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121.
Chen Shifeng Wei Xuebin Liu Jinhui Sun Zhanxue Chen Gongxin Yang Mei Liu Yuanyuan Wang Duo Ma Chengcui Kong Dexuan 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2583-2596
Journal of Radioanalytical and Nuclear Chemistry - Mineralogical study showed that the Yuejin uranium ore is from a low grade, high carbonate and high pyrite sandstone type uranium deposit. Uranium... 相似文献
122.
利用水热合成法制备了一种基于[Cu(en)2]2+修饰的仲钨酸化合物:[{Na3(H2O)10}2H2{Cu(en)2(H2W12O42)}].16H2O(en=乙二胺)(1),借助元素分析、X射线单晶衍射分析I、R、UV、热分析和X射线光电子能谱对这种化合物进行了结构和性质研究.化合物(1)属于三斜晶系,P-1空间群.晶胞参数为:a=1.183 2(5)nm,b=1.296 0(6)nm,c=1.416 9(6)nm,α=63.348 0(10)°,β=82.844 0(10)°,γ=68.907 0(10)°,V=1.810 0(14)nm3,Z=1,R1[I2σ(I)]=0.024 7,wR2[I2σ(I)]=0.058 2.化合物(1)通过仲钨酸阴离子,铜离子和[Na3(H2O)10]3+三核簇形成了新型的二维层状结构. 相似文献
123.
Zhou W Liu H Wang J Liu D Du G Han S Lin J Wang R 《Physical chemistry chemical physics : PCCP》2010,12(45):15119-15123
Electrostatic self-assembled Ag(2)O/TiO(2) nanobelts heterostructure was synthesized via simple physical mixing of Ag(2)O nanoparticles and TiO(2) nanobelts. The morphologies and microstructures of Ag(2)O/TiO(2) nanobelt heterostructure were characterized by high resolution transmission electron microscopy. The interface dominated high UV photocatalytic activity and degraded photoluminescence strength of composite catalyst confirmed the heterostructure effect between Ag(2)O nanoparticles and TiO(2) nanobelts. X-ray photoelectron spectroscope provided direct evidence of charge transfer on the heterostructures between them. 相似文献
124.
In this paper,a sidelobe suppression method using nonuniformly spaced array with aperture apodization processing is proposed for underwater acoustic imaging in near field,which is studied both in theory and experiment.The focused beamforming based on spherical wave propagation theory is used in the method.Firstly,the nonuniform array with low sidelobe is designed for suppressing the sidelobe of one-way beam pattern by spacing perturbation.Then, applying the aperture apodization technique to underwater acoustic imaging,the different size apertures for transmitting and receiving are used for further suppressing the sidelobe of two-way beam pattern.The experimental results from water tank show that the proposed method can suppress the sidelobe more effectively only with fractional mainlobe width increase.Since the method is simple-realized,the imaging system can be simplified as well as achieving improved performance. 相似文献
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Krow GR Lester WS Liu N Yuan J Hiller A Duo J Herzon SB Nguyen Y Cannon K 《The Journal of organic chemistry》2001,66(5):1811-1817
Methyl- and phenyl-substituted N-(ethoxycarbonyl)-2-azabicyclo[2.2.0]hex-5-enes 6 were reacted with NBS in wet DMSO to afford bromohydrins. Mixtures of unrearranged 6-exo-bromo-5-endo-hydroxy-2-azabicyclo[2.2.0]hexanes 7a,b and rearranged 5-anti-bromo-6-anti-hydroxy-2-azabicyclo[2.1.1]hexanes 8a,b were formed stereoselectively from the parent alkene 6a and 4-methyl alkene 6b. The 5-methyl alkene 6c affords only unrearranged bromohydrin 7c and dibromohydrin 9. By contrast, solely rearranged 3-endo-substituted-2-azabicyclo[2.1.1]hexane bromohydrins 8d-f result from additions to 3-endo-methyl alkene 6d, 3-endo-4-dimethyl alkene 6e, and 3-endo-phenyl alkene 6f. As an alternative route to bromohydrins, the parent 5,6-exo-epoxide 10a and 5-endo-methyl-5,6-exo-epoxide 10b were ring opened with bromine/triphenylphosphine to afford unrearranged 5-endo-bromo-6-exo-hydroxy-2-azabicyclo[2.2.0]hexanes 11a,b, while the 3-endo-methyl epoxide 10c afforded solely the rearranged 5-anti-bromo-6-anti-hydroxy-3-exo-methyl-2-azabicyclo[2.1.1]hexane isomer 8g. Tributyltin hydride reduction of bromohydrins 7a,b and 11a afforded novel 2-azabicyclo[2.2.0]hexan-5-ols 13a,b and -6-ol 14, and bromohydrins 8a,b, 8d-g afforded new 2-azabicyclo[2.1.1]-hexan-5-ols 15a,b and 15d-g. 相似文献
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Xin Qiang Wang Wen Tao Yu Dong Xu Meng Kai Lu Duo Rong Yuan 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(1):m36-m38
The title complex, [MnHg(SCN)4(CH4N2O)3]n, consists of slightly distorted octahedral MnN3O3 and tetrahedral HgS4 units. The MnII atom is coordinated by the O atoms of three urea molecules and by the N atoms of three SCN? ions; HgII is coordinated by four S atoms from SCN? ions. Each pair of MnII and HgII atoms is connected by an –SCN– bridge, forming infinite two‐dimensional –Mn—NCS—Hg– networks. 相似文献