-field together with the lower limit of relaxation time enforced by the values of the vibration-distortion correlation time in liquids give rise to effective electronic relaxation times which are in satisfactory overall agreement with the experimental data. In particular, these considerations explain why the electronic relaxation times vary little with the coordinating ligand and are practically independent of the external field magnitude. 相似文献
47.
A sensitive gas-liquid chromatographic technique for the quantitative analysis of SCH-12679 (d-7,8-dimethoxy-3-methyl-phenyl-2,3,4,5-tetrahydro-1H-3-benzazepine acid maleate) and its major metabolites in plasma of aggressive mental retardates receiving therapeutic doses of the medicament has been developed. The lower limits of detection are 20 ng/ml for SCH-12679, 0.5 ng/ml for 3-desmethyl SCH-12679 and 0.4 ng/ml for 7-desmethyl plus 8-desmethyl SCH-12679. SCH-12679 is estimated with a flame ionization detector. Its metabolites are quantitated using an electron-capture detector after conversion of the compounds to their heptafluorobutyryl derivatives by reaction with the appropriate anhydride. Data on plasma levels of unchanged SCH-12679, 3-desmethyl SCH-12679 and a combination of 7-desmethyl and 8-desmethyl SCH-12679 in fifteen patients treated with the medicament are presented. 相似文献
48.
The aim of this Note is to give a convergence result for a variant of the eXtended Finite Element Method (XFEM) on cracked domains using a cut-off function to localize the singular enrichment area. The difficulty is caused by the discontinuity of the displacement field across the crack, but we prove that a quasi-optimal convergence rate holds in spite of the presence of elements cut by the crack. The global linear convergence rate is obtained by using an enriched linear finite element method. To cite this article: E. Chahine et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
49.
Hervé K. Tchakouté Elie Kamseu Charles Banenzoué Claus H. Rüscher Fernanda Andreola Claudia C. L. Tchamo Cristina Leonelli 《Journal of Sol-Gel Science and Technology》2018,86(2):305-315
The main target of this work is to investigate the influence of ?-Al2O3 on the properties of metakaolin-based geopolymer cements. The kaolin used as starting material for producing geopolymer cements contains approximately 28 and 64% of gibbsite and kaolinite, respectively. This kaolin was transformed to metakaolins by calcination at 500, 550, 600, 650, and 700?°C for 1?h. Gibbsite contained in kaolin was transformed to γ-Al2O3 during the calcination process. The hardener was obtained by mixing commercial sodium silicate and sodium hydroxide solution (10?M) with a mass ratio sodium silicate/sodium hydroxide equal to 1.6:1. Geopolymer cements, GMK-500, GMK-550, GMK-600, GMK-650, and GMK-700, were obtained using the prepared hardener with a mass ratio hardener/metakaolin equal to 0.87:1. It could be seen that the specific surface area of metakaolins decreases with increasing the calcination temperature of kaolin owing to the formation of the particles of γ-Al2O3. The compressive strengths 18.21/29.14/36.61/36.51 increase in the course GMK-550/GMK-600/GMK-650/GMK-700. The X-ray patterns and micrograph images of geopolymer cements, GMK-600, GMK-650, and GMK-700, indicate the presence of γ-Al2O3 in their structure. It was typically found that γ-Al2O3 remains largely unaffected during the geopolymerisation, and therefore could act as an inert filler and reinforce the structure of geopolymer cements. 相似文献
50.
Acayanka Elie Tarkwa Jean-Baptiste Laminsi Samuel 《Plasma Chemistry and Plasma Processing》2019,39(1):75-87
Plasma Chemistry and Plasma Processing - This work presents the treatment of an organic waste solution using gliding arc plasma in moist air, which is an excellent source of oxidizing species.... 相似文献