Structure determination of the nonlinear hydrocarbon chains C9H3 and C11H3 by deuterium labeling

A systematic deuterium labeling experiment is presented that aims at an unambiguous determination of the geometrical ground state structure of the C(9)H(3) and C(11)H(3) hydrocarbon chains. Cavity ring-down spectroscopy and special plasma expansions constituting C/H, C/D, and C/H/D are used to record optical transitions of both species and their (partially) deuterated equivalents in the 19,000 cm(-1) region. The number of observed bands, the quantitative determination of isotopic shifts, and supporting calculations show that the observed C(9)H(3) and C(11)H(3) spectra originate from HC(4)(CH)C(4)H and HC(4)[C(C(2)H)]C(4)H species with C(2v) symmetry. This result illustrates the potential of deuterium labeling as a useful approach to characterize the molecular structure of nonlinear hydrocarbon chains.     

Nontrivial periodic solutions for strong resonance Hamiltonian systems via a local linking theorem

In this paper, we first establish an existence result of critical points for a class of functionals defined on Hilbert spaces by using a local linking idea. Then as an application of the existence result, we obtain the existence of periodic solutions of strong resonance Hamiltonian systems which are asymptotically linear both at infinity and at origin.     

A quarter-car vehicle model based feature for wheeled and tracked vehicles classification

Seismic signals are widely used in ground vehicle classification due to their inherent characteristics. In this paper, a kind of feature extracted by the Short-time Power Spectrum Density (STPSD) from ground-vehicle-induced seismic signals was introduced for wheeled and tracked vehicle distinction. According to theoretical analysis, based on a simplified quarter-car vehicle model, the cepstrums of the STPSD of seismic signals can depict the structure differences of wheel and track. In addition, the extracted feature is also less affected by the underlying geologies than traditional Power Spectrum Density based features. It is verified with mixed datasets from our field experiments and SensIT project.     

提高超高能中子计算效率的蒙特卡罗抽样技巧

利用蒙特卡罗方法模拟中子与中子碰撞及超高能中子的产生与输运,原有抽样方法需要模拟大量样本方能使与超高能中子有关统计量的计算误差达到要求.针对ICF聚变靶中子输运问题的特点,发展一种"加权赌分裂抽样方法",以增加重要区域的抽样数、减少非重要区域的抽样数,同时通过权修正保证计算结果无偏.典型模型数值模拟计算结果显示,该方法能够有效增加聚变区的中子抽样数、增加中子相互碰撞数,使超高能中子通量计算误差显著降低,达到提高超高能中子计算效率的目的.     

介孔分子筛Ti-AlKIT-1的制备、表征与催化性能

分别采用直接(ds)和后合成法(ps)合成含铝的介孔分子筛Al(ds or ps)KIT-1。 以钛酸四丁酯Ti（OEt）4为钛源,将钛嫁接在AlKIT-1表面制备出Ti-AlKIT-1样品。 用傅里叶变换红外光谱、X射线粉末衍射、固体核磁共振(MAS NMR)、固体紫外 可见漫反射光谱（DRS）、能谱(EDS)和N2吸附-脱附对样品进行了表征,并以双氧水氧化环己醇为探针考察了样品的催化活性。 实验结果表明,分子筛Ti-AlKIT-1具有规整的介孔孔道结构,钛进入介孔分子筛骨架而成为四配位的骨架钛,铝的存在形式与样品AlKIT-1的预处理有关,经铵溶液洗涤的Al(ds)KIT-1中没有非骨架铝。 Ti-AlKIT-1在催化双氧水氧化环己醇反应中铝和钛存在明显的协同作用。 样品Ti-Al(ds)KIT-1表现出更高的催化作用,这与其具有较高的比表面积、较大的孔容和较高钛铝比有关,80 ℃反应48 h,重复使用3次后,环己醇的转化率降低至51.3%,仅下降4.31%。     

利用超高能中子诊断惯性约束聚变的燃烧

惯性约束聚变靶丸中,高能中子相互之间发生碰撞将导致超高能中子的产生.本文讨论超高能中子产生与聚变燃烧速率的关系.数值模拟理想模型,分析超高能中子产生量与平均烧氚体积的关系,讨论利用出壳超高能中子流与烧氚量诊断二维效应和混合效应.进一步分析出壳超高能中子流与平均烧氚率的关系,探讨利用超高能中子诊断平均烧氚温度并判断是否发生非平衡效应问题.     

Pr_(0.15)Tb_(0.85)Fe_(1.9)B_x内禀磁致伸缩的测量与分析

利用电弧熔炼法制备了Pr_(0.15)Tb_(0.85)Fe_(1.9)B_x系列样品,通过X射线衍射法对粉末样品的(440)衍射峰进行精细步进扫描并拟合数据,分析获得样品的内禀磁致伸缩λ_(111),通过电阻应变片法测得块状样品在外加磁场下的磁致伸缩值变化趋势,外推得到宏观饱和磁致伸缩值λ_s,并从Laves相晶体结构特性出发对两者进行详细比较对照和进一步深化分析.结果表明,常温下Pr在Laves相化合物中对磁致伸缩具有较大的贡献,适量B的掺入可以增加Pr在Laves相化合物中的含量且不降低材料的磁致伸缩性能.     

Gevrey Smoothness of Families of Invariant Curves for Analytic Area Preserving Mappings

In this paper we prove the existence of a Gevrey family of invariant curves for analytic area preserving mappings. The Gevrey smoothness is expressed by Gevrey index. We specifically obtain the Gevrey index of families of invariant curves which is related to the smoothness of area preserving mappings and the exponent of small divisors condition. Moreover, we obtain a Gevrey normal form of area preserving mappings in a neighborhood of the union of the invariant curves.     

非局域非线性介质中的拉盖尔-高斯涡旋呼吸子和涡旋光孤子

在圆柱坐标系下,利用分离变量的方法求得了非局域克尔介质中拉盖尔-高斯光束传输的精确解析解。当输入功率等于临界功率时,光束演变为拉盖尔-高斯涡旋光孤子,是一种旋转的多环光孤子;当输入功率接近于临界功率时,光束在传输过程中形成拉盖尔-高斯涡旋呼吸子。结果表明,低阶的拉盖尔-高斯孤子呈现中空多峰亮环分布。     

复合稀土对α-Ni0.8Co0.05Al0.15(OH)2.15-2y(CO3)y·xH2O电化学性能的影响

为了同时改善固相共沉积法合成的α-Ni0.8Co0.05Al0.15(OH)2.15-2y(CO3)y·xH2O的常、高温充放电性能,样品经混合掺杂不同比率的La2O3,Sm2O3,Y2O3,Lu2O3以及La2O3+Y2O3后,作为模拟MH/Ni电池的正极材料,在不同温度下由恒流充放电和循环伏安测定其电化学性能.结果表明:复合掺加0.5%La2O3+1.0%Y2O3(质量分数),在0.5C和5C充放电下,30℃时可分别提高样品的放电比容量3.3%和4.7%,60℃时可分别提高17.4%和19.9%.同时也改善了高温放电电位.