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561.
Tyagi P Deratani A Bouyer D Cot D Gence V Barboiu M Phan TN Bertin D Gigmes D Quemener D 《Angewandte Chemie (International ed. in English)》2012,51(29):7166-7170
When pressure is applied to dynamic interactive membranes consisting of micelles composed of a triblock copolymer, their morphologies can be fine-tuned. Membranes with a range of porosities are accessible which can regulate and thereby control filtration performance and also display effective autonomous healing. 相似文献
562.
Barrère C Chendo C Phan TN Monnier V Trimaille T Humbel S Viel S Gigmes D Charles L 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(25):7916-7924
A sample pretreatment was evaluated to enable the production of intact cationic species of synthetic polymers holding a labile end-group using matrix-assisted laser desorption/ionization (MALDI) mass spectrometry. More specifically, polymers obtained by nitroxide-mediated polymerization involving the MAMA-SG1 alkoxyamine were stirred for a few hours in trifluoroacetic acid (TFA) to induce the substitution of a tert-butyl group on the nitrogen of nitroxide end-group by a hydrogen atom. Nuclear magnetic resonance, electrospray ionization tandem mass spectrometry, and theoretical calculations were combined to scrutinize this sample pretreatment from both mechanistic and energetic points of view. The substitution reaction was found to increase the dissociation energy of the fragile C-ON bond to a sufficient extent to prevent this bond to be spontaneously cleaved during MALDI analysis. This TFA treatment is shown to be very efficient regardless of the nature of the polymer, as evidenced by reliable MALDI mass spectrometric data obtained for poly(ethylene oxide), polystyrene and poly(butylacrylate). 相似文献
563.
Oraphin Chaikumpollert Yoshimasa Yamamoto Krisda Suchiva Phan Trung Nghia Seiichi Kawahara 《先进技术聚合物》2012,23(4):825-828
Protein‐free natural rubber was prepared by incubation of natural rubber latex with urea and polar organic solvent in the presence of surfactant. Effect of the polar organic solvent on the removal of the proteins was investigated with respect to chemical affinity and concentration of the solvents. Under a suitable condition, nitrogen content of the deproteinized natural rubber (DPNR) was 0.000 wt%, which was less than that of natural rubber deproteinized with proteolytic enzyme or urea in the presence of surfactant. The removal of all proteins from natural rubber was proved through FT‐IR spectroscopy. Changes in morphology of the DPNR were also investigated by transmission electron microscopy. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
564.
In this paper we develop new extremal principles in variational analysis that deal with finite and infinite systems of convex and nonconvex sets. The results obtained, unified under the name of tangential extremal principles, combine primal and dual approaches to the study of variational systems being in fact first extremal principles applied to infinite systems of sets. The first part of the paper concerns the basic theory of tangential extremal principles while the second part presents applications to problems of semi-infinite programming and multiobjective optimization. 相似文献
565.
Tuoc Van Phan 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2012,4(1):395-400
Let Ω be an open, bounded domain in
\mathbbRn (n ? \mathbbN){\mathbb{R}^n\;(n \in \mathbb{N})} with smooth boundary ∂Ω. Let p, q, r, d
1, τ be positive real numbers and s be a non-negative number which satisfies
0 < \fracp-1r < \fracqs+1{0 < \frac{p-1}{r} < \frac{q}{s+1}}. We consider the shadow system of the well-known Gierer–Meinhardt system:
$ \left \{ {l@{\quad}l} \displaystyle{u_t = d_1\Delta u - u + \frac{u^p}{\xi^q}}, & \quad {\rm in}\;\Omega \times (0,T), \\ \displaystyle{\tau \xi_t = -\xi + \frac{1}{|\Omega|} \int\nolimits_\Omega\frac{u^r}{\xi^s} {\rm d}x}, & \quad {\rm in}\;(0,T), \\ \displaystyle{\frac{\partial u}{\partial \nu} =0}, & \quad {\rm on}\;\partial \Omega \times (0,T), \\ \displaystyle{\xi(0) = \xi_0 >0 , \quad u(\cdot,0) = u_0(\cdot)} \geq 0 & \quad {\rm in}\;\Omega. \right. $ \left \{ \begin{array}{l@{\quad}l} \displaystyle{u_t = d_1\Delta u - u + \frac{u^p}{\xi^q}}, & \quad {\rm in}\;\Omega \times (0,T), \\ \displaystyle{\tau \xi_t = -\xi + \frac{1}{|\Omega|} \int\nolimits_\Omega\frac{u^r}{\xi^s} {\rm d}x}, & \quad {\rm in}\;(0,T), \\ \displaystyle{\frac{\partial u}{\partial \nu} =0}, & \quad {\rm on}\;\partial \Omega \times (0,T), \\ \displaystyle{\xi(0) = \xi_0 >0 , \quad u(\cdot,0) = u_0(\cdot)} \geq 0 & \quad {\rm in}\;\Omega. \end{array} \right. 相似文献
566.
