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31.
Dušan J. Radanović Zoran D. Matović Vesna D. Miletić Luigi P. Battaglia Sandra Ianelli Inessa A. Efimenko Gustavo Ponticelli 《Transition Metal Chemistry》1996,21(2):169-175
Summary The reactions of N,N,N,N-tetramethylthiuram disulfide (tmtds) with gold(III) complexes of the [Au(L)X3] type [L = N-methylimidazole (N-Melm), 2-methylbenzoxazole (2-MeBO) and 2,5-dimethylbenzoxazole (2,5-diMeBO), X = Cl, Br or I] are reported, and yielded two main types of product - [Au(Me2dtc)X2] (A) and [Au(Me2dtc)2]X (B) (Me2dtc = N,N-dimethyldithiocarbamato anion). The ratio of the product yields (B/A) depends upon the nature of the ligand (L) and halogen (X). The ratio B/A for the reaction: [Au(L)Cl3] + tmtds = A + B, increases in the sequence N-MeIm < 2- MeBO < 2,5-diMeBO, which correlates well with the level of cytotoxic activity exhibited by the [Au(L)Cl3] complexes. A and B were characterized by their i.r., u.v-vis. and 1-n.m.r. spectra. The magnetic measurements were also recorded. The data support a squareplanar geometry for gold(III) complexes with the Me2dtc ligand bonded in a bidentate fashion; a conjecture has been verified crystallographically for [Au(Me2NCS2)2]-Br·2H2O. The X-ray analysis confirmed that the complex is composed of ionic units: [Au(Me2dtc)2] + and Br– and H2O molecules. The Au—S distances are markedly similar, falling in the 2.343(4)–2.350(3) A range. 相似文献
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33.
I. A. Efimenko N. A. Ivanova O. S. Erofeeva M. E. Akat’eva N. A. Dobrynina 《Russian Journal of Coordination Chemistry》2009,35(4):272-278
The systems Pd(II)-Cl?-HA-H2O (where HA are the conformers of 2-methylamino-1-phenylpropan-1-ol) were studied. The acid dissociation constants of the ligands HA and the resulting complexes were determined by pH-metric titration and mathematical modeling. The pH-distribution diagram of the complex species in the system containing different HA conformers was obtained. The complexes (H2A)2[PdCl4] were obtained and structurally characterized; their toxicity and radioprotective effects were estimated. The biological activity of the complexes was found to depend on both the ligand basicity and the hydrogen bonding system formed by different conformers of the ligand in the cation-anion complexes. 相似文献
34.
L. M. Sorokin L. P. Efimenko A. E. Kalmykov Yu. I. Smolin 《Physics of the Solid State》2004,46(5):983-988
Transmission electron microscopy is used to study the structure of the surface layer of an Al-7 wt % Si alloy subjected to laser alloying. The base volume is found to be occupied by an aluminum matrix having a braidlike structure. New phases have been revealed, and their composition, shape, and spatial distribution have been determined. 相似文献
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36.
K. Efimenko V. Rybka V. Švorčík V. Hnatowicz 《Applied Physics A: Materials Science & Processing》1999,68(4):479-482
Received: 25 September 1998 / Accepted: 25 November 1998 / Published online: 24 February 1999 相似文献
37.
Efimenko I. A. Churakov A. V. Erofeeva O. S. Ivanova N. A. Demina L. I. 《Russian Journal of Coordination Chemistry》2019,45(9):615-625
Russian Journal of Coordination Chemistry - The effect of the nature of halogen-substituted carboxylic acids RCOOH, where R is ClCH2, Cl2CH, Cl3C, or F3C, on the complexation of palladium... 相似文献
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Efimenko I. A. Efimov N. N. Erofeeva O. S. Demina L. I. Simonenko N. P. Churakov A. V. Minin V. V. 《Russian Journal of Coordination Chemistry》2021,47(10):707-716
Russian Journal of Coordination Chemistry - Palladium(I) coordination polymers with unsaturated dicarboxylic acids, {[cis-Pd(C4H2O4)(H2O)]·(H2O)}n (I) (maleic acid),... 相似文献
40.
Anastasia E. Kuvarina Irina A. Gavryushina Maxim A. Sykonnikov Tatiana A. Efimenko Natalia N. Markelova Elena N. Bilanenko Sofiya A. Bondarenko Lyudmila Y. Kokaeva Alla V. Timofeeva Marina V. Serebryakova Anna S. Barashkova Eugene A. Rogozhin Marina L. Georgieva Vera S. Sadykova 《Molecules (Basel, Switzerland)》2022,27(5)
Features of the biochemical adaptations of alkaliphilic fungi to exist in extreme environments could promote the production of active antibiotic compounds with the potential to control microorganisms, causing infections associated with health care. Thirty-eight alkaliphilic and alkalitolerant Emericellopsis strains (E. alkalina, E. cf. maritima, E. cf. terricola, Emericellopsis sp.) isolated from different saline soda soils and belonging to marine, terrestrial, and soda soil ecological clades were investigated for emericellipsin A (EmiA) biosynthesis, an antifungal peptaibol previously described for Emericellopsis alkalina. The analysis of the Emericellopsis sp. strains belonging to marine and terrestrial clades from chloride soils revealed another novel form with a mass of 1032.7 Da, defined by MALDI-TOF Ms/Ms spectrometers, as the EmiA lacked a hydroxyl (dEmiA). EmiA displayed strong inhibitory effects on cell proliferation and viability of HCT 116 cells in a dose- and time-dependent manners and induced apoptosis. 相似文献