Transport des CaO im Lichtbogenplasma

Transport of the excited CaO molecules, formed in the reaction between a small quantity of Ca atoms and oxygen in DC arc plasma, was followed by a high-speed camera. Axial transport velocities of substances were measured. The diffusion coefficient was determined from the distributions of the intensity of light and their time dependence (found by photometric measurements). The calculation of the diffusion coefficient was performed by using the equation corresponding to the spherical diffusion.     

Über den Stetigkeitsmodul von Fourier-Reihen mit monotonen Koeffizienten

Ohne Zusammenfassung     

Bericht über das „Symposium on Coagulation and Coagulant Aids“ vom 1. bis 3. April 1963 in Los Angeles,Cal. (USA)

Ohne Zusammenfassung     

Difference equations in statistical mechanics. II. Solid-on-solid models in two dimensions

A review and some new results are presented for the solid-on-solid models of wetting in two dimensions (i.e., line interfaces) with an emphasis on the difference equations arising in the transfer matrix calculations for these models. Methods for solving the appropriate difference equations exactly or approximately are surveyed, including specific results for short-range, long-range power-law, and applied field-like (binding) external potentials.     

Quantum critical behaviour of a disordered granular superconductor with charging effects

The effect of quantum fluctuations of the phase on the low-temperature critical behaviour of a three-dimensional disordered (site-diluted) granular superconductor with Coulomb interactions is studied using the renormalization group method. In the one-loop approximation the system exhibits a focus-type stable fixed point which gives rise to unusual critical behaviour with oscillating corrections to the scaling.     

Molecular-weight scaling of coexistence curves for monodisperse polymer solutions

The available data for the polymer volume fraction along the coexistence curves for monodisperse solutions of polystyrene in methylcyclohexane are used to derive the exponent z ≈ 0.61 such that the “correct” order parameter is only a function of ?M^Z (M is the polymer's molecular weight while ? is the reduced temperature). It is shown that a knowledge of the “correct” order parameter is unnecessary for a determination of z which is expected to be universal, i.e. independent of the polymer-solvent system.     

Nonlinear Parabolic Equations with Singularities in Colombeau Vector Spaces

We consider nonlinear parabolic equations with nonlinear non-Lipschitz＇s term and singular initial data like Dirac measure, its derivatives and powers. We prove existence-uniqueness theorems in Colombeau vector space yC^1,W^2,2（[0,T）,R^n）,n ≤ 3. Due to high singularity in a case of parabolic equation with nonlinear conservative term we employ the regularized derivative for the conservative term, in order to obtain the global existence-uniqueness result in Colombeau vector space yC^1,L^2（[0,T）,R^n）,n≤ 3.     

How far, how long: on the temporal scope of prosodic boundary effects

Acoustic lengthening at prosodic boundaries is well explored, and the articulatory bases for this lengthening are becoming better understood. However, the temporal scope of prosodic boundary effects has not been examined in the articulatory domain. The few acoustic studies examining the distribution of lengthening indicate that boundary effects extend from one to three syllables before the boundary, and that effects diminish as distance from the boundary increases. This diminishment is consistent with the pi-gesture model of prosodic influence [Byrd and Saltzman, J. Phonetics 31, 149-180 (2003)]. The present experiment tests the preboundary and postboundary scope of articulatory lengthening at an intonational phrase boundary. Movement-tracking data are used to evaluate durations of consonant closing and opening movements, acceleration durations, and consonant spatial magnitude. Results indicate that prosodic boundary effects exist locally near the phrase boundary in both directions, diminishing in magnitude more remotely for those subjects who exhibit extended effects. Small postboundary effects that are compensatory in direction are also observed.     

Kinetics and mechanism of the reactions of Pd(II) complexes with azoles and diazines. Crystal structure of [Pd(bpma)(H2O)](ClO4)2.2H2O

Substitution reactions of the complexes [Pd(bpma)(H2O)]2+, [Pd(bpma)Cl]+, [Pd(dien)(H2O)]2+ and [Pd(dien)Cl]+, where bpma = bis(2-pyridylmethyl)amine and dien = diethylentriamine or 1,5-diamino-3-azapentane, with some nitrogen-donor ligands such as triazole, pyrazole, pyrimidine, pyrazine and pyridazine, were studied in an aqueous 0.10 M NaClO4 at pH 2.8 using variable-temperature and -pressure stopped-flow spectrophotometry. The second-order rate constants indicate that the Pd(II) complexes of bpma, viz. [Pd(bpma)(H2O)]2+ and [Pd(bpma)Cl]+, are more reactive than the complexes of dien, viz. [Pd(dien)(H2O)]2+ and [Pd(dien)Cl]+. Also, the aqua complexes, [Pd(bpma)(H2O)]2+ and [Pd(dien)(H2O)]2+, are much more reactive than the corresponding chloro complexes. The most reactive nucleophile of the five-membered rings is triazole and for the six-membered rings the most reactive one is pyridazine. Activation parameters were determined for all reactions and the negative entropies and volumes of activation (Delta S++, Delta V++) support an associative ligand substitution mechanism. The crystal structure of [Pd(bpma)(H2O)](ClO4)2.2H2O was determined by X-ray diffraction. Crystals are monoclinic with the space group P2(1)/c. The coordination geometry of [Pd(bpma)(H2O)]2+ is distorted square-planar. The Pd-N (central) bond distance, 1.958(5) A, is shorter than the other two Pd-N distances, 2.007(5) and 2.009(5) A. The Pd-O distance is 2.043(5) A.