567.
Phan T. Nam 《Applied mathematics and computation》2009,214(2):374-380
Exponential stability of time-delay systems with nonlinear uncertainties is studied in this paper. Based on the Lyapunov method and the approaches of decomposing the matrix, a new exponential stability criterion is derived in terms of a matrix inequality, which allows to compute simultaneously the two bounds that characterize the exponential nature of the solution. Some numerical examples are also given to show the superiority of our result to those in the literature. 相似文献
568.
We report a systematic study of the influence of Nb substitution for Fe on the magnetic properties and magneto-impedance (MI) effect in amorphous and annealed Fe76.5−xSi13.5B9Cu1Nbx (x=0, 1, 2, 3, 4, 5, 6, and 7) ribbons. The amorphous ribbons were annealed at different temperatures ranging from 530 to 560 °C in vacuum for different annealing times between 5 and 20 min. We have found that for the as-quenched amorphous ribbons, the substitution of Nb for Fe first increases the saturation magnetization (Ms) and decreases the coercivity (Hc) until x=3, for which the largest Ms∼152 emu/g and the smallest Hc∼1.3 Oe are obtained, then an opposite trend is found for x>3. The largest MI ratio (ΔZ/Z∼38% at f=6 MHz) is achieved in the amorphous ribbon with x=3. A similar trend has been observed for the annealed ribbons. The most desirable magnetic properties (Ms∼156 emu/g and Hc∼1.8 Oe) and the largest MI ratio (ΔZ/Z∼221% at f=6 MHz) are achieved for the x=3 sample annealed at 540 °C for 15 min. A correlation between the microstructure, magnetic properties, and MI effect in the annealed ribbons has been established. 相似文献
569.
Dr. Vee Vee Cheong Dr. Christopher Jacques Lech Dr. Brahim Heddi Prof. Dr. Anh Tuân Phan 《Angewandte Chemie (International ed. in English)》2016,55(1):160-163
G‐quadruplexes are four‐stranded nucleic acid structures that are built from consecutively stacked guanine tetrad (G‐tetrad) assemblies. The simultaneous incorporation of two guanine base lesions, xanthine (X) and 8‐oxoguanine (O), within a single G‐tetrad of a G‐quadruplex was recently shown to lead to the formation of a stable G?G?X?O tetrad. Herein, a judicious introduction of X and O into a human telomeric G‐quadruplex‐forming sequence is shown to reverse the hydrogen‐bond polarity of the modified G‐tetrad while preserving the original folding topology. The control exerted over G‐tetrad polarity by joint X?O modification will be valuable for the design and programming of G‐quadruplex structures and their properties. 相似文献
570.
Shaofei Wu Minchan Li Dr. Hoa Phan Dingguan Wang Dr. Tun Seng Herng Prof. Jun Ding Prof. Zhouguang Lu Prof. Jishan Wu 《Angewandte Chemie (International ed. in English)》2018,57(27):8007-8011
Reported is the synthesis, characterization, and material properties of the first π‐conjugated two‐dimensional covalent organic radical framework (CORF), PTM‐CORF , based on the stable polychlorotriphenylmethyl (PTM) radical. The covalent organic framework (COF) precursor ( PTM‐H‐COF ) was first synthesized by liquid/liquid interfacial acetylenic homocoupling of a triethynylpolychlorotriphenylmethane monomer, and showed crystalline features with a hexagonal diffraction pattern matching that of A‐B‐C stacking. Subsequent deprotonation and oxidation of the PTM units in PTM‐H‐COF gave PTM‐CORF . Magnetic measurements revealed that the neighboring PTM radicals in the PTM‐CORF are anti‐ferromagnetically coupled each other, with a moderate exchange interaction (J=?375 cm?1). The PTM‐CORF has a small energy gap (ca. 0.88 eV) and a low‐lying LUMO energy level (?4.72 eV), and exhibits high electrocatalytic activity and durability toward the oxygen reduction reaction. 相似文献
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