Vortices with fractional flux in two-gap superconductors and in extended faddeev model

We discuss linear topological defects allowed in two-gap superconductors and equivalent extended Faddeev model. We show that, in these systems, there exist vortices which carry an arbitrary fraction of magnetic flux quantum. Besides that, we discuss topological defects which do not carry magnetic flux and describe features of ordinary one-magnetic-flux-quantum vortices in the two-gap system. The results could be relevant for the newly discovered two-band superconductor MgB2.     

Pion scattering on medium-weight nuclei and distortion effects in double charge exchange reactions

An eikonal version of the DWIA is used to compute absorption and dispersion effects on the cross section for double charge exchange to its double analogue. Lacking information on the π?⁵¹V optical potential, recent data on π?⁴⁰ Ca elastic scattering have been analyzed in the Glauber approximation and the extracted elastic phase function has been scaled up to correspond to ⁵¹V. The result is used in a computation of the DWIA amplitude. Large reduction factors are obtained in agreement with experimental upper bounds. Discrepancies with previous estimates are discussed.     

Methods of Synthesis and Antiviral Activity of New 4-Alkyl-3-Nitro-1,4-Dihydroazolo[5,1-c][1,2,4]Triazin-4-ols

Chemistry of Heterocyclic Compounds - An azo coupling reaction of α-nitro ketones with 5-diazoazoles was used to obtain 4-alkyl-3-nitro-1,4-dihydroazolo[5,1-с][1,2,4]triazines, which...     

Kinetic measurements of hydrocarbon conversion reactions on model metal surfaces

Examples from recent studies in our laboratory are presented to illustrate the main tools available to surface scientists for the determination of the kinetics of surface reactions. Emphasis is given here to hydrocarbon conversions and studies that rely on the use of model systems, typically single crystals and controlled (ultrahigh vacuum) environments. A detailed discussion is provided on the use of temperature-programmed desorption for the determination of activation energies as well as for product identification and yield estimations. Isothermal kinetic measurements are addressed next by focusing on studies under vacuum using molecular beams and surface-sensitive spectroscopies. That is followed by a review of the usefulness of high-pressure cells and other reactor designs for the emulation of realistic catalytic conditions. Finally, an analysis of the power of isotope labeling and chemical substitutions in mechanistic research on surface reactions is presented.     

Recent Advances in the Synthesis and Biomedical Applications of Heterocyclic NO-Donors

Nitric oxide (NO) is a key signaling molecule that acts in various physiological processes such as cellular metabolism, vasodilation and transmission of nerve impulses. A wide number of vascular diseases as well as various immune and neurodegenerative disorders were found to be directly associated with a disruption of NO production in living organisms. These issues justify a constant search of novel NO-donors with improved pharmacokinetic profiles and prolonged action. In a series of known structural classes capable of NO release, heterocyclic NO-donors are of special importance due to their increased hydrolytic stability and low toxicity. It is no wonder that synthetic and biochemical investigations of heterocyclic NO-donors have emerged significantly in recent years. In this review, we summarized recent advances in the synthesis, reactivity and biomedical applications of promising heterocyclic NO-donors (furoxans, sydnone imines, pyridazine dioxides, azasydnones). The synthetic potential of each heterocyclic system along with biochemical mechanisms of action are emphasized.     

Push–Pull Derivatives Based on 2,4′-Biphenylene Linker with Quinoxaline, [1,2,5]Oxadiazolo[3,4-B]Pyrazine and [1,2,5]Thiadiazolo[3,4-B]Pyrazine Electron Withdrawing Parts

A series of novel V-shaped quinoxaline, [1,2,5]oxadiazolo[3,4-b]pyrazine and [1,2,5]thiadiazolo[3,4-b]pyrazine push–pull derivatives with 2,4′-biphenylene linker were designed and their electrochemical, photophysical and nonlinear optical properties were investigated. [1,2,5]Oxadiazolo[3,4-b]pyrazine is the stronger electron-withdrawing fragment as shown by electrochemical, and photophysical data. All compounds are emissive in a solid-state (from the cyan to red region of the spectrum) and quinoxaline derivatives are emissions in DCM solution. It has been found that quinoxaline derivatives demonstrate important solvatochromism and extra-large Stokes shifts, characteristic of twisted intramolecular charge transfer excited state as well as aggregation induced emission. The experimental conclusions have been justified by theoretical (TD-)DFT calculations.     

Synthesis of allobetulin-based asialoglycoprotein receptor-targeted glycoconjugates

1. Download : Download high-res image (65KB)
2. Download : Download full-size image

     

Large-angle pD scattering, the form factor and the NN content of the deuteron

Single scattering and n-exchange are shown to account for all large-q² pD data (k_L 1.5 GeV/c) our to q² 8.5 (GeV/c)². From the extracted body-form factor we predict the deuteron charge form factor which agrees with the recent SLAC data. The agreement invalidates previous estimates of the NN^* content of the neuteron.     

Gasification of metal-containing coals and carbons via their reaction with carbon dioxide

1. Download high-res image (104KB)
2. Download full-size image

     

Design and synthesis of pyrazolo[3,4-d]pyridazine 5,6-dioxides as novel NO-donors

1. Download : Download high-res image (187KB)
2. Download : Download full-size image