首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   358350篇
  免费   2239篇
  国内免费   862篇
化学   187794篇
晶体学   5184篇
力学   16604篇
综合类   13篇
数学   42187篇
物理学   109669篇
  2020年   3339篇
  2019年   3960篇
  2018年   5591篇
  2017年   5644篇
  2016年   7300篇
  2015年   3779篇
  2014年   6482篇
  2013年   14721篇
  2012年   11142篇
  2011年   13390篇
  2010年   10278篇
  2009年   10307篇
  2008年   13039篇
  2007年   13004篇
  2006年   11999篇
  2005年   10786篇
  2004年   9938篇
  2003年   8995篇
  2002年   9071篇
  2001年   9873篇
  2000年   7632篇
  1999年   5791篇
  1998年   5126篇
  1997年   5029篇
  1996年   4664篇
  1995年   4032篇
  1994年   4065篇
  1993年   4141篇
  1992年   4314篇
  1991年   4621篇
  1990年   4443篇
  1989年   4491篇
  1988年   4325篇
  1987年   4331篇
  1986年   4123篇
  1985年   5300篇
  1984年   5422篇
  1983年   4505篇
  1982年   4840篇
  1981年   4622篇
  1980年   4263篇
  1979年   4708篇
  1978年   5005篇
  1977年   5078篇
  1976年   5130篇
  1975年   4855篇
  1974年   4777篇
  1973年   5047篇
  1972年   3746篇
  1971年   3326篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
122.
A nonlinear (in the cubic approximation) relaxation equation of state is derived for a rod containing cracks partially filled with an incompressible viscous liquid. The nonlinear effects of the self-action and interaction of low-and high-frequency longitudinal elastic waves propagating in such a rod are studied for the cases of identical and size-varied cracks. Linear and nonlinear acoustic parameters characterizing the self-action and interaction of elastic waves in a cracked rod are determined.  相似文献   
123.
We describe in detail fundamental properties of continuity modules of various orders in the spaces L p of functions defined on a finite segment. We establish some general estimates of seminorms in terms of continuity modules with the best known constants. An example of application of these results to the best approximations is considered. Bibliography: 32 titles.  相似文献   
124.
The dynamics of the photoinduced differential absorption and excited-state bleaching spectra of single-walled carbon nanotubes suspended in a micellar solution were studied in the spectral range from 40 to 1000 nm within a time interval from 70 fs to 150 ps under excitation by 50-fs pulses with photon energies 2 and 4 eV. The bleaching and absorption bands were observed in the spectra; the positions of the bleaching peaks were independent of the photon energy of the exciting femtosecond pulse in the range 2–4 eV. It was established that, for delay times shorter than 1 ps, the shape of the differential spectrum of excited nanotubes coincided with the shape of the second derivative of the absorption spectrum of unexcited nanotubes in the frequency range of exciting pulse above 18000 cm?1 (the range of absorption bands of metallic nanotubes). In the frequency range below 16000 cm?1 (the range of absorption peaks of semiconducting nanotubes), the bleaching peaks in the differential spectrum of excited nanotubes undergo a high-frequency shift of 200–300 cm?1 with respect to the second-derivative spectrum of unexcited nanotubes. The excited-state relaxation rate constants were measured. They are well approximated by the exponential dependences and depend on the probe-pulse wavelength. An assumption was made about the nature of the observed spectra of excited nanotubes and about the excitation relaxation.  相似文献   
125.
Photorefractive scattering occurs in rhodium-doped lithium niobate crystals irradiated by coherent light. The photorefractive scattering has both wide-angle and selective components. The results of experimental investigation of selective photorefractive scattering in LiNbO3:Rh crystals and calculation of the spatial structure of scattering are reported. The selective scattering is regarded as a kind of a frequency-degenerate fourwave vector interaction.  相似文献   
126.
Equivalent acoustic source characterization of duct-borne fluid machinery noise is often undertaken by interpolating the results of two-microphone pressure measurements with different external acoustic loads over a linear one-port source model. If the source is time-invariant, the one-port source characteristics can be determined by using only two external loads. This is well known as the two-load method. An extension of the two-load method for time-variant sources is also available and known as the multiple-load method. In these methods the source is treated as a ‘black-box’. This paper addresses the problem of one-port source characterization when the linear operations inherent in the ‘black-box’ are known explicitly. The equations governing the explicit one-port source models are derived and the source characteristics are shown to be measurable using only few acoustic loads. It is not the purpose of this paper to discuss the application of these models to any specific fluid machinery; however, of particular interest are the explicit source models that require only two loads. Numerical results are presented to show some features of such time-invariant and time-variant explicit one-port source models.  相似文献   
127.
In this paper we introduce symplectic invariants for convex Hamiltonian energy surfaces and their periodic trajectories and show that these quentities satisfy several nontrivial relations. In particular we show that they can be used to prove multiplicity results for the number of periodic trajectories.This paper represents results obtained while holding a visiting position at the Courant Institute for Mathematical Sciences, New YorkResearch partially supported by NSF Grant No. DMS-8603149 and a Rutgers University Research Council Grant  相似文献   
128.
129.
130.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号