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11.
C. Amsler F. Rudolf P. Weymuth L. Dubal G.H. Eaton R. Frosch S. Mango F. Požar 《Physics letters. [Part B]》1975,57(3):289-292
The P parameter for π+p scattering at 236.3 MeV has been measured between 50° and 146° c.m. with very low background using a butanol polarized proton target. The resulting D phases are in fair agreement with dispersion relation values. 相似文献
12.
M Pattabiraman G Rangarajan Kwang-Yong Choi P Lemmens G Guentherodt G Balakrishnan DMcK Paul MR Lees 《Pramana》2002,58(5-6):1013-1017
We report polarized Raman scattering in single crystals of Nd0.7Sr0.3MnO3. The temperature dependence of the MnO6 octahedral bending and stretching modes observed in the XX spectra points to the existence of local lattice distortions,
possibly polarons. The XY spectra have been analyzed using a collision-dominated model, which allows the extraction of the
carrier scattering rate. 相似文献
13.
Beulen MW Bugler J de Jong MR Lammerink B Huskens J Schonherr H Vancso GJ Boukamp BA Wieder H Offenhauser A Knoll W van Veggel FC Reinhoudt DN 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(7):1176-1183
We have developed synthesis routes for the introduction of short and long dialkylsulfides onto the primary side of alpha-, beta-, and gamma-cyclodextrins. Monolayers of these cyclodextrin adsorbates were characterized by electrochemistry, wettability studies, X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and atomic force microscopy (AFM). The differences in thickness and polarity of the outerface of the monolayers were measured by electro-chemistry and wettability studies. On average about 70% of the sulfide moieties were used for binding to the gold, as measured by XPS. Tof-SIMS measurements showed that the cyclodextrin adsorbates adsorb without any bond breakage. AFM measurements revealed for beta-cyclodextrin monolayers a quasi-hexagonal lattice with a lattice constant of 20.6 A, which matches the geometrical size of the adsorbate. The alpha-cyclodextrin and gamma-cyclodextrin monolayers are less ordered. Interactions of the anionic guests 1-anilinonaphthalene-8-sulfonic acid (1,8-ANS) and 2-(p-toluidinyl)naphthalene-6-sulfonic acid (2,6-TNS) and the highly ordered monolayers of heptapodant beta-cyclodextrin adsorbates were studied by surface plasmon resonance (SPR) and electrochemical impedance spectroscopy. The SPR measurements clearly showed interactions between a beta-cyclodextrin monolayer and 1,8-ANS. Electrochemical impedance spectroscopy measurements gave high responses even at low guest concentrations (< or = 5 microM). The association constant for the binding of 1,8-ANS (K = 289,000 +/- 13,000M-1) is considerably higher than the corresponding value in solution. (Partial) methylation of the secondary side of the beta-cyclodextrin strongly decreases the binding. 相似文献
14.
Franciele Wolfart Deepak P. Dubal Marcio Vidotti Rudolf Holze Pedro Gómez-Romero 《Journal of Solid State Electrochemistry》2016,20(4):901-910
A detailed study of the effects of different electropolymerization methods on the supercapacitive properties of polypyrrole (PPy) thin films deposited on carbon cloth is reported. Deposition mechanisms of PPy thin films through cyclic voltammetry (CV), potentiostatic (PS), and galvanostatic (GS) modes have been analyzed. The resulting PPy thin films have been characterized by X-ray photoelectron spectroscopy (XPS), SEM, and TEM. The electrochemical properties of PPy thin films were investigated by cyclic voltammetry and galvanostatic charge/discharge. The results showed that the different electrodeposition modes of synthesis significantly affect the supercapacitive properties of PPy thin films. Among different modes of electrodeposition, PPy synthesized by a potentiostatic mode exhibits maximum specific capacitance of 166 F/g with specific energy of 13 Wh/kg; this is attributed to equivalent proportions of the oxidized and neutral states of PPy. Thus, these results provide a useful orientation for the use of optimized electrodeposition modes for the growth of PPy thin films to be applied as electrode material in supercapacitors. 相似文献
15.
16.
