Synthesis of poly(vinyl chloride)‐b‐poly(n‐butyl acrylate)‐b‐poly(vinyl chloride) by the competitive single‐electron‐transfer/degenerative‐chain‐transfer‐mediated living radical polymerization in water

The synthesis of a block copolymer poly(vinyl chloride)‐b‐poly(n‐butyl acrylate)‐b‐poly(vinyl chloride) is reported. This new material was synthesized by single‐electron‐transfer/degenerative‐chain‐transfer‐mediated living radical polymerization (SET‐DTLRP) in two steps. First, a bifunctional macroinitiator of α,ω‐di(iodo)poly (butyl acrylate) [α,ω‐di(iodo)PBA] was synthesized by SET‐DTLRP in water at 25 °C. The macroinitiator was further reinitiated by SET‐DTLRP, leading to the formation of the desired product. This ABA block copolymer was synthesized with high initiator efficiency. The kinetics of the copolymerization reaction was studied for two PBA macroinitiators with number–average molecular weight of 10 k and 20 k. The relationship between the conversion and the number–average molecular weight was found to be linear. The dynamic mechanical thermal analysis suggests just one phase, indicating that copolymer behaves as a single material with no phase separation. This methodology provides the access to several block copolymers and other complex architectures that result from combinations of thermoplastics (PVC) and elastomers (PBA). From industrial standpoint, this process is attractive, because of easy experimental setup and the environmental friendly reaction medium. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3001–3008, 2006     

Single electron transfer–degenerative chain transfer living radical polymerization of N‐butyl acrylate catalyzed by Na2S2O4 in water media

Living radical polymerization of n‐butyl acrylate was achieved by single electron transfer/degenerative‐chain transfer mediated living radical polymerization in water catalyzed by sodium dithionate. The plots of number–average molecular weight versus conversion and ln[M]₀/[M] versus time are linear, indicating a controlled polymerization. This methodology leads to the preparation of α,ω‐di(iodo) poly (butyl acrylate) (α,ω‐di(iodo)PBA) macroinitiators. The influence of polymerization degree ([monomer]/[initiator]), amount of catalyst, concentration of suspending agents and temperature were studied. The molecular weight distributions were determined using a combination of three detectors (TriSEC): right‐angle light scattering (RALLS), a differential viscometer (DV), and refractive index (RI). The methodology studied in this work represents a possible route to prepare well‐tailored macromolecules made of butyl acrylate in an environmental friendly reaction medium. Moreover, such materials can be subsequently functionalized leading to the formation of different block copolymers of composition ABA. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2809–2825, 2006     

Identified charged particles in quark and gluon jets

A sample of 2.2 million hadronic Z decays, selected from the data recorded by the Delphi detector at Lep during 1994–1995 was used for an improved measurement of inclusive distributions of and p and their antiparticles in gluon and quark jets. The production spectra of the individual identified particles were found to be softer in gluon jets compared to quark jets, with a higher multiplicity in gluon jets as observed for inclusive charged particles. A significant proton enhancement in gluon jets is observed indicating that baryon production proceeds directly from colour objects. The maxima, , of the -distributions for kaons in gluon and quark jets are observed to be different. Received: 24 January 2000 / Revised version: 15 May 2000 / Published online: 8 September 2000     

B* production in Z decays

The decayB ^*B has been observed with the DELPHI detector at LEP, where theB ^* meson is produced inZ boson decays. The combination of inclusively reconstructedB mesons with well-measured converted photons yields a measurement of the flavour-averagedB ^*-B mass difference of 45.5±0.3 (stat.) ±0.8 (syst.) MeV/c². 95% confidence level upper limits at 6 MeV/c² are placed on both the isospin (i.e.B ⁺-B ⁰) and theB _s -B _ud splitting of the mass difference. The production ratio ofB ^* toB mesons inZ decays is measured to be 0.72±0.03 (stat.) ±0.06 (syst.). Limits on the production cross-section of other hypothetical excitedB hadron states decaying radiatively are established. The differentialB ^* cross section has been measured to be in good agreement with the averageb fragmentation, yielding an average fractionalB ^* energy of x _E =0.695±0.009 (stat.) ±0.013 (syst.). From the decay angular distribution the relative contribution of longitudinalB ^* polarisation states is measured to be _L/(_L + _T) = 0.32 ± 0.04 (stat.) ±0.03 (syst.).CICYT_AEN93-0832     

