A method for simultaneously determining the zeta potentials of the channel surface and the tracer particles using microparticle image velocimetry technique

The zeta potentials of channel surfaces and tracer particles are of importance to the design of electrokinetic microfluidic devices, the characterization of channel materials, and the quantification of the microparticle image velocimetry (microPIV) measurement of EOFs. A method is proposed to simultaneously measure the zeta potentials of the channel surface and the tracer particles in aqueous solutions using the microPIV technique. Through the measurement of the steady velocity distributions of the tracer particles in both open- and closed-end rectangular microchannels under the same water chemistry condition, the electrophoretic velocity of the tracer particles and the EOF field of the microchannel are determined using the expressions derived in this study for the velocity distributions of charged tracer particles in the open- and closed-end rectangular microchannels. Thus, the zeta potentials of the tracer particles and the channel surfaces are simultaneously obtained using the least-square method to fit the microPIV measured velocity distribution of the tracer particles. Measurements were carried out with a microPIV system to determine the zeta potentials of the channel wall and the fluorescent tracer particles in deionized water and sodium chloride and boric acid solutions of various concentrations.     

Frustrated structure of an anticlinic-like smectic-C phase

We present a polarising optical microscopy study of the low-temperature anticlinic-like tilted mesophase of the liquid-crystal compound octylphenyl-2-chloro-4-(p-cyano-benzoyloxy) (DB₈Cl). This mesophase has been described as a bilayer smectic structure in which the molecules within each layer are organised in an anticlinic way. The optical textures observed in samples with planar orientation show a double stripe pattern, with the lines aligned parallel to the rubbing direction, characteristic of a double periodic modulation of the refractive index of the material. The long-period modulation is temperature dependent and disappears for thin sample cells (< 5μm). The short-period modulation is nearly independent of the thickness of the cells. The experimental results are analysed in terms of a model which considers that there is a special distribution of the principal optical axis which may be in or out of the polariser-analyser plane. The observed periodic variation of the principal optical axis could not be interpreted in terms of the original structure proposed for this phase. DB₈Cl presents a structure formed by dimers that can be viewed as flexible bent-core-like molecules, showing similarities with phases found in banana-like systems, but exhibiting a much more complex structure.     

Long-Time Stability of Multi-Dimensional Noncharacteristic Viscous Boundary Layers

We establish long-time stability of multi-dimensional noncharacteristic boundary layers of a class of hyperbolic–parabolic systems including the compressible Navier–Stokes equations with inflow [outflow] boundary conditions, under the assumption of strong spectral, or uniform Evans, stability. Evans stability has been verified for small-amplitude layers by Guès, Métivier, Williams, and Zumbrun. For large-amplitude layers, it may be efficiently checked numerically, as done in the one-dimensional case by Costanzino, Humpherys, Nguyen, and Zumbrun.     

Material force method: theoretical and numerical aspects in nonlinear electro-elastostatics

Formulations of the spatial and material motion problem in nonlinear electroelastostatics are considered in this work by a virtual work approach. Based on these formulations, a finite element discretization is realized and a numerical example is presented to demonstrate possible uses of the material force method in studying the closing process of cracks. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

POLAR project: Numerical modeling of the accretion column

In this paper we study the formation and evolution of radiative accretion shocks in the context of accretion columns in magnetic cataclysmic variables. The phenomenon induces extreme regimes of matter and the radiation emitted by those region dominates the observed emission from polars. A 2D hydrodynamical code, HYDRO-COOL, has been developed in order to deal with high-Mach number flows and is currently improved to produce a numerical model of the accretion column. This code is the hydrodynamical part of the HADES code which aims at modeling radiative hydrodynamical systems. The final goal of this model is to improve our understanding of observational results. First numerical results are reported here, as well as a discussion about the time-dependent evolution of the column.     

Exact buckling solution for two-layer Timoshenko beams with interlayer slip

This paper deals with the buckling behavior of two-layer shear-deformable beams with partial interaction. The Timoshenko kinematic hypotheses are considered for both layers and the shear connection (no uplift is permitted) is represented by a continuous relationship between the interface shear flow and the corresponding slip. A set of differential equations is obtained from a general 3D bifurcation analysis, using the above assumptions. Original closed-form analytical solutions of the buckling load and mode of the composite beam under axial compression are derived for various boundary conditions. The new expressions of the critical loads are shown to be consistent with the ones corresponding to the Euler–Bernoulli beam theory, when transverse shear stiffnesses go to infinity. The proposed analytical formulae are validated using 2D finite element computations. Parametric analyses are performed, especially including the limiting cases of perfect bond and no bond. The effect of shear flexibility is particularly emphasized.     

