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Beatriz Veleirinho Manuel F. Rei J. A. Lopes‐DA‐Silva 《Journal of Polymer Science.Polymer Physics》2008,46(5):460-471
This study describes the preparation and characterization of nanofibrous mats obtained by electrospinning poly(ethylene terephthalate) (PET) solutions in trifluoroacetic acid/dichloromethane (TFA/DCM). Special attention was paid to the effect of polymer concentration and solvent properties on the morphology, structure, and mechanical and thermal properties of the electrospun nonwovens. The results show that the spinnable concentration of PET solution in TFA/DCM solvents is above 10 wt %. Mats have nanofibrous morphology with fibers having an average diameter in the range of 200–700 nm (depending on polymer concentration and solvent composition) and an interconnected pore structure. Higher solution concentration favors the formation of uniform fibers without beads and with higher diameter. Morphology and fiber assembly changed with the solvent properties. Solvent mixtures rich in TFA, i.e., those with higher dielectric constant and lower surface tension, originated fibers with small diameter. However, due to the lower volatility, those solvent mixtures also produced more branched and crosslinking fibers, with less morphologic uniformity. Mechanical properties (Young's modulus, ultimate strength, and elongation at break) and thermal properties (glass transition, crystallization, and melting) have been studied for the PET electrospun nanomats and compared with those of the original polymer. Solvent effect on fiber crystallinity was not significant, but a complex effect was observed on the mechanical properties of the electrospun mats, as a consequence of the different structural organization of the fibers within the mat network. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 460–471, 2008 相似文献
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This paper is a continuation of the authors recent work [Beir?o da Veiga, H.and Yang, J., On mixed pressure-velocity regularity criteria to the Navier-Stokes equations in Lorentz spaces, Chin. Ann. Math., 42(1), 2021, 1–16], in which mixed pressure-velocity criteria in Lorentz spaces for Leray-Hopf weak solutions of the three-dimensional NavierStokes equations, in the whole space R~3 and in the periodic torus T~3, are established. The purpose of the present work is to extend the result of mentio... 相似文献
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用十二胺-N乙酸-N亚甲基膦酸(DAPA)改性氧化锆制备了一种新的锆基质色谱固定相(DAPAZ),研究发现,DAPA在氧化锆表面有两种结合方式:红外光谱中1611cm^-1处的特征吸收表明羧基主要与胺基形成偶极离子,以羧酸根离子形式存在,大部分的DAPA分子通过膦酸基团与氧化锆结合;而与钼酸的显色反应则表明有少量DAPA以羧居与氧化锆结合,另外,对固定相的屏蔽效应、碱性条件(pH9.5)下的稳定性等色谱性能的研究也证实这两种吸附方式同时存在,但以膦酸基结合为主。 相似文献
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COMPONENT ALLEE EFFECTS AND STAGE‐SPECIFIC PREDATION: A BRIEF INSIGHT INTO CONSERVATION AND BIOLOGICAL CONTROL ISSUES 下载免费PDF全文
In this paper, we propose a two‐stage structured population model subject to component Allee effects in fecundity and maturation, and with two disturbances (predation only and harvest and predation) acting on both stages. It is shown that this combination leads to a demographic Allee effect—a characteristic that could be exploited in pest biological control, but on the other hand, it represents a bane in conservation biology. The analysis is performed for disturbances with functional responses type 2 and 3, and the models show that they yield qualitatively similar results. This characteristic is discussed from the species conservation and biological control point of view, together with possible extensions of this work. 相似文献
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针对水中运动声源定位问题,建立了一种基于声场干涉结构谱向量相似度匹配的目标运动参数估计方法。结合声场干涉结构水平纵向相关特性,利用目标辐射噪声LOFAR谱图中不同频率的谱值序列,基于两方位-两距离目标运动要素计算方法获取的目标距离解向量,构造声场干涉结构谱向量相似度匹配代价因子,实现目标运动参数估计。仿真数据与试验数据验证结果表明:在绘制的目标运动要素解算结果可视化分布图中可清晰呈现出目标初距、航向和速度结果。该算法实现过程简单、解算效率高,对目标方位误差有较好的鲁棒性。 相似文献