Measurement of the forward-backward asymmetry of charm and bottom quarks at theZ pole usingD*± mesons

The forward-backward asymmetries for the processes and at theZ resonance are measured using identifiedD ^*± mesons. In 905,000 selected hadronic events, taken in 1991 and 1992 with the DEL-PHI detector at LEP, 4757D ^*+D ⁰⁺ decays are reconstructed. Thec andb quark forward-backward asymmetries are determined to be:

Observation of a centrality-dependent dijet asymmetry in lead-lead collisions at sqrt[S(NN)] =2.76 TeV with the ATLAS detector at the LHC

By using the ATLAS detector, observations have been made of a centrality-dependent dijet asymmetry in the collisions of lead ions at the Large Hadron Collider. In a sample of lead-lead events with a per-nucleon center of mass energy of 2.76 TeV, selected with a minimum bias trigger, jets are reconstructed in fine-grained, longitudinally segmented electromagnetic and hadronic calorimeters. The transverse energies of dijets in opposite hemispheres are observed to become systematically more unbalanced with increasing event centrality leading to a large number of events which contain highly asymmetric dijets. This is the first observation of an enhancement of events with such large dijet asymmetries, not observed in proton-proton collisions, which may point to an interpretation in terms of strong jet energy loss in a hot, dense medium.     

A precision measurement of the average lifetime ofB hadrons

The average lifetime ofB hadrons was measured using data collected with the DELPHI detector at the LEP collider during 1991 and 1992. The measurement was performed using two different anayses. The first method was an improvement on a previous technique, which used charged particle impact parameter distributions. This analysis measured an average lifetime forB hadrons of

Calculated Infrared, Raman, and Rayleigh Properties of the CO(3) Molecule

Properties associated with the infrared, Rayleigh, and Raman spectra of the CO(3) molecule are calculated by the Hartree-Fock and M?ller-Plesset perturbation theory methods. Vibrational frequencies and infrared activities are found to be in agreement with the experiment and previous calculations. The values obtained for the Raman spectrum show a very sensitive dependence to the treatment of electron correlation. The OCO wag normal mode, unobserved in the IR experiment, is predicted to have a very small Raman scattering activity. Copyright 2000 Academic Press.     

Production rate and decay lifetime measurements ofBs0 mesons at LEP usingDs and? mesons

The study of the properties of inclusive production ofD _s mesons and of events in which a and a muon are present in the same jet provides two independent measurements of the probability,f _s ^w , for a heavy quark to hadronize into a strangeB orD meson. The data sample analysed corresponds to 243,000 hadronicZ ⁰ decays. The combined value of these measurements isf _s ^w =0.19±0.06±0.08. From the flight distance distributions ofD _s and of (-lepton) secondary vertices, with the lepton emitted at high transverse momentum relative to the jet axis, two values are obtained for theB _s ⁰ meson lifetime. Combining these measurements with a previous result based on the study ofD _s- events, theB _s ⁰ meson lifetime is measured to be: 0.96±0.37 ps.     

可用于建筑结构检测的分布式光纤形变片

本文在光时域反射计（OTDR）和光纤形片的基础上,提出了一种分布式光纤传感器－分布式光纤形变片,该检测方法属于OTDR的损耗调制法,即通过测量粘贴于光纤形变片上的光纤弯曲损耗来获取测量点的应变量或位移量,作者分别在微位移架和悬臂梁进行了位移检测和应变检测,结果表明该分布式光纤形变片提供了一种可检测应变量与位移量的检测方法,值得注意的是,该分布式光纤形变片的传感网络采用时分复用的总线拓扑,能在一根光纤上同时检测多个检测点的变化。