PIV measurements of an air jet impinging on an open rotor-stator system

The current work experimentally investigates the flow characteristics of an air jet impinging on an open rotor-stator system with a low non-dimensional spacing, G?=?0.02, and with a very low aspect ratio, e/D?=?0.25. The rotational Reynolds numbers varied from $0.33\times10^5$ to $5.32\times10^5$ , while the jet Reynolds numbers ranged from 17.2?×?10³ to 43?×?10³. Particle image velocimetry (PIV) measurements were taken along the entire disk diameter in three axial planes. From the obtained PIV velocity fields, the flow statistics were computed. A recirculation flow region, which was centered at the impingement point and possessed high turbulence intensities, was observed. Local peaks in root-mean-square fluctuating velocity distributions appeared in the recirculation region and near the periphery, respectively. Proper orthogonal decomposition analysis was applied to the cases of the jet impinging on the rotor with and without rotation to reveal the coherent structures in the jet region.     

Porous monoliths consisting of aluminum oxyhydroxide nanofibrils: 3D structure,chemical composition,and phase transformations in the temperature range 25–1700 °C

We present a study on the chemical and structural transformations in highly porous monolitic materials consisting of the nanofibrils of aluminum oxyhydroxides (NOA, Al₂O₃·nH₂O) in the temperature range 20–1700 °C. A remarkable property of the NOA material is the preservation of the monolithic state during annealing over the entire temperature range, although the density of the monolith increases from ~0.02 up to ~3 g/cm³, the total porosity decreases from 99.3 to 25% and remains open up to 4 h annealing at the temperature ~1300 °C. The physical parameters of NOA monoliths such as density, porosity, specific area were studied and a simple physical model describing these parameters as the function of the average size of NOA fibrils—the basic element of 3D structure—was proposed. The observed thermally induced changes in composition and structure of NOA were successfully described and two mechanisms of mass transport in NOA materials were revealed. (i) At moderate temperatures (T?≤?800 °C), the mass transport occurs along a surface of amorphous single fibril, which results in a weak decrease of the length-to-diameter aspect ratio from the initial value ~24 till ~20; the corresponding NOA porosity change is also small: from initial ~99.5 to 98.5%. (ii) At high temperatures (T >?800 °C), the mass transport occurs in the volume of fibrils, that results in changes of fibrils shape to elliptical and strong decrease of the aspect ratio down to ≤?2; the porosity of NOA decreases to 25%. These two regimes are characterized by activation energies of 28 and 61 kJ/mol respectively, and the transition temperature corresponds to the beginning of γ-phase crystallization at 870 °C.

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A comparative study on the morphology of P3HT:PCBM solar cells with the addition of Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> nanoparticles by spin and rod coating methods

Our previous study presented up to 20% power conversion efficiency (PCE) enhancement of poly(3-hexylthiophene):phenyl-C₆₁-butyric acid methyl ester (P3HT:PCBM) solar cells under the Fe₃O₄ nanoparticles (NPs) self-assembly (SA) effect by spin coating. Fe₃O₄ NPs (about 11 nm hydrodynamic diameter) form a thin layer at the top interface of the light absorbing active layer, which results in the generation of PCBM rich region improving the charge transport (Zhang et al. Sol Energ Mat Sol C 160:126–133, 2017). In order to investigate the feasibility of this Fe₃O₄ NPs SA effect under large-scale production condition, a smooth rod was implemented to mimic roll-to-roll coating technique and yield active layers having about the same thickness as the spin-coated ones. Small angle neutron scattering and grazing incidence X-ray diffraction were employed finding out similar morphologies of the active layers by these two coating techniques. However, rod-coated solar cell’s PCE decreases with the addition of Fe₃O₄ NPs compared with the one without them. This is because PCBM rich region is not created at the top interface of the active layer due to the absence of Fe₃O₄ NPs, which is attributed to the weak convective flow and low diffusion rate. Moreover, in the rod-coated solar cells, the presence of Fe₃O₄ NPs causes decrease in P3HT crystallinity, thus the charge transport and the device performance. Our study confirms the role of spin coating in the Fe₃O₄ NPs SA effect and enables researchers to explore this finding in other polymer nanocomposite systems.     

Pressure effects on the thermodynamic and mechanical properties of zinc-blende ZnTe compound

In this paper, the moment method in statistical mechanics has been employed to study the pressure effects on thermodynamic and mechanical properties of zinc-blende zinc telluride using many-body potential. We have derived the analytical expressions of the pressure-dependent lattice parameter, volume compression as well as mean-square displacement of zinc-blende type compound. Numerical calculations performed for ZnTe compound up to 12 GPa are found to be in good and reasonable agreement with available experimental data as well as with previous theoretical studies. These results have been used to evaluate the bulk modulus and its first pressure derivative of ZnTe. The present moment method has taken into account the quantum zero-point vibrations at low temperature and the higher-order anharmonic terms in the atomic displacements. This research shows the advantage of moment method on extensively studying thermo-mechanical properties of materials under high pressures.