全文获取类型
收费全文 | 190篇 |
免费 | 7篇 |
专业分类
化学 | 113篇 |
晶体学 | 2篇 |
力学 | 8篇 |
数学 | 43篇 |
物理学 | 31篇 |
出版年
2023年 | 2篇 |
2022年 | 1篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 8篇 |
2015年 | 9篇 |
2014年 | 6篇 |
2013年 | 20篇 |
2012年 | 6篇 |
2011年 | 7篇 |
2010年 | 6篇 |
2009年 | 4篇 |
2008年 | 9篇 |
2007年 | 7篇 |
2006年 | 5篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1971年 | 2篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1927年 | 1篇 |
排序方式: 共有197条查询结果,搜索用时 15 毫秒
61.
Ridley T Hennessy JT Donovan RJ Lawley KP Wang S Brint P Lane E 《The journal of physical chemistry. A》2008,112(31):7170-7176
The vacuum ultraviolet laser-excited photoion-pair formation spectrum of CH 3Br has been measured under high resolution in the threshold region. The (2 + 1) and (3 + 1) resonance-enhanced multiphoton ionization spectra in the same energy region are also reported. By comparison of the spectra in this and a more extended region, resonances in the photoion-pair formation spectrum are assigned to p and f Rydberg states. It is concluded that all the structure in the photoion-pair formation spectrum near threshold can be accounted for by members of the Omega = 0 subset of Rydberg states that act as doorway states to the ion channel. 相似文献
62.
Dr. Wenzhi Ji Dr. Woong Sub Byun Dr. Wenchao Lu Xijun Zhu Dr. Katherine A. Donovan Dr. Brendan G. Dwyer Dr. Jianwei Che Dr. Linjie Yuan Dr. Xianmixinuer Abulaiti Dr. Steven M. Corsello Dr. Eric S. Fischer Dr. Tinghu Zhang Dr. Nathanael S. Gray 《Angewandte Chemie (International ed. in English)》2023,62(43):e202308292
Chemical probes are essential tools for understanding biological systems and for credentialing potential biomedical targets. Programmed cell death 2 (PDCD2) is a member of the B-cell lymphoma 2 (Bcl-2) family of proteins, which are critical regulators of apoptosis. Here we report the discovery and characterization of 10 e , a first-in-class small molecule degrader of PDCD2. We discovered this PDCD2 degrader by serendipity using a chemical proteomics approach, in contrast to the conventional approach for making bivalent degraders starting from a known binding ligand targeting the protein of interest. Using 10 e as a pharmacological probe, we demonstrate that PDCD2 functions as a critical regulator of cell growth by modulating the progression of the cell cycle in T lymphoblasts. Our work provides a useful pharmacological probe for investigating PDCD2 function and highlights the use of chemical proteomics to discover selective small molecule degraders of unanticipated targets. 相似文献
63.
Fatih Demirkale Diane Donovan Joanne Hall Abdollah Khodkar Asha Rao 《Graphs and Combinatorics》2016,32(4):1353-1374
A pair of Latin squares, A and B, of order n, is said to be pseudo-orthogonal if each symbol in A is paired with every symbol in B precisely once, except for one symbol with which it is paired twice and one symbol with which it is not paired at all. A set of t Latin squares, of order n, are said to be mutually pseudo-orthogonal if they are pairwise pseudo-orthogonal. A special class of pseudo-orthogonal Latin squares are the mutually nearly orthogonal Latin squares (MNOLS) first discussed in 2002, with general constructions given in 2007. In this paper we develop row complete MNOLS from difference covering arrays. We will use this connection to settle the spectrum question for sets of 3 mutually pseudo-orthogonal Latin squares of even order, for all but the order 146. 相似文献
64.
The optical-optical double resonance spectra of I(2) and I(2)-Xe mixtures at room temperature reported in the literature using a fixed-wavelength, broad band pump laser have now been recorded using a tuneable, narrow band source. We show that during the time of the overlapped laser pulses ( approximately 10 ns) and with 10-20 Torr of Xe there is widespread collisional energy transfer in the intermediate state and that this phenomenon offers an alternative explanation for the broad bands in the excitation spectrum, assigned to XeI(2) complexes by the authors of the earlier study (M. E. Akopyan, I. Y. Novikova, S. A. Poretsky and A. M. Pravilov, Chem. Phys., 2005, 310, 287). Dispersed emission bands, previously attributed to direct fluorescence from the ion-pair state(s) of the complexes, are re-assigned to emission from ion-pair states of the parent I(2) that are populated by collisional energy transfer out of the initially excited state. 相似文献
65.
Ridley T Lawley KP Donovan RJ Alekseev VA 《Physical chemistry chemical physics : PCCP》2007,9(44):5885-5890
A range of vibrational levels of the D 0(u)(+)((3)P(2)) and F' 0(u)(+)((1)D(2)) ion-pair states of I(2) is shown to be easily generated by amplified spontaneous emission (ASE) from their more accessible partners, E 0(g)(+)((3)P(2)) and f' 0(g)(+)((1)D(2)), in sufficient concentration for dispersed fluorescence studies of the D 0(u)(+)((3)P(2)) --> 0(g)(+)(bb) and F' 0(u)(+)((1)D(2)) --> 0(g)(+)(bb) transitions to be carried out. T(0) (J = 49) of this shallow-bound 0(g)(+)(bb) valence state is unambiguously determined and an improved R(e) value of 3.952 +/- 0.005 A is obtained from optimizing the fit of the intensities of the vibrational progressions in the 0(g)(+)(bb) state, and T(e) is found to be 27311.3 +/- 2 cm(-1), leading to D(e) = 442.0 +/- 2 cm(-1). 相似文献
66.
Dr. Mingxing Teng Dr. Jie Jiang Zhixiang He Dr. Nicholas P. Kwiatkowski Dr. Katherine A. Donovan Dr. Caitlin E. Mills Chiara Victor Dr. John M. Hatcher Dr. Eric S. Fischer Dr. Peter K. Sorger Dr. Tinghu Zhang Dr. Nathanael S. Gray 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(33):13969-13974
67.
68.
Two constructions are described that yield an improved lower bound for the number of 2-designs with the parameters of PG d (n, q), and a lower bound for the number of resolved 2-designs with the parameters of AG d (n, q). 相似文献
69.
Using high-resolution Fourier transform emission techniques, we have resolved rotational structure in the D0(u)(+)((3)P(2)) → X0(g)(+) emission following collisional transfer from the E0(g)(+)((3)P(2)) state in I(2). The P:R branch ratios in the E0(g)(+)((3)P(2)) → D0(u)(+)((3)P(2)) transfer are found to vary enormously with v(E) and v(D). We show that the observed intensities are all consistent with the transfer being dominated by long-range, near-resonant collisions with residual H(2)O. Unequal P:R branch ratios in the E0(g)(+)((3)P(2)) → A1(u) emission have been shown to result from mixing of the E0(g)(+)((3)P(2)) and β1(g)((3)P(2)) states via Ω-uncoupling. 相似文献
70.
The min-edge clique partition problem asks to find a partition of the vertices of a graph into a set of cliques with the fewest edges between cliques. This is a known NP-complete problem and has been studied extensively in the scope of fixed-parameter tractability (FPT) where it is commonly known as the Cluster Deletion problem. Many of the recently-developed FPT algorithms rely on being able to solve Cluster Deletion in polynomial time on restricted graph structures. 相似文献