Ionic liquid-functionalized magnetic nanostructures as an efficient catalyst for the synthesis of 6H-chromeno[4,3-b]quinolin-6-ones

A novel imidazole ionic liquid (IL)-functionalized \(\hbox {silica}@\gamma \)-\(\hbox {Fe}_{2}\hbox {O}_{3}\) (\(\hbox {IL-SiO}_{2}@\hbox {MNP}\)) is prepared by the functionalization of \(\hbox {SiO}_{2}@\hbox {MNP}\) by 1-butyl-3-(3-trimethoxypropyl)-1H-imidazol-3-ium chloride as the IL moiety. The catalyst is characterized by transmission electron microscopy, scanning electron microscope, vibrating sample magnetometer, dynamic light scattering and Fourier transform infrared spectroscopy. \(\hbox {IL-SiO}_{2}@\hbox {MNP}\) showed good activity in the synthesis of 6H-chromeno[4,3-b]quinolin-6-one derivatives via multicomponent reaction of 4-hydroxycoumarin, anilines and benzaldehydes. The nanocatalyst is magnetically separable and easily recoverable and showed successful activity up to 10 runs.     

Hypergeometric-Gaussian modes

We studied a novel family of paraxial laser beams forming an overcomplete yet nonorthogonal set of modes. These modes have a singular phase profile and are eigenfunctions of the photon orbital angular momentum. The intensity profile is characterized by a single brilliant ring with the singularity at its center, where the field amplitude vanishes. The complex amplitude is proportional to the degenerate (confluent) hypergeometric function, and therefore we term such beams hypergeometric-Gaussian (HyGG) modes. Unlike the recently introduced hypergeometric modes [Opt. Lett. 32, 742 (2007)], the HyGG modes carry a finite power and have been generated in this work with a liquid-crystal spatial light modulator. We briefly consider some subfamilies of the HyGG modes as the modified Bessel Gaussian modes, the modified exponential Gaussian modes, and the modified Laguerre-Gaussian modes.     

Folding model analysis of pion elastic and inelastic scattering from 6Li and 12C

π ^±-Nucleus scattering cross sections are calculated applying the Watanabe superposition model with a phenomenological Woods-Saxon potential. The phenomenological potential parameters are searched for π ^± scattering from ⁶Li and ¹²C to reproduce not only differential elastic cross sections but also inelastic and total and reaction cross sections at pion kinetic energies from 50 to 672 MeV. The optical potentials of ⁶Li and ¹²C are calculated in terms of the alpha particle and deuteron optical potentials. Inelastic scattering has been analyzed using the distorted waves from elastic-scattering data. The values of deformation lengths thus obtained compare very well with the ones reported earlier.     

Mapping of Shape Invariant Potentials by the Point Canonical Transformation

In this paper by using the method of point canonical transformation we find that the Coulomb and Kratzer potentials can be mapped to the Morse potential. Then we show that the Pöschl-Teller potential type I belongs to the same subclass of shape invariant potentials as Hulthén potential. Also we show that the shape-invariant algebra for Coulomb, Kratzer, and Morse potentials is SU(1,1), while the shape-invariant algebra for Pöschl-Teller type I and Hulthén is SU(2).     

Ciprofloxacin-functionalized magnetic silica nanoparticles: as a reusable catalyst for the synthesis of 1H-chromeno[2,3-d]pyrimidine-5-carboxamides and imidazo[1,2-a]pyridines

Molecular Diversity - In this research, synthesis and characterization of new surface-functionalized magnetic silica nanoparticles are reported. The magnetic silica nanoparticle was synthesized by...     

