Groups Admitting an Automorphism of Prime Order with Finite Centralizer

We consider a group G with an automorphism of finite, usually prime, order. If G has finite Hirsch number, and also if G satisfies various stronger rank restrictions, we study the consequences and equivalent hypotheses of having only finitely many fixed-points. In particular we prove that if a group G with finite Hirsch number ${\mathfrak{h}}$ admits an automorphism ${\varphi}$ of prime order p such that ${\vert C_{G}(\varphi) \vert = n < \infty,}$ then G has a subgroup of finite index bounded in terms of p, n and ${\mathfrak{h}}$ that is nilpotent of p-bounded class.     

Triplet harvesting in poly(9‐vinylcarbazole) and poly(9‐(2,3‐epoxypropyl)carbazole) doped with CdSe/ZnS quantum dots encapsulated with 16‐(N‐carbazolyl) hexadecanoic acid ligands

Semiconductor quantum dots (QDs) can be used as alternative for transition metal complexes to harvest the nonemissive triplet excitons in organic light‐emitting diodes (OLEDs). In search for a QD‐based OLED material generating blue emission, poly(9‐vinylcarbazole) (PVK) and poly(9‐(2,3‐epoxypropyl) carbazole) (PEPK) are chosen as host for blue‐emitting CdSe/ZnS core/shell QDs. The QDs are encapsulated with 16‐(N‐carbazolyl) hexadecanoic acid (C16), a ligand terminated by a carbazole moiety. As alternative for PVK, PEPK, where the lower molecular weight and less extensive excimer formation could promise a better film formation and more extensive exciton hopping, is explored. The efficiencies of singlet ( ) and triplet ( ) energy transfer to the C16 capped QDs are estimated by combining stationary photoluminescence spectra and fluorescence decays of pristine polymer films with those of polymer films doped with the QDs. At a loading of 30 wt % of the QDs, increases from 12 ± 1% in PVK to 41 ± 2% in PEPK while increases from 37 ± 22% in PVK to 72 ± 48% in PEPK. The investigation of the film morphology by atomic force microscopy confirms that the main factor limiting the triplet transfer efficiency in the PVK matrix is the clustering of the C16 capped QDs. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 539–551     

Response functions of 58Ni, 116Sn AND 208Pb to the excitation of intermediate-energy α-particles

Inelastic scattering of 340 MeV and 480 MeV α-particles has been measured on ⁵⁸Ni, ¹¹⁶Sn and ²⁰⁸Pb up to 60 MeV excitation energy. Consistent background subtraction and multipole analysis has provided the repartition of multipole strength for all three nuclei. The so-obtained response functions show the already known low-energy giant resonances in a detailed way, as well as new giant resonances at high energy.     

Measurement of np and pp asymmetry with an accelerated polarized deuteron beam from 725 to 1000 MeV per nucleon

The accelerated polarized deuteron beam of Saturn II was used to measure the analyzing power for np elastic scattering at five energies. The left-right asymmetries ε = (L + R)/(L + R) for np and for pp elastic scattering were measured simultaneously by CH₂? carbon subtraction using one of the beam-line polarimeters. The analyzing power A_00n0(np) is given by the ratio ε_np^d/ε_pp^d multiplied by the known analyzing power for pp elastic scattering. Experimental evidence is consistent with the underlying assumption that in the kinetmatic region of the experiment the ratio of the np to pp analyzing powers for scattering of quasifree nucleons in deuterons is the same as for scattering of free neutrons and protons, respectively.     

Establishing dual electrogenerated chemiluminescence and multicolor electrochromism in functional ionic transition-metal complexes

A combination of electrochromism and electroluminescence in functional materials could lead to single-layer dual electrochromic/electroluminescent (EC/EL) display devices, capable of simultaneous operation in emissive and reflective modes. Whereas such next generation displays could provide optimal visibility in any ambient lighting situation, materials available that exhibit such characteristics in the active layer are limited due to the required intrinsic multifunctionality (i.e., redox activity, electroluminescence, electrochromism, and ion conductivity) and to date can only be achieved via the rational design of ionic transition-metal complexes. Reported herein is the synthesis and characterization of a new family of acrylate-containing ruthenium (tris)bipyridine-based coordination complexes with multifunctional characteristics. Potential use of the presented compounds in EC/EL devices is established, as they are applied as cross-linked electrochromic films and electrochemiluminescent layers in light-emitting electrochemical cell devices. Electrochromic switching of the polymeric networks between yellow, orange, green, brown and transmissive states is demonstrated, and electrochemiluminescent devices based on the complexes synthesized show red-orange to deep red emission with λ(max) ranging from 680 to 722 nm and luminance up to 135 cd/m(2). Additionally, a dual EC/EL device prototype is presented where light emission and multicolor electrochromism occur from the same pixel comprised of a single active layer, demonstrating a true combination of these properties in ionic transition-metal complexes.     

