One‐Pot Three‐Component Synthesis of Oxazine Derivatives in Water

A one‐pot synthesis of oxazine derivatives via reaction between activated acetylenic compounds, benzoyl cyanide, and N‐nucleophiles in water as the solvent is described?.     

Isocyanide-based multicomponent reactions: synthesis of 2-(1-(alkylcarbamoyl)-2,2-dicyanoethyl)-N-alkylbenzamide and 1,7-diazaspiro[4,4]nonane-2,4-dione derivatives

A four-component reaction between 2-formylbenzoic acid, malononitrile, isocyanides, and primary alkyl amines has been developed for an efficient preparation of 2-(1-(alkylcarbamoyl)-2,2-dicyanoethyl)-N-alkylbenzamide and 1,7-diazaspiro[4,4]nonane-2,6-dione derivatives under two different conditions. It is shown that simply by changing the reaction solvent from ethanol to dichloromethane and controlling the order of the addition of reagents, two completely different products can be obtained. These multicomponent reactions showed high atom economy.     

Palladium-catalyzed addition of arylboronic acids to isocyanates

The addition of arylboronic acids to isocyanates catalyzed by palladium acetate in the presence of triphenylphosphine as the ligand is described.     

The efficient synthesis of 14-alkyl or aryl 14H-dibenzo[a,j]xanthenes catalyzed by bismuth(Ⅲ)chloride under solvent-free conditions

An efficient method for the synthesis of 14-alkyl or aryl 14H-dibenzo[a,j]xanthene derivatives by the reaction of β-naphthol,and aldehydes in the presence of a catalytic amount of bismuth（Ⅲ） chloride（BiCl₃） under solvent-free conditions at 110℃is described.Aliphatic and aromatic aldehydes were used in the reaction and in all cases the desired products were synthesized successfully.This reaction was studied under different temperatures;the maximum yield was obtained in a short reaction period at 110℃.The method offers the advantages of high yields,short reaction times,simplicity and easy workup compared to the conventional method of syntheses.     

Prime virtually semisimple modules and rings

Abstract

We show that the multiplication algebra of a nondegenerate Jordan algebra is a semiprime algebra.     

Evaluation of some pollutant levels in environmental samples collected from the area of the new campus of Taif University

The levels of radioactivity and heavy metals in soil, plant and groundwater samples collected from the area of the new campus of Taif University, Saudi Arabia, and its neighbouring areas have been determined. High-resolution gamma-ray spectroscopy was used for radioactivity measurements, and inductively coupled plasma atomic emission spectroscopy was used to determine the concentration of heavy metals. The means of ²²⁶Ra, ²²⁸Ra and ⁴⁰K concentrations in water samples collected from four wells were found to be 0.13±0.03, 0.05±0.03 and 1.3±0.5 Bq l^?1, respectively. The means of ²³⁸U, ²²⁶Ra, ²²⁸Ra (²³²Th for soil samples) and ⁴⁰K concentrations in wild plant and soil samples were found to be 3.7±4.1, 8.8±11.6, 3.8±2.9 and 1025±685, and 8.6±3.4, 12.8±3.4, 16.6±7.1 and 618±82 Bq kg^?1 dry weight (DW), respectively. The ¹³⁷Cs of artificial origin was also detected in soil samples with a mean concentration of 3.8±2.2 Bq kg^?1 DW. Evaluating the results, it can be concluded that the concentrations of ²³⁸U, ²²⁶Ra, ²³²Th and ⁴⁰K in soil samples fall within the world average. Furthermore, 19 trace and major elements in groundwater samples and 22 elements in soil and plant samples were determined. The sampling locations of soil can be classified into three groups (relatively high, medium and low polluted) according to their calculated metal pollution index using the contents of trace and major elements. A cluster analysis of the contents of radioactivity and trace element contents in soil samples shows the presence of two main distinct clusters of sampling locations.     

Folding model analysis of pion elastic and inelastic scattering from 6Li and 12C

π ^±-Nucleus scattering cross sections are calculated applying the Watanabe superposition model with a phenomenological Woods-Saxon potential. The phenomenological potential parameters are searched for π ^± scattering from ⁶Li and ¹²C to reproduce not only differential elastic cross sections but also inelastic and total and reaction cross sections at pion kinetic energies from 50 to 672 MeV. The optical potentials of ⁶Li and ¹²C are calculated in terms of the alpha particle and deuteron optical potentials. Inelastic scattering has been analyzed using the distorted waves from elastic-scattering data. The values of deformation lengths thus obtained compare very well with the ones reported earlier.     

Coupled-channels analysis of K<Superscript>+</Superscript> scattering from <Superscript>6</Superscript>Li and <Superscript>12</Superscript>C using the Watanabe superposition model

Coupled-channels calculations for the elastic and inelastic scattering of K⁺ at 715 MeV/c by ⁶Li and ¹²C at 635, 715 and 800 kaon Lab momenta have been analysed. The optical potentials of ¹²C and ⁶Li are calculated in terms of the alpha-particle and deuteron optical potentials. Good fits to the experimental data and phenomenological calculations are obtained for ⁶Li and ¹²C nuclei.     

Application of palladium nanoparticle‐decorated Artemisia abrotanum extract‐modified graphene oxide for highly active catalytic reduction of methylene blue,methyl orange and rhodamine B

A green palladium‐based catalyst supported on Artemisia abrotanum extract‐modified graphene oxide (Pd NPs/RGO‐A. abrotanum) hybrid material has been used as a recoverable and heterogeneous nanocatalyst for the catalytic reduction of various dyes, including methylene blue, methyl orange and rhodamine B, in the presence of NaBH₄ as reducing agent in aqueous medium at room temperature. With the help of UV–visible spectroscopy, the catalytic reactions were investigated. According to the results, these reactions followed the pseudo‐first‐order rate equation.