Thiruselvam Ponnusamy Sushilkumar A. Dubal 《Journal of Dispersion Science and Technology》2013,34(8):1123-1128
The ability of surfactants to remove a organic soil from the cotton fabric has been investigated using various parameters such as temperature and hardness of water. The surfactants such as alkylpolyglucosides (APG), sodium lauryl sulphate (SLS), and alpha olefin sulphonate (AOS) have been taken to formulate the detergent as such and in mixtures to evaluate the detergency performance to remove motor oil from the 100% cotton fabric. In the past, the detergency of nonionic APG surfactants has not been well studied. The behavior of commercial APG surfactants and mixtures of APGs with other common surface cleaning agents (SLS & AOS) in laundry applications has been investigated. Motor oil is the toughest soil to remove as it contains nonpolar organic compounds. The performance of detergency was evaluated at different temperatures (30°C, 45°C, and 60°C) and in the presence of hard water (40, 100, and 300 ppm). 相似文献
17.
M. Daum L. Dubal G.H. Eaton R. Frosch J. McCulloch R.C. Minehart E. Steiner C. Amsler R. Hausammann 《Physics letters. [Part B]》1976,60(4):380-384
We have measured the muon momentum in pion decay at rest using a magnetic spectrometer. From the result, pμ+ = (29.787±0.005) MeV/c, we deduce a squared muon neutrino mass of (0.23±0.54) MeV2/c4. 相似文献
18.
A new approach to variable selection in least squares problems 总被引:9,自引:0,他引:9
The title Lasso has been suggested by Tibshirani (1996) as acolourful name for a technique of variable selection which requiresthe minimization of a sum of squares subject to an l1 bound on the solution. This forces zero components in the minimizingsolution for small values of . Thus this bound can functionas a selection parameter. This paper makes two contributionsto computational problems associated with implementing the Lasso:(1) a compact descent method for solving the constrained problemfor a particular value of is formulated, and (2) a homotopymethod, in which the constraint bound becomes the homotopyparameter, is developed to completely describe the possibleselection regimes. Both algorithms have a finite terminationproperty. It is suggested that modified Gram-Schmidt orthogonalizationapplied to an augmented design matrix provides an effectivebasis for implementing the algorithms. 相似文献
19.
RM. Murugappan M. Karthikeyan A. Aravinth MR. Alamelu 《Applied biochemistry and biotechnology》2012,168(8):2170-2183
In the present study, siderophore produced by the marine yeast Aureobasidium pullulans was characterized as hydroxamate by chemical and bioassays. The hydroxamate assignment was supported by the appearance of peaks at 1,647.21?C1,625.99?cm?1 and at 1,435.04?cm?1 in the infrared spectrum. The purified siderophore exhibited specific growth-promoting activity under iron-limited conditions for siderophore auxotrophic probiotic bacteria. Cross-utilization of siderophore indicates a symbiotic relationship between the yeast A. pullulans and the selected probiotic bacterial strains. Statistical optimization of medium components for improved siderophore production in A. pullulans was depicted by response surface methodology. The shift in UV?CVis spectroscopy indicates the photoreactive property and subsequent oxidative cleavage of purified siderophore on exposure to sunlight. 相似文献
20.
The present investigation describes the addition of iron (Fe) in order to improve the supercapacitive properties of MnO2 electrodes using galvanostatic mode. These amorphous worm like Fe: MnO2 electrodes are characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDAX), Fourier transform infrared spectroscopy (FTIR) and wettability test. The supercapacitive properties of MnO2 and Fe: MnO2 electrodes are investigated using cyclic voltammetry, chronopotentiometry and impedance techniques. It is seen that the supercapacitance increases with increase in Fe doping concentration and achieved a maximum of 173 F g?1 at 2 at% Fe doping. The maximum supercapacitance obtained is 218 F g?1 for 2 at% Fe: MnO2 electrode. This hydrous binary oxide exhibited ideal capacitive behavior with high reversibility and high pulse charge–discharge property between ?0.1 and +0.9 V/SCE in 1 M Na2SO4 electrolyte indicating a promising electrode material for electrochemical supercapacitors. 相似文献