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51.
Tiantian Si Lei Liu Xiaojing Liang Huixiao Duo Licheng Wang Shuai Wang 《Journal of separation science》2019,42(12):2148-2154
A zirconium(IV)‐based metal–organic framework material (MOF‐808) has been synthesized in a simple way and used for the extraction of phenoxyacetic acids in complex samples. The material has good thermal and chemical stability, large specific surface area (905.36 m²/g), and high pore size (22.18 Å). Besides, it contains a large amount of Zr‐O groups, easy‐to‐form Zr‐O‐H bond with carboxyl groups of phenoxyacetic acids, and possesses biphenyl skeleton structure, easy to interact with compounds through π‐π and hydrophobic interactions. These characteristics make the material very suitable for the extraction of certain compounds with a high extraction efficiency and excellent selectivity. The extraction conditions were optimized, and then an analytical method was successfully established and applied for analysis of actual samples. The solid‐phase extraction method based on prepared material had a wide linear range of 0.2–250 μg/L and a low detection limit of 0.1–0.5 μg/L for four phenoxyacetic acid compounds including 2,4‐dichlorophenoxyacetic acid, 2‐(2,4‐dichlorophenoxy) propionic acid, 4‐chlorophenoxyacetic acid, and dicamba. The relative standard deviations of intra‐ and interday precision were 1.8–3.8 and 4.3–6.9%, and the recoveries after spiking were between 77.1 and 109.3%. The results showed that the material is a desired substituent for the extraction of compounds with benzene ring structure containing carboxyl groups. 相似文献
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Further reduction for classical normal forms of formal maps is considered in this note. Based on a recursive formula for computing the transformed map of a formal map under a near identity formal transformation, we develop the concepts of Nth order normal forms and infinite order normal forms for formal maps, and give some sufficient conditions for uniqueness of normal forms of formal maps. To cite this article: D. Wang et al., C. R. Acad. Sci. Paris, Ser. I 343 (2006). 相似文献
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In this paper, a three-species food chain model with Holling type IV and Beddington–DeAngelis functional responses is formulated. Numerical simulations show that this system can generate chaos for some parameter values. But the mechanism behind chaos is still unclear only through numerical simulations. Then, using the topological horseshoe theories and Conley–Moser conditions, we present a computer-assisted analysis to show the chaoticity of this system in the topological sense, that is, it has positive topological entropy. We prove that the Poincaré map of this model possesses a closed uniformly hyperbolic chaotic invariant set, and it is topologically conjugate to a 2-shift map. At last, we consider the impact of fear on this three-species model. It is an important factor in controlling chaos in biological models, which has been validated in other models. 相似文献
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Weimin Hou Li Chen Maoyou Yang Mingjian Zhang Junmei Wang Jiakuo Shi Shuo Su Duo Zhang Hongping Wu 《Annalen der Physik》2023,535(7):2300061
Based on the first-principles calculation, the effect of intercalated LiF on the contact characteristics of the interface between Au electrode and MoS2 layer is studied. It is found that adding LiF film can change the contact type between metal electrode Au and MoS2 layer from Schottky contact to ohmic contact, which is accompanied by interfacial charge transfer from LiF layer to MoS2 layer and the downward movement of d (dxy and dz2) orbital of Mo atom and p (px and py) orbital of S atom to Fermi level. And the interlayer spacing between LiF layer and Au electrode has a great impact on the interface contact characteristics. The electric field effect and stress effect of interface contact of Au, LiF and MoS2 (Au/LiF/MoS2)is more obvious than that of interface contact of Au and MoS2 (Au/MoS2). Au/LiF/MoS2 shows ohmic contact with the interlayer spacing between Au layer and LiF layer less than 3.05 Å and with the electric field less than 0.15 VÅ−1, respectively, while Au/MoS2 still shows N-type Schottky contact. These findings are helpful to control the contact resistance and have guiding significance for high performance MoS2 field effect transistor and other electronic components. 相似文献
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Optical Review - Quantum dot-converted LEDs (QCLEDs) are a new type of LED device. However, the low luminous efficiency of the QCLED cannot meet the requirements for practical applications. In this... 相似文献
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沟谷坡面风沙起动规律研究 总被引:3,自引:0,他引:3
根据坡面风沙受力情况,以滚动模式建立了坡面风沙起动的风速公式.计算分析了相同风向条件下不同坡度风沙的起动风速和相同坡度条件下不同风向风沙的起动风速,并与平面风沙起动计算风速和实测风速进行了比较.计算分析表明,在风向一定时,坡面风沙更容易起动,风沙起动速率随着坡度的变陡而变小.在坡度一定时,风沙起动风速受到风向的影响很大,起动风速随风力与水平面垂线夹角的增大而增大.与平面相比,当风力与水平面垂线夹角小于90°时,坡面风沙起动流速比平面为小.在当风力与水平面垂线夹角大于90°时,起动风速比平面为大.当坡面为平面时,风沙起动公式与平面拜格诺起动公式完全一致. 相似文献
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Steady-state response of a binon-linear hysteretic system 总被引:1,自引:0,他引:1
The steady-state responses are analyzed for a binon-linear hysteretic system using the method of slowly varying parameters. It is shown that the triple-valued and quintuple-valued response curves exist in this system in certain parameter ranges. The stability is studied for the steady-state responses. The results obtained show that the unstable region of response is divided into two regions in certain parameter range, and the distance between the two regions goes to infinity as the value of non-linearity parameter goes to zero. 相似文献