首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4036篇
  免费   687篇
  国内免费   335篇
化学   2619篇
晶体学   54篇
力学   295篇
综合类   17篇
数学   399篇
物理学   1674篇
  2024年   16篇
  2023年   108篇
  2022年   144篇
  2021年   174篇
  2020年   162篇
  2019年   157篇
  2018年   158篇
  2017年   123篇
  2016年   217篇
  2015年   200篇
  2014年   229篇
  2013年   310篇
  2012年   382篇
  2011年   368篇
  2010年   248篇
  2009年   215篇
  2008年   239篇
  2007年   224篇
  2006年   214篇
  2005年   177篇
  2004年   129篇
  2003年   104篇
  2002年   82篇
  2001年   73篇
  2000年   82篇
  1999年   69篇
  1998年   65篇
  1997年   52篇
  1996年   57篇
  1995年   52篇
  1994年   31篇
  1993年   44篇
  1992年   42篇
  1991年   25篇
  1990年   21篇
  1989年   15篇
  1988年   11篇
  1987年   8篇
  1986年   7篇
  1985年   10篇
  1984年   1篇
  1983年   6篇
  1981年   2篇
  1980年   2篇
  1979年   1篇
  1978年   1篇
  1957年   1篇
排序方式: 共有5058条查询结果,搜索用时 15 毫秒
991.
Size effect of lattice material and minimum weight design   总被引:3,自引:0,他引:3  
The size effects of microstructure of lattice materials on structural analysis and minimum weight design are studied with extented multiscale finite element method(EMsFEM) in the paper. With the same volume of base material and configuration, the structural displacement and maximum axial stress of micro-rod of lattice structures with different sizes of microstructure are analyzed and compared.It is pointed out that different from the traditional mathematical homogenization method, EMsFEM is suitable for analyzing the structures which is constituted with lattice materials and composed of quantities of finite-sized micro-rods.The minimum weight design of structures composed of lattice material is studied with downscaling calculation of EMsFEM under stress constraints of micro-rods. The optimal design results show that the weight of the structure increases with the decrease of the size of basic sub-unit cells. The paper presents a new approach for analysis and optimization of lattice materials in complex engineering constructions.  相似文献   
992.
We examine the profile of second harmonic generation (SHG) for GaAs/GaAlAs spherical quantum dots (QDs) of Woods-Saxon (WS) plus attractive inversely quadratic (AIQ) potential under the joint influence of additional factors (pressure and temperature) and structural parameters (strengths and radius). The energies and wave functions in GaAs/GaAlAs spherical QDs under WS-AIQ limiting potential are calculated using the parametric Nikiforov-Uvarov (NU) method. Depending on the calculated energies and corresponding wave functions, the SHG coefficient is examined by the iterative procedure in the density matrix method for this system. Finally, the calculated results display that a strong SHG coefficient response, and red shift or blue shift energy can be acquired by adjusting parameters.  相似文献   
993.
Journal of Russian Laser Research - We demonstrate a mid-infrared (mid-IR) ZnGeP2 (ZGP) rectangle ring optical parametric oscillator (OPO) pumped by an actively/passively Q-switched polycrystalline...  相似文献   
994.
Formation flight for unmanned aerial vehicles (UAVs) is a rather complicated global optimum problem. In the global optimum problem, the complex relationship between the controller parameters and the performance index, and the different kinds of constrains under complex combat field environment are taken into account. Brain storm optimization (BSO) is a brand-new swarm intelligence optimization algorithm inspired by a human being’s behavior of brainstorming. In this paper, in allusion to the drawbacks that the basic BSO algorithm traps into local optimum easily and has a slow convergent speed, some novel designs are proposed to enhance the performance of the optimization algorithm. The modified BSO is applied to solve the optimization problem based on the nonlinear Receding horizon control (RHC) mode of UAVs to seek the RHC control parameters for UAV formation flight. Series of comparative experimental results are presented to show the feasibility, validity, and superiority of our proposed method.  相似文献   
995.
