全文获取类型
收费全文 | 215442篇 |
免费 | 1564篇 |
国内免费 | 627篇 |
专业分类
化学 | 117926篇 |
晶体学 | 3271篇 |
力学 | 8349篇 |
综合类 | 6篇 |
数学 | 23305篇 |
物理学 | 64776篇 |
出版年
2020年 | 1970篇 |
2019年 | 2263篇 |
2018年 | 3205篇 |
2017年 | 3113篇 |
2016年 | 4267篇 |
2015年 | 2371篇 |
2014年 | 3818篇 |
2013年 | 9260篇 |
2012年 | 6891篇 |
2011年 | 8434篇 |
2010年 | 6071篇 |
2009年 | 5921篇 |
2008年 | 8136篇 |
2007年 | 8206篇 |
2006年 | 7629篇 |
2005年 | 6937篇 |
2004年 | 6166篇 |
2003年 | 5641篇 |
2002年 | 5500篇 |
2001年 | 5939篇 |
2000年 | 4685篇 |
1999年 | 3471篇 |
1998年 | 3007篇 |
1997年 | 3033篇 |
1996年 | 2823篇 |
1995年 | 2319篇 |
1994年 | 2419篇 |
1993年 | 2450篇 |
1992年 | 2595篇 |
1991年 | 2657篇 |
1990年 | 2559篇 |
1989年 | 2533篇 |
1988年 | 2463篇 |
1987年 | 2434篇 |
1986年 | 2357篇 |
1985年 | 3037篇 |
1984年 | 3194篇 |
1983年 | 2559篇 |
1982年 | 2827篇 |
1981年 | 2703篇 |
1980年 | 2503篇 |
1979年 | 2718篇 |
1978年 | 2833篇 |
1977年 | 2856篇 |
1976年 | 2832篇 |
1975年 | 2687篇 |
1974年 | 2665篇 |
1973年 | 2810篇 |
1972年 | 1875篇 |
1967年 | 1830篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
951.
952.
953.
954.
On P? P Containing Cyclic Compounds. II. Reaction of N,N'-dimethylthiourea with phenyl dichlorophosphane yields 1.4-dimethyl-2. 3-diphenyl-1.4.2.3-diazadiphospholidine-5-thione-2-sulfide ( II ). The compound is characterized by its nmr, vibration and mass spectra as well as the results of an X-ray structural analysis. Byproduct of the reaction is N-(N,N'-dimethylcarbamimidoyl)-N,N'-dimethyl thiourea hydrochloride ( III ), which crystallizes with pyridinium chloride. Molecular and crystal structure are reported. With methyl dichlorophosphane N,N'-dimethylthiourea forms 1.2.3.4-tetramethyl-1.4.2.3-diazadiphospholidine-5-thione-2-sulfide ( IV ), which is characterized by its nmr and vibration spectra. 相似文献
955.
M. V. Priyutov M. A. Kovner I. E. Krainova P. V. Kosterin 《Journal of Structural Chemistry》1983,24(5):653-658
956.
957.
A H van Gennip J Grift E J van Bree-Blom D Ketting S K Wadman 《Journal of chromatography. A》1979,163(4):351-362
Chromatographic characteristics of urinary metabolites of theophylline were studied by two-dimensional thin-layer chromatography, high-performance liquid chromatography and gas chromatography--mass spectrometry. Quantitative date for the urinary metabolites of theophylline in asthmatic children are given. It was shown that 1,3-dimethyluric acid is the predominant excretory product. In addition, smaller amounts of 1-methyluric acid, 3-methylxanthine and unchanged theophylline were found. Excretory patterns after theophylline ingestion before and during the administration of allopurinol in asthma patients and in rats suggest the existence of three metabolic pathways of theophylline. The administration of this drug to a patient with xanthine oxidase of theophylline. The administration of this drug to a patient with xanthine oxidase deficiency resulted in the excretion of 1-methyluric acid in addition to 1,3-dimethyluric acid, 3-methylxanthine, 1-methylxanthine and unchanged theophylline. It was concluded that in man the oxidation of theophylline is not catalysed by xanthine oxidase. 相似文献
958.
A new pyridine synthesis has been found by refluxing certain simple secondary car☐amides in HMPA. Thus 2,6-dimethylpyridine, 2-ethyl-6-methylpyridine, 2,3,6-trimethylpyridine, 2-ethyl-3,6-dimethylpyridine, 2-benzyl-6-methyl-3-phenylpyridine, 2-ethyl-3-methyl-5,6,7,8-tetrahydroquinoline and 2-t-butyl-6-methylpyridine were prepared in 15–40% yield. 相似文献
959.
G. B. Golubitskii E. V. Budko E. M. Basova A. V. Kostarnoi V. M. Ivanov 《Journal of Analytical Chemistry》2007,62(2):152-156
The effects of acetonitrile and potassium dihydrogen phosphate concentrations in a mobile phase and the pH of the mobile phase on the retention of analgin (dipyrone) and anesthesin (benzocaine) on Symmetry C18 and Nova-Pak CN HP sorbents with grafted octadecylsilanol and nitrile groups, respectively, were studied. It was found that, under identical conditions, retention on the sorbent with grafted nitrile groups was weaker. A rapid and cost-effective procedure was developed for the determination of analgin and anesthesin in the analysis of Bellalgin tablets. 相似文献
960.
E. M. Peresleni M. Ya. Uritskaya V. A. Azimov V. A. Loginova T. F. Vlasova Yu. N. Sheinker L. N. Yakhontov 《Chemistry of Heterocyclic Compounds》1974,10(3):340-344
It was shown by means of IR, UV, and PMR spectra that -(3-nitro-2-pyridyl)pyruvic acid esters are practically completely enolized in the crystal state and in solution; ethyl -(3-nitro-4-pyridyl)pyruvate has an enol structure in the crystalline state and in pyridine solution but exists as a mixture of keto and enol forms in low-polarity solvents.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 389–393, March, 1974. 相似文献