首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   294篇
  免费   11篇
  国内免费   1篇
化学   199篇
晶体学   1篇
力学   7篇
数学   43篇
物理学   56篇
  2023年   1篇
  2022年   3篇
  2021年   8篇
  2020年   7篇
  2019年   4篇
  2018年   2篇
  2017年   6篇
  2016年   6篇
  2015年   8篇
  2014年   5篇
  2013年   20篇
  2012年   18篇
  2011年   16篇
  2010年   13篇
  2009年   10篇
  2008年   16篇
  2007年   13篇
  2006年   20篇
  2005年   15篇
  2004年   14篇
  2003年   8篇
  2002年   9篇
  2001年   2篇
  2000年   3篇
  1999年   5篇
  1998年   1篇
  1997年   3篇
  1996年   6篇
  1995年   2篇
  1994年   1篇
  1993年   4篇
  1992年   6篇
  1991年   3篇
  1990年   6篇
  1989年   2篇
  1988年   2篇
  1987年   6篇
  1986年   2篇
  1985年   4篇
  1984年   4篇
  1983年   5篇
  1982年   1篇
  1981年   2篇
  1980年   3篇
  1979年   5篇
  1978年   1篇
  1977年   1篇
  1975年   1篇
  1972年   1篇
  1966年   2篇
排序方式: 共有306条查询结果,搜索用时 15 毫秒
31.
A series of 4-hydroxy-2H-1,2-benzothiazme-3-carboxamide 1,1-dioxides substituted on the sulfonamide nitrogen with ethoxycarbonylalkyl, cyanoalkyl and dialkylaminoalkyl groups was synthesized. Spectroscopic properties of the obtained products were analyzed. Findings from the pharmacological study of some of the compounds as antiinflammatory and analgesic agents are reported.  相似文献   
32.
We investigated the self‐aggregation of 12 short ionic oligopeptides constituted by 4–7 amino acid residues to establish useful structure–property relationships that might be exploited in the biomedical field by using the concept of molecular Lego. We show that the critical aggregation concentration (CAC) of tetrapeptides decreases with increasing hydrophobicity of neutral residues. Additionally, the dependence of the CAC of isomeric oligopeptides on the distribution of amino acid residues confirms the high tendency to self‐organization of molecules with alternating ionic and neutral residues. Indeed, atomic force microscopy (AFM) images recorded on oligopeptide solutions above the CAC show the presence of either fibrillar or spherical aggregates depending on oligopeptide structure and concentration, steric hindrance, solution pH, and time. The potential of the investigated oligopeptides in tissue engineering applications is supported by their in vitro cytocompatibility. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 889–897, 2010  相似文献   
33.
34.
35.
The crystal structure and crystallization behavior of a series of poly(ester amide)s derived from L ‐tartaric acid, 1,6‐hexanediamine, and 6‐amino‐1‐hexanol were examined. The study included aregic polymers containing 5, 10, and 20% of ester groups in addition to the syndioregic polymer containing equal amounts of amide and ester groups. X‐ray diffraction data revealed that all the aregic poly(ester amide)s adopt the same crystal structure as the parent polyamide made of L ‐tartaric acid, and 1,6‐hexanediamine. In this structure, chains are slightly compressed and arranged as in the α‐form of nylon 66. Solid‐state nuclear magnetic resonance (NMR) revealed that ester groups are excluded from the crystal phase except for the case of the syndioregic polymer. Isothermal crystallization kinetics was analyzed according to the Avrami theory. Crystallization rates were found to decrease regularly with increasing contents in ester groups and with increasing crystallization temperature. Avrami exponent values close to 2 were found whereas spherulitic morphologies were observed by optical microscopy. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 116–125, 2007  相似文献   
36.
Chiral 2-acyl-3-allyl-perhydro-1,3-benzoxazines derived from (−)-8-aminomenthol were easily cyclized in the presence of Lewis acids at 0 °C. The diastereoselectivity of the cyclization was dependent on the nature of the Lewis acid. The cyclization compounds can be transformed into enantiopure cis-3,4-disubstituted 3-hydroxypyrrolidines by ring opening of the N,O-acetal moiety and subsequent elimination of the menthol appendage.  相似文献   
37.
As a result of the increased focus on data literacy and data science across the world, there has been a large demand for professional development in statistics. However, exactly how these professional development opportunities should be structured remains an open question. The purpose of this paper is to describe the first iteration of a design experiment involving Project-SET (www.project-set.com) professional development program. Project-SET provided professional development to enhance teachers’ understanding of statistics concepts. The project constructed two learning trajectories for teacher learning and subsequently used the learning trajectories to structure the professional development curriculum. The main goal of this paper is to illustrate how the utilization of the teacher-learning trajectories to structure the professional development allowed participating teachers to develop several aspects of Statistics Knowledge for Teaching (Groth, 2013).  相似文献   
38.
This is the second of a sequence of papers devoted to applying the localized adjoint method (LAM), in space-time, to problems of advective-diffusive transport. We refer to the resulting methodology as the Eulerian-Lagrangian localized adjoint method (ELLAM). The ELLAM approach yields a general formulation that subsumes many specific methods based on combined Lagrangian and Eulerian approaches, so-called characteristic methods (CM). In the first paper of this series the emphasis was placed in the numerical implementation and a careful treatment of implementation of boundary conditions was presented for one-dimensional problems. The final ELLAM approximation was shown to possess the conservation of mass property, unlike typical characteristic methods. The emphasis of the present paper is on the theoretical aspects of the method. The theory, based on Herrera's algebraic theory of boundary value problems, is presented for advection-diffusion equations in both one-dimensional and multidimensional systems. This provides a generalized ELLAM formulation. The generality of the method is also demonstrated by a treatment of systems of equations as well as a derivation of mixed methods. © 1993 John Wiley & Sons, Inc.  相似文献   
39.
The reactions of saccharin derivatives 1 with sodium alkoxides were studied. Under mild conditions, compounds 1a-f gave the corresponding open sulfonamides 5a-f . Under drastic conditions, β-(saccharin-2)propionic acid derivatives 1a,b reacted with sodium ethoxide affording saccharin and β-ethoxypropionic acid derivatives 4a,b . γ-(Saccharin-2)butyric acid derivatives 1c,d and γ-(saccharin-2)-butyrophenone 1f reacted with sodium t-butoxide in dimethyl sulfoxide affording 5-substituted 6-hydroxy-3,4-dihydro-2H-1,2-benzothiazocine 1,1-dioxides 9 . From mother liquors, 1-substituted 2,3-dihydro-pyrrolo[1,2-b][1,2]benzisothiazole 5,5-dioxides 10 were isolated several hours later, though not detected immediately after completing the reaction. When the reactions were carried out in t-butyl alcohol, the yields of 9 diminished and those of 10 increased with product ratio inversion. Different experimental observations on the possible pathway generating 9 and 10 are discussed.  相似文献   
40.
The algebraic theory for numerical methods, as developed by Herrera [3–7], provides a broad theoretical framework for the development and analysis of numerical approximations. To this point, the technique has only been applied to ordinary differential equations with constant coefficients. The present work extends the theory by developing a methodology for equations with variable coefficients. Approximation of the coefficients by piecewise polynomials forms the foundation of the approach. Analysis of the method provides firm error estimates. Furthermore, the analysis points to particular procedures that produce optimal accuracy. Example calculations illustrate the computational procedure and verify the theoretical convergence rates.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号