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51.
The fracture behavior of a core-shell rubber (CSR) modified epoxy is investigated using both fracture mechanics and microscopy tools. The CSR-modified epoxy is found to be toughened via numerous line-array cavitations of the CSR particles, followed by plastic flow of the epoxy matrix. The toughening effect via the above craze-like damage process is found to be as effective as that of the well-known widespread rubber cavitation/matrix shear yielding mechanisms. The conditions for triggering the craze-like damage appear to be both stress state and rubber concentration dependent. The type of rubber tougheners utilized also plays a critical role in triggering this rather unusual craze-like damage in epoxy systems. © 1993 John Wiley & Sons, Inc.  相似文献   
52.
In situ measurements of gas-liquid surface reactions of single aerosol microdroplets are presented. By means of optical levitation in combination with elastic (Mie) and inelastic (Raman) light scattering it is possible to get information on the chemistry of e.g. acid/base reactions as well as the physical behavior of single microparticles.  相似文献   
53.
We examine the influence of relativistic and QED effects on the existence of the 1,3P o H- resonances between n = 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths of fifteen 1P o resonances, and fifteen 3P o resonances. The fifteen 1P o resonances are classified to be 3 (2, 0) - n ( 4 ? n ? 12) and 3 (1, 1) + n ( 3 ? n ? 8). The fifteen 3P o resonances are classified to be 3 (2, 0) + n ( 3 ? n ? 12) and 3 (1, 1) - n ( 4 ? n ? 8). We found there exist six Feshbach resonances for 3 (2, 0) - n (1P o ) series, four Feshbach resonances for 3 (1, 1) + n (1P o ) series, seven Feshbach resonances for 3 (2, 0) + n (3P o ) series, and three Feshbach resonances for 3 (1, 1) - n (1P o ) series. Received 22 February 2002 Published online 24 September 2002  相似文献   
54.
A representation in the form of a functional integral is obtained for the partition function of the inhomogeneous 2D Ising model on a triangular lattice where the coupling parameters are arbitrary functions of coordinates. The method for transforming the partition function into an integral uses an auxiliary six-component Grassmann field in which the Grassmann fields corresponding to one of the components commute with the others. Thus, one pair of components realizes a representation of the q-deformed group SLq(2, R) with q=–1 and the other two pairs correspond to the usual Grassmann spinors (q=1). An explicit expression in terms of the modified Pfaffian is found for the Gaussian integral over these fields and its relation to the ordinary Grassmann functional integral is established.Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 109, No. 3, pp. 441–463, December, 1996.  相似文献   
55.
Thermoelastic stress analysis was used to document the effect of composite damage on the stress distribution in three ceramic matrix composites. Composite damage was found to significantly alter the thermoelastic response of each material, with the greatest effect noted in SiC/CAS. Thermoelastic imaging of these materials affords a more complete picture of how the various damage mechanisms affect the stress distribution. In particular, a stress concentration factor computed from thermoelastic images, serves as an indicator of stress redistribution. The stress concentration factors were computed by comparing notch root to far field temperatures, and monitored after the introduction of various amounts of damage. In each material, the stress concentration factor diminished as the damaging load approached the ultimate stress. Reduction in the stress concentration is associated with local changes in modulus, mechanistically arising from combinations of fiber, matrix and interface fracture. Stress redistribution occurs as a consequence of modulus changes, leading to lower notch sensitivity in each of the tested composites.  相似文献   
56.
57.
The Mathematical Intelligencer encourages comments about the material in this issue. Letters to the editor should be sent to either of the editors-in-chief, Chandler Davis or Marjorie Senechal.  相似文献   
58.
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007  相似文献   
59.
In this work, we propose that retardation in vinyl acetate polymerization rate in the presence of toluene is due to degradative chain transfer. The transfer constant to toluene (Ctrs) determined using the Mayo method is equal to 3.8 × 10?3, which is remarkably similar to the value calculated from the rate data, assuming degradative chain transfer (2.7 × 10?3). Simulations, including chain‐length‐dependent termination, were carried out to compare our degradative chain transfer model with experimental results. The conversion–time profiles showed excellent agreement between experiment and simulation. Good agreement was found for the Mn data as a function of conversion. The experimental and simulation data strongly support the postulate that degradative chain transfer is the dominant kinetic mechanism. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3620–3625, 2007  相似文献   
60.
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments.  相似文献   
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