Electrooptical anharmonicity parameters of the strong hydrogen bond

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 54, No. 4, pp. 581–587, April, 1991.     

A dynamical test of phase transition order: New things in old places or old wine in new bottles

We first discuss nonlinear aspects of phase transition theory applied to a particular liquid crystal phase transition. A simple derivation is given to show how two coupled Goldstone modes (one appearing as gauge fluctuations of the ordered phase) can force a phase transition, against all expectations, to take place discontinuously (theory of Halperin, Lubensky, and Ma)-but the discontinuity may be immeasurably small. Then, we describe a new dynamical test of phase transition order, developed by Cladiset al., that turns out to be more sensitive than x-ray diffraction and adiabatic calorimetry. Quantitative data found by this new method are in excellent agreement with the measurements of adiabatic calorimetry and x-ray diffraction as well as expectations implicit in the predictions of HLM.This is the text of an after-banquet talk given at the CNLS Workshop on the Dynamics of Concentrated Systems.     

Study of formation mechanism of 1,3-benzodioxanes from tertiary phenoloalcohols and carbonyl compounds using labeled atoms

It was shown that the reaction of o-hyroxyphenyldiphenylmethanol with benzaldehyde labeled with ¹⁷O and ¹⁸O isotopes proceeds in such a way that oxygen atoms of the starting phenoloalcohol are retained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 632–633, May, 1991.     

Dynamics of the two-atom Jaynes-Cummings model with nondegenerate two-photon transitions

An exact solution is found for the collective model of two identical two-level atoms that resonantly interact with a two-mode quantum electromagnetic field in an ideal cavity via two-photon nondegenerate transitions. In the case under study, at the initial moment, both field modes are in the coherent state and atoms are in the excited state. The time dependences of the atomic probabilities, the mean number of photons in the modes, and the statistics and squeezing of the photon modes are studied based on the exact solution.     

The application of a vehicle routing model to a waste-collection problem: two case studies

In this paper we suggest a unique model for estimating the operating cost of each of three waste-collection systems. Under the traditional system, which is widely used, waste is typically collected in plastic bags and a three-man crew is needed on each vehicle. The other two systems require a one-man crew for vehicle collecting street containers. The side-loader system with fixed body automatically empties street containers into the vehicle body and empties the load at the disposal site. The side-loader system with demountable body allows the separation of the waste collection phase from transport to the disposal site, since the vehicle body can be demounted. We also present two case studies and show how the estimation of operating costs is a critical issue in decisions regarding the type of system to be used for waste collection.     

Half twists and the cohomology of hypersurfaces

A Hodge structure V of weight k on which a CM field acts defines, under certain conditions, a Hodge structure of weight , its half twist. In this paper we consider hypersurfaces in projective space with a cyclic automorphism which defines an action of a cyclotomic field on a Hodge substructure in the cohomology. We determine when the half twist exists and relate it to the geometry and moduli of the hypersurfaces. We use our results to prove the existence of a Kuga-Satake correspondence for certain cubic 4-folds. Received: 25 August 2000; in final form: 8 January 2001 / Published online: 18 January 2002     

Characterization and Computation of Canonical Tight Windows for Gabor Frames

Let (\gnm)_{n,m ? \Zst}(\gnm)_{n,m\in\Zst} be a Gabor frame for \LtR\LtR for given window gg. We show that the window \ho = \SQI g\ho=\SQI g that generates the canonically associated tight Gabor frame minimizes ||g-h||\|g-h\| among all windows hh generating a normalized tight Gabor frame. We present and prove versions of this result in the time domain, the frequency domain, the time-frequency domain, and the Zak transform domain, where in each domain the canonical \ho\ho is expressed using functional calculus for Gabor frame operators. Furthermore, we derive a Wiener--Levy type theorem for rationally oversampled Gabor frames. Finally, a Newton-type method for a fast numerical calculation of \ho\ho is presented. We analyze the convergence behavior of this method and demonstrate the efficiency of the proposed algorithm by some numerical examples.     

Raman spectroscopy of topotecan, an inhibitor of DNA topoisomerase I

Topotecan (TPT), a water-soluble derivative of camptothecin (inhibitor of human DNA topoiomerase I), has found wide application in cancer chemotherapy. The central problem in using topotecan is the presence of lactone rings in its molecules, which undergo hydrolysis at a physiological pH yielding an inactive and even toxic form of the drug. The analysis of Raman spectra of TPT in H₂O and D₂O solutions made it possible to assign the spectral bands to the vibrations of particular molecular groups. Spectral features indicative of the opening of the lactone rings of the TPT molecules, deprotonation of the hydroxyl groups in their quinoline fragments, and of possible participation of the hydroxyl and carbonyl groups in H bonding are found. The data obtained are necessary to study the molecular mechanisms of TPT-DNA interaction and the formation of ternary complexes between TPT, DNA, and DNA topoisomerase I.     

Black-hole horizon and metric singularity at the brane separating two sliding superfluids

An analogue of a black hole can be realized in the low-temperature laboratory. The horizon can be constructed for “relativistic” ripplons (surface waves) living on the brane. The brane is represented by the interface between two superfluid liquids, ³He-A and ³He-B, sliding along each other without friction. A similar experimental arrangement was recently used for the observation and investigation of the Kelvin-Helmholtz type of instability in superfluids [1]. The shear-flow instability in superfluids is characterized by two critical velocities. The lowest threshold measured in recent experiments [1] corresponds to the appearance of the ergoregion for ripplons. In the modified geometry, this will give rise to the black-hole event horizon in the effective metric experienced by ripplons. In the region behind the horizon, the brane vacuum is unstable due to interaction with the higher-dimensional world of bulk superfluids. The time of the development of instability can be made very long at low temperature. This will allow us to reach and investigate the second critical velocity—the proper Kelvin-Helmholtz instability threshold. The latter corresponds to the singularity inside the black hole, where the determinant of the effective metric becomes infinite.