An anomalous emission excited near the absorption edge of pyrene crystals

Emission spectra and decay times of the fluorescence excited at the absorption edge region in pyrene crystals were measured. At liquid nitrogen temperature, the fluorescence under the excitation at 390 nm is considered as the excimer emission and its band peak shifts a little to the short wavelength in comparison with that of the excimer emission under the excitation at 360 nm. The emission decay times under the excitation at the 390 nm and 360 nm are about 155 ns and 180 ns, respectively, at liquid nitrogen temperature. The former decay time changes its value abruptly near 127 K. This abrupt change of the decay time may be due to the phase transition in pyrene crystals.     

Magnetic scattering of neutrons in magnetic superconductors

The magnetic dipolar interaction responsible for the neutron scattering due to magnetic moments in a crystal is affected by the persistent current in the superconducting state. From this effect, the small angle scattering of neutrons is strongly depressed, and the intensity maximum of the critical scattering appears at a finite scattering wave number even in ferromagnetic superconductors.     

Complexity of Body Movements during Sleep in Children with Autism Spectrum Disorder

Recently, measuring the complexity of body movements during sleep has been proven as an objective biomarker of various psychiatric disorders. Although sleep problems are common in children with autism spectrum disorder (ASD) and might exacerbate ASD symptoms, their objectivity as a biomarker remains to be established. Therefore, details of body movement complexity during sleep as estimated by actigraphy were investigated in typically developing (TD) children and in children with ASD. Several complexity analyses were applied to raw and thresholded data of actigraphy from 17 TD children and 17 children with ASD. Determinism, irregularity and unpredictability, and long-range temporal correlation were examined respectively using the false nearest neighbor (FNN) algorithm, information-theoretic analyses, and detrended fluctuation analysis (DFA). Although the FNN algorithm did not reveal determinism in body movements, surrogate analyses identified the influence of nonlinear processes on the irregularity and long-range temporal correlation of body movements. Additionally, the irregularity and unpredictability of body movements measured by expanded sample entropy were significantly lower in ASD than in TD children up to two hours after sleep onset and at approximately six hours after sleep onset. This difference was found especially for the high-irregularity period. Through this study, we characterized details of the complexity of body movements during sleep and demonstrated the group difference of body movement complexity across TD children and children with ASD. Complexity analyses of body movements during sleep have provided valuable insights into sleep profiles. Body movement complexity might be useful as a biomarker for ASD.     

Neutron irradiation effects on magnetic minor hysteresis loops in nuclear reactor pressure vessel steels

Magnetic minor hysteresis loops have been measured on A533B-type nuclear reactor pressure vessel steels with various combinations of Cu and Ni contents after neutron irradiation to a fluence up to 3.32 × 10¹⁹ n cm^?2. A strong compositional dependence of minor-loop properties, which are indicators of internal stress, was found. The properties of high-Cu and high-Ni steel show a large increase in the low fluence regime below 0.4 × 10¹⁹ n cm^?2, followed by a slow decrease, while those for low-Cu or low-Ni steel show a sudden decrease. The changes are roughly in linear proportion to the yield strength changes. The results were explained from the viewpoint of the formation and growth of Cu-rich precipitates and/or fine scale defects in the matrix and along pre-existing dislocations.     

Analysing the sintering of heterogeneous powder structures by in situ microtomography

This work analyses the microstructure changes of various copper-based powder systems during sintering from 3D images provided by in situ synchrotron microtomography. The investigated systems include a copper powder with a wide particle size distribution of 0–63 µm poured into a quartz capillary, a pre-sintered copper compact with artificially created large pores and a mixture of copper and alumina particles. The experiments were carried out at the European Synchrotron in Grenoble, France. Powders were sintered up to 1060°C under reducing atmosphere in a furnace located between the X-ray source and the detector. During each experiment, 3D images were taken at various times of the thermal cycle. We have obtained images with a resolution of 1.5 µm and the time of acquisition of every image was ～1 min. Quantitative analysis of these images allowed the changes of various important parameters to be followed. Such parameters characterise the sintering process at the particle length scale: interparticle coordination, pore size distribution and particle centre-to-centre distance. Moreover, by tracking the displacement of each particle centre and comparing it to the displacement predicted by classical mean field assumption, we have been able to assess the magnitude of particle rearrangement occurring during sintering. From these data, the sintering behaviour of heterogeneous powder systems is discussed with particular emphasis of collective particle phenomena.     

Migration of excimers in pyrene crystals

Emission decay times of the new excimer were measured for undoped and perylene doped pyrene crystals. From the decay times obtained, the temperature dependence of the diffusion coefficient of the excimers was deduced by assuming a model in which two electronic states of the new excimer are involved in the energy transfer process. Within this model, it was found that in the upper excimer state the excimers migrated by a hopping process, while in the lower excimer state they migrated as free excimer excitons while undergoing phonon scattering.