New bis[N-(4-pyridyl)-P-Toluene Sulfonamide] Palladium Dichloride a Novel Fluorophore for Determination of Lysine Amino Acid

Here, we are describing the study of the chemiluminescence arising from the reaction of bis (2,4,6-trichlorophenyl) oxalate (TCPO) system with new bis [N-(4-pyridyl)-p-toluene sulfonamide] palladium dichloride (BSPC) as a novel luminescent. The optimum concentrations of all reagents such as sodium salicylate (SS) as catalyst, hydrogen peroxide as oxidizing reagent and the relationships between the chemiluminescence intensity and concentrations of TCPO, SS, hydrogen peroxide and BSPC are reported. After optimization the required reagents, the system were used for determination of amino acid lysine, as an effective and selective quencher in the solution functioning in a Stern–Volmer fashion. This resulted in the development of a facile and highly sensitive chemiluminescence detection scheme for the determination of lysine in biological samples. Ultimately, estimating quenching constant K _q of 4.29?×?10³ M^?1 was successfully carried out. Under the optimal conditions, the evaluated lower and upper detection limits of measurable concentration of lysine are 1.17?×?10^?7 and 3.18?×?10^?4 M, respectively.     

Promoting the Range and Range Resolution of a LIDAR (DIAL) System Using a Suitable Pinhole Plasma Shutter

Pulsed transversely exited atmospheric (TEA) CO₂ lasers, employed extensively in various applications such as light detection and ranging (LIDAR), have a pulse duration of about a microsecond due totheir nitrogen tail. In order to promote the measurement accuracy and the mean power of the laser pulse, the pulse duration should be shortened. In this research, we present the details of making a passive pinhole plasma shutter for a LIDAR (DIAL) system, which shortens the pulse duration of CO₂ lasers from 1.5 μs to 25 ns in air at atmospheric pressure. This instrument increases the range resolution of the LIDAR system from 225 to 3.75 m. Also we show the results of investigation of the clipped pulse duration of the microsecond CO₂ laser pulse using aluminum and copper pinhole metal targets with different pinhole diameters (1.5 and 1.8 mm) and at various laser output energies (338 and 309 mJ). Our experimental results show that the aluminum pinhole is more suitable than the copper pinhole for shortening the nitrogen tail of the CO₂ laser pulse with a larger output average power. Thus, the range of the LIDAR system, which is proportional to the logarithm of the output pulse power, is increased.     

Entanglement generation between two colliding particles

Harmonics with the photon energy of up to ~150 eV were studied using extended ablation plumes as the nonlinear media. The application of the ablation pulses of different duration covering the range between a few tens of femtoseconds and a few tens of nanoseconds revealed the advanced features of the extended plasmas produced by the subnanosecond pulses for efficient harmonic generation. The examples of the quasi-phase-matching of a group of harmonics in the plateau range and the advantages of using the two-color pump and cluster-containing plasmas are presented. We analyze the spatial and coherence characteristics of the high-order harmonics produced during propagation of the 64 fs pulse through the extended plasma plume produced by 370 ps pulses. It is shown that the divergence of plasma harmonics in the plateau range is 7 times smaller than the divergence of the driving radiation used for high-order harmonic generation. The measurements of the coherence properties of the lower-order harmonics showed that the visibility of interference fringes in the far field was in the range of 0.54–0.73.     

Series solutions for steady three-dimensional stagnation point flow of a nanofluid past a circular cylinder with sinusoidal radius variation

This article deals with the study of the steady three-dimensional stagnation point flow of a nanofluid past a circular cylinder that has a sinusoidal radius variation. By means of similarity transformation, the governing partial differential equations are reduced into highly non-linear ordinary differential equations. The resulting non-linear system has been solved analytically using an efficient technique namely homotopy analysis method (HAM). Expressions for velocity and temperature fields are developed in series form. In this study, three different types of nanoparticles are considered, namely alumina (Al₂O₃), titania (TiO₂), and copper (Cu) with water as the base fluid. For alumina–water nanofluid, graphical results are presented to describe the influence of the nanoparticle volume fraction φ and the ratio of the gradient of velocities c on the velocity and temperature fields. Moreover, the features of the flow and heat transfer characteristics are analyzed and discussed for foregoing nanofluids. It is found that the skin friction coefficient and the heat transfer rate at the surface are highest for copper–water nanofluid compared to the alumina–water and titania–water nanofluids.