Versuche zur Gewinnung einiger neuer Azofarbstoffe

Ohne Zusammenfassung     

Optimizing over the split closure

The polyhedron defined by all the split cuts obtainable directly (i.e. without iterated cut generation) from the LP-relaxation P of a mixed integer program (MIP) is termed the (elementary, or rank 1) split closure of P. This paper deals with the problem of optimizing over the elementary split closure. This is accomplished by repeatedly solving the following separation problem: given a fractional point, say x, find a rank-1 split cut violated by x or show that none exists. Following Caprara and Letchford [17], we formulate this separation problem as a nonlinear mixed integer program that can be treated as a parametric mixed integer linear program (PMILP) with a single parameter in the objective function and the right hand side. We develop an algorithmic framework to deal with the resulting PMILP by creating and maintaining a dynamically updated grid of parameter values, and use the corresponding mixed integer programs to generate rank 1 split cuts. Our approach was implemented in the COIN-OR framework using CPLEX 9.0 as a general purpose MIP solver. We report our computational results on well-known benchmark instances from MIPLIB 3.0 and several classes of structured integer and mixed integer problems. Our computational results show that rank-1 split cuts close more than 98% of the duality gap on 15 out of 41 mixed integer instances from MIPLIB 3.0. More than 75% of the duality gap can be closed on an additional 10 instances. The average gap closed over all 41 instances is 72.78%. In the pure integer case, rank-1 split cuts close more than 75% of the duality gap on 13 out of 24 instances from MIPLIB 3.0. On average, rank 1 split cuts close about 72% of the duality gap on these 24 instances. We also report results on several classes of structured problems: capacitated versions of warehouse location, single-source facility location, p-median, fixed charge network flow, multi-commodity network design with splittable and unsplittable flows, and lot sizing. The fraction of the integrality gap closed varies for these problem classes between 100 and 67%. We also gathered statistics on the average coefficient size (absolute value) of the disjunctions generated. They turn out to be surprisingly small. Research was supported by the National Science Foundation through grant #DMI-0352885 and by the Office of Naval Research through contract N00014-03-1-0133.     

Mathematical modelling of selected characterisation procedures for oil fractions

Models of two important characterisation procedures for oil and oil fractions, ASTM D86 (ASTM = American Society for Testing of Materials) and EFV (Equilibrium Flash Vaporization), were presented. The purpose was to provide a basis for the construction of substitute mixtures of real components used in modelling and simulation of chemical engineering processes instead of original complex mixtures. It was shown how to deal with a possible problem of higher index of differential-algebraic model of the ASTM D86. A number of examples proved the adequacy of the presented models. Presented at the 34th International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 21–25 May 2007.     

Computation of transition to turbulence in the compression stage of a reciprocating engine

The transition to turbulent flow in the compression stage of a reciprocating engine is studied by obtaining the finite-difference numerical solutions to the governing Navier-Stokes equations without using explicit turbulence models. A computational method is developed under the assumption that the flow is in a low-subsonic regime with strong compression. The numerical method is a simple extension of the well known MAC method. Computations were performed for three different chamber geometries at the engine speed of 1400 rpm. The results of the computations clearly demonstrate the transient process in which large tumbling vortices break down into smaller ones near the end of the compression process. The transition process is also caught experimentally by using Mach-Zehnder interferometry.     

Brazilian <Emphasis Type="Italic">Dioscoreaceas</Emphasis> starches

Determination of the characteristics of native starches is crucial in order to select their best application in various industrial fields. Thus, two different types of non-traditional native starches from the Dioscoreaceas species (Dioscorea sp. and Dioscorea piperifolia Humb. var. Wild) were studied regarding their thermal, structural and rheological properties. The results were contrasted with traditional commercial starch sources (potato, cassava and corn). From the thermogravimetric results (TG/DTG), D. piperifolia starch obtained the highest thermal stability of the samples, except for potato starch. Furthermore, using differential scanning calorimetry and viscoamylograph profiles (RVA), it was found that the Dioscoreaceas starches presented a higher onset (T _o) temperature and susceptibility to retrogradation. They also showed lower values in relation to relative crystallinity, which was calculated from their X-ray patterns and tendency to white (L*) colour. The shapes of the Discoreaceas starch granules were determined using electron microscopy; it was found that as the potato starch the Dioscoreaceas starches showed a wide range of particle size.     

Experimente mit thermisch getriebenen Gas-Flüssigkeits-Schwingungen

Zusammenfassung Bei thermisch angeregten Gas-Flüssigkeits-Schwingungen wurden die angefachten Druckschwingungen für verschiedene Temperaturverhältnisse direkt gemessen. Dies erlaubte die Ermittlung der Anfachung und einen Vergleich mit theoretischen Werten.Mit den Druckamplituden im stationären Zustand wurde der Charakter der nichtlinearen Dämpfung bestimmt.

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Summary Direct measurements of the amplified pressure oscillations in a thermally driven gas-liquid system have been made for several temperature ratios. The rates of amplification have been evaluated and compared with theoretical values.From the measured steady-state pressure amplitudes it has also been possible to determine the character of the nonlinear damping.