New amphiphilic gelators that contained both Schiff base and L-glutamide moieties, abbreviated as o-SLG and p-SLG, were synthesized and their self-assembly in various organic solvents in the absence and presence of metal ions was investigated. Gelation test revealed that o-SLG formed a thermotropic gel in many organic solvents, whilst p-SLG did not. When metal ions, such as Cu(2+), Zn(2+), Mg(2+), Ni(2+), were added, different behaviors were observed. The addition of Cu(2+) induced p-SLG to from an organogel. In the case of o-SLG, the addition of Cu(2+) and Mg(2+) ions maintained the gelating ability of the compound, whilst Zn(2+) and Ni(2+) ions destroyed the gel. In addition, the introduction of Cu(2+) ions caused the nanofiber gel to perform a chiral twist, whilst the Mg(2+) ions enhanced the fluorescence of the gel. More interestingly, the Mg(2+)-ion-mediated organogel showed differences in the fluorescence quenching by D- and L-tartaric acid, thus showing a chiral recognition ability.  相似文献   
996.
997.
A fluorescent logic gate was fabricated based on calcein/layered double hydroxide ultrathin films (UTFs) via alternate assembly technique, which exhibits high stability, reversibility, and resettability. The logic gate was manipulated by utilizing pH value, Hg(2+) and Cl(-) ion as inputs, and the fluorescence emission of the (calcein/LDH)(16) UTF as output, serving as a three-input logic gate that combines the YES and INHIBIT operation.  相似文献   
998.
N-4,6-dimethyl-2-pyrimidinylimidazole 1 and its hydroxyethyl derivative 1-(2-hydroxyethyl)-3-(4,6-dimethyl-2-pyrimidinyl)imidazolium chloride 2 have been synthesized and characterized. The attempted synthesis of bis(N-heterocyclic carbene)palladium complexes via the direct reaction of 2 with Pd(OAc)2 results in the unexpected formation of a bis(N-arylimidazole) palladium complex 3. Additionally, the analogous bis(N-methylimidazole) palladium complex 4 has also been synthesized by the above method. Compounds 14 were characterized by elemental analysis, IR, and 1H NMR. Additionally, their crystal structures have been determined by X-ray diffraction. Complexes 3 and 4 were found to be efficient catalysts for the Suzuki reaction.  相似文献   
999.
Flat-top and steep-edge spectral response of photodetectors is important for dense wavelength-division-multiplexed system. Realization of the flat-top and steep-edge response is very challenging. In the last two decades many methods have been proposed, but the spectral response linewidth is not acceptable to wavelength-division-multiplexes system. In this paper a novel RCE photodetector with flat-top and steep-edge spectral response is presented. Using the step shaped structure, designing multiple-step-type p-type In0.67Ga0.33As0.7P0.3 contact layer and adjusting the thickness of the absorption layer, a design with good flat-top performance is demonstrated such that the quantum efficiency is 51.161% in the flat-top passband, 0.5 and 3 dB bandwidths are 0.26 and 0.4 nm, respectively.  相似文献   
1000.
Duan L  Wang S  Liao R  Liu W 《Chemistry & biology》2012,19(4):443-448
Thiostrepton (TSR), often referred as to a parent compound in the thiopeptide family, is a bimacrocyclic member that features a quinaldic acid (QA) moiety-containing side ring appended to the characteristic core system. QA biosynthesis requires an unusual ring-expanding conversion, showing a methyl transfer onto and a rearrangement of the indole part of L-tryptophan to give a quinoline ketone. Herein, we report that the process involves the activities of the radical methyltransferase TsrT, aminotransferase TsrA, dehydrogenase TsrE, and cyclase TsrD. TsrU, a stereospecific oxidoreductase, catalyzes the further conversion of the ketone into an enantiomerically pure S-alcohol. Elucidation of this chemistry, which is common in the biosynthesis of a number of thiopeptides sharing a QA side ring system, facilitates analog generation, as shown by the achievement of region-specific fluorination of thiostrepton with the improved antibacterial activity.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号