加油站附近绿色植物中铅含量的测定

研究了HNO3，H2O2，HClO4体系中溶解绿色植物的最佳条件，在石墨炉原子分光光度计上测定了样液中的铅含量。发现距离加油站越近的地方绿色植物中的铅含量越高；在500m以外铅含量稳定，污染可以忽略不计。     

用ICCD作光开关测量储存环中光学速调管谐波超辐射

 用高通断比ICCD作为快速光开关,在中国科学技术大学的800MeV电子储存环上建造了一套光学速调管谐波超辐射测量系统,从每隔106个自发辐射脉冲1个谐波超辐射脉冲所形成的脉冲链里选出超辐射脉冲,测量谐波辐射的相干增强因子和谱宽。     

IgA肾病免疫吸附剂的研究(Ⅱ)

通过1,4-丁二醇-二缩水甘油醚法活化琼脂糖载体,既起到了活化载体的作用,同时又由于该活化剂分子是长链结构而给载体提供了一定长度的手臂,有利于人免疫球蛋白G(IgG)大分子配基与载体的连接,用该方法制成的免疫吸附剂对高IgA肾病病人血清中IgA进行了吸附研究.通过体外实验条件的优化发现,最高可吸附60%的IgA,同CDI法比较(吸附率可达35%左右),该吸附剂具有较高的吸附效率.     

循环伏安法测定维生素B6

循环伏安法测定维生素B6;多壁碳纳米管;修饰玻碳电极;循环伏安法     

Hydrophilic Quaternary Ammonium‐Group‐Containing [FeFe]‐Hydrogenase Models: Synthesis,Structures, and Electrocatalytic Hydrogen Production

The first quaternary ammonium‐group‐containing [FeFe]‐hydrogenase models [(μ‐PDT)Fe₂(CO)₄{κ²‐(Ph₂P)₂N(CH₂)₂NMe₂BzBr}] ( 2 ; PDT=propanedithiolate) and [(μ‐PDT)Fe₂(CO)₄{μ‐(Ph₂P)₂N(CH₂)₂NMe₂BzBr}] ( 4 ) have been prepared by the quaternization of their precursors [(μ‐PDT)Fe₂(CO)₄{κ²‐(Ph₂P)₂N(CH₂)₂NMe₂}] ( 1 ) and [(μ‐PDT)Fe₂(CO)₄{μ‐(Ph₂P)₂N(CH₂)₂NMe₂}] ( 3 ) with benzyl bromide in high yields. Although new complexes 1 – 4 have been fully characterized by spectroscopic and X‐ray crystallographic studies, the chelated complexes 1 and 2 converted into their bridged isomers 3 and 4 at higher temperatures, thus demonstrating that these bridged isomers are thermodynamically favorable. An electrochemical study on hydrophilic models 2 and 4 in MeCN and MeCN/H₂O as solvents indicates that the reduction potentials are shifted to less‐negative potentials as the water content increases. This outcome implies that both 2 and 4 are more easily reduced in the mixed MeCN/H₂O solvent than in MeCN. In addition, hydrophilic models 2 and 4 act as electrocatalysts and achieve higher i_cat/i_p values and turnover numbers (TONs) in MeCN/H₂O as a solvent than in MeCN for the production of hydrogen from the weak acid HOAc.     

延性材料的动态崩落研究

采用Ｇｒａｄｙ发展的一种动态崩落的一般描述方法，考虑了Ｈｅｒｔｚｂｅｒｇ对崩落过程的塑性修正，借助于不同的基体材料的等效应力假定，给出了考虑粘性（应变率）效应的强冲击载荷下延性材料的动态崩落尺寸与孔隙度的定量关系。这对动态断裂的细观描述提供了一个新的途径。     

DYNAMIC ANALYSIS OF A BURIED RIGID ELLIPTIC CYLINDER PARTIALLY DEBONDED FROM SURROUNDING MATRIX UNDER SHEAR WAVES

This paper investigates the dynamic behavior of a buried rigid ellipticcylinder partially debonded from surrounding matrix under the action of anti-planeshear waves (SH waves). The debonding region is modeled as an elliptic arc-shapedinterface crack with non-contacting faces. By using the wave function (Mathieufunction) expansion method and introducing the dislocation density function as anunknown variable, the problem is reduced to a singular integral equation which issolved numerically to calculate the near and far fields of the problem. The resonanceof the structure and the effects of various parameters on the resonance are discussed.     

P波对界面部分脱胶的刚性圆柱夹杂物的散射

本文求解了弹性Ｐ波对界面部分脱胶的可动刚性圆柱夹杂物的散射问题。将脱胶区看作表面不相接触的弧形界面裂纹，借助波函数展开法并利用边界条件将问题转化为一组对偶级数方程。然后通过引入裂纹面的位错密度函数，将其化为一组具有Ｈｉｌｂｅｒｔ核的第二类奇异积分方程，并进一步化为Ｃａｕｃｈｙ型奇异积分方程组，数值求解方程组可获得动应力强度因子，夹杂物刚体振动位移和散射截面等重要参量。结果显示该类结构在较低的频率上发生共振，此低频共振特性与脱胶区大小，入射波方向、材料组合等多种参数有关。与已有方法相比，本文的方法更具一般性，适用于任意材料组合。     

爆炸变形战斗部模型试验研究

测量了爆炸变形战斗部模型的破片密度和初速分布 ,得到了辅助装药爆炸驱动壳体变形的过程的X光照片。结果表明 ,与相同尺寸的柱形战斗部相比 ,爆炸变形战斗部飞向目标的破片不仅密度大幅度地增加 ,而且初速也有一定程度的提高 ,从而增强了战斗部对目标的毁伤能力。     

双材料间界面断裂分析的广义界面层模型

给出了双材料间界面层区域的广义模型，并对承受扭转载荷的界面间硬币形裂纹进行了分析与计算．通过处理奇异积分方程得到了应力强度因子，数值结果给出了材料特性、界面层厚度、尤其是分布特征参数ｋ对应力强度因子的影响．与Ｅｒｄｏｇａｎ界面层模型的结果比较表明，本文的模型更具有一般性．