Alpha-nucleus elastic scattering at intermediate energies

Elastic scattering of 288,340,480 and 699 MeV Alpha-particles was measured on ²⁰⁸Pb, ¹¹⁶Sn and ⁵⁸Ni. The data were analysed in terms of a phenomenological optical model. The optical potentials obtained were found to vary consistently with the target nucleus and the incident energy. The radial zone where the potentials are well determined was studied in detail. The data for ²⁰⁸Pb were also analysed with a folding model. The energy dependence of the strong-absorption radius and of the reaction cross section shows that the nuclear surface becomes slightly transparent for incident energies above 150 MeV per nucleon.     

Intramolecular cyclization of delta-iminoacetylenes: a new entry to pyrazino[1,2-a]indoles

[reaction: see text] The synthesis of the pyrazino[1,2-a]indole nucleus was achieved by intramolecular cyclization of several 2-carbonyl-1-propargylindoles in the presence of ammonia. The reaction conditions were optimized using microwave heating and a pool of catalysts. Cyclization of 1-alkynylindole-2-carbaldehydes was easily accomplished under standard heating conditions, whereas microwave heating contributed to reduced reaction times and improved overall yields. Moreover, a fine-tuning of the microwave irradiation time made possible the selective synthesis of both pyrazino[1,2-a]indole isomers. TiCl4 proved the catalytic system of choice to achieve pyrazinoindoles in satisfactory yields starting from 1-alkynyl-2-acetylindoles and 1-alkynyl-2-benzoylindole derivatives. Also in these cases, microwave heating contributed to faster reactions and improved yields. The uncatalyzed versus catalyzed reaction mechanism is discussed.     

Dimethyldithiocarbamatoarsane und -stibane

Dimethyldithiocarbamatoarsanes and -stibanes The Halogeno-bis(dimethyldithiocarbamato)-compounds (dtc)₂AsCl 1 , (dtc)₂AsBr 2 , (dtc)₂AsI 3 and (dtc)₂SbI 4 are prepared from (dtc)₃As and (dtc)₃Sb resp. Reaction of 1 to 4 with CF₃SO₃Sime₃ yields the ionic compounds (dtc)₂As⁺CF₃SO₃^? 5 and [(dtc)₂El⁺]₂Hal^?(CF₃SO₃^?) · CH₂Cl₂ 6 (El = As; Hal = I), 7 (El = Sb; Hal = I) and 8 (El = As; Hal = Br) resp. by elimination of me₃SiHal. The mass spectra and the main fragmentation from 1 to 8 are reported. The vibrational spectra of these compounds, of As(dtc)₃, Sb(dtc)₃ and of the antimony compounds which are corresponding to 6 and 8 are discussed.     

A new synthetic procedure to spiro[cyclohexane-1,3′-indoline]-2′,4-diones

A new synthetic pathway to spiro[cyclohexane-1,3′-indoline]-2′,4-diones was found starting from 3-chloromethylene-2-indolones 1 and Danishefsky's diene 2. Their synthesis consists of several steps involving the formation of the cycloadducts, the 6-chloro-4-trimethylsilyloxy-2-methoxyspiro[cyclohex-3-en-1,3′-indolin]-2′-one derivatives, transformed into spiro[cyclohexa-2,5-dien-1,3′-indoline]-2′,4-diones via 6-chloro-spiro[cyclohex-2-en-1,3′-indoline]-2′,4-dione intermediates. The reduction of spiro[cyclohexa-2,5-dien-1,3′-indoline]-2′,4-diones gave spiro[cyclohexane-1,3′-indoline]-2′,4-diones 7. Using a ‘one pot reaction’, starting from 1 and 2, compounds 7 were obtained in satisfactory overall yield.     

Groups of finite exponent acting regulary on an abelian group

Let G be a group of squarefree exponent e which acts regularly on some abelian p-group V. If V is the union of a finite number of G-orbits and e divides p ? 1, we show that G is the cyclic group of order e.