Electron-hole coupling and the charge density wave transition in TiSe2

Angle-resolved photoemission is employed to measure the band structure of TiSe2 in order to clarify the nature of the ( 2 x 2 x 2) charge density wave transition. The results show a very small indirect gap in the normal phase transforming into a larger indirect gap at a different location in the Brillouin zone. Fermi surface topology is irrelevant in this case. Instead, electron-hole coupling together with a novel indirect Jahn-Teller effect drives the transition.     

Elasticity transition and loop formation in vibrated bead chains: A simulation of polymer chains

By measuring the distribution function of the end-to-end distance, we find that strongly shaken bead chains exhibit many properties, such as the rigid-rod-to-Gaussian chain transition, scaling, fast drop of loop formation probability in the short-chain regime, and enhancement of loop formation probability for kinked chains, of long-chain polymers. Though there is difference in local details between our chains and the worm-like chains, our results are consistent with recent calculations based on the worm-like chain model in many respects.     

WALL CONDUCTION EFFECT ON THE ONSET OF THERMAL INSTABILITY IN HORIZONTAL RECTANGULAR CHANNELS

The effect of peripheral thermal conduction in the bottom wall on the onset of thermal instability in the thermal entrance region of horizontal, rectangular, bottom-uniform-heated channels was studied by experiment and theoretical simulation. The predicted results of the onset of thermal instability for the cases of uniform peripheral wall heat flux are in agreement with the published experimental data, but the predicted results for the cases of uniform peripheral wall temperature exceed the previous data by about an order of magnitude. The present experimental data reconfirm the present predictions. The effect of increasing the peripheral wall conduction is shown to stabilize the flow.     

CdxHg(1−x)Te Alloy Colloidal Quantum Dots: Tuning Optical Properties from the Visible to Near‐Infrared by Ion Exchange

The energy gap between valence and conduction levels in colloidal semiconductor quantum dots can be tuned via the nanoparticle diameter when this is comparable to or less than the Bohr radius. In materials such as cadmium mercury telluride, which readily forms a single phase ternary alloy, this quantum confinement tuning can also be augmented by compositional tuning, which brings a further degree of freedom in the bandgap engineering. Here it is shown that compositional control of 2.3 nm diameter Cd_xHg_(1?x)Te nanocrystals by exchange of Hg²⁺ in place of Cd²⁺ ions can be used to tune their optical properties across a technologically useful range, from 500 nm to almost 1200 nm. Data on composition‐dependent changes in the optical properties are provided, including bandgap, extinction coefficient, emission energy and spectral shape, Stokes shift, quantum efficiency, and radiative lifetimes as the exchange process occurs, which are highly relevant for those seeking to use these technologically important QD materials.     

Wavenumber Measurements of CO(2) Transitions in 1.5-µm Atmospheric Window Using an External-Cavity Diode Laser

Using an external-cavity diode laser (ECDL) as the light source, we have observed the spectrum of CO(2) in the 1.5-μm atmospheric window including the (30(0)1)(I) <-- (00(0)0) and (31(1)1)(I) <-- (01(1)0)(I) bands. Good signal-to-noise ratio allowed us to lock the frequency of our ECDL to the absorption line centers. Wavenumber measurements of the transitions with accuracy about 6.6 x 10(-4) cm(-1) are made with the help of a precision wavemeter calibrated to the accurate C(2)H(2) frequency references in the 1.5-μm wavelength region. Molecular constants are obtained by making the least-squares fits of the measured transition wavenumbers. The rotational and centrifugal distortion constants are consistent with the previous results using high-resolution Fourier transform spectroscopy. However, the band centers are different with previous results by several thousandth reciprocal centimeters. Copyright 2001 Academic Press.     

Nonuniform sampling and maximum entropy reconstruction applied to the accurate measurement of residual dipolar couplings

Residual dipolar couplings (RDC) provide important global restraints for accurate structure determination by NMR. We show that nonuniform sampling in combination with maximum entropy reconstruction (MaxEnt) is a promising strategy for accelerating and potentially enhancing the acquisition of RDC spectra. Using MaxEnt-processed spectra of nonuniformly sampled data sets that are reduced up to one fifth relative to uniform sampling, accurate 13C'-13Calpha RDCs can be obtained that agree with an RMS of 0.67 Hz with those derived from uniformly sampled, Fourier transformed spectra. While confirming that frequency errors in MaxEnt spectra are very slight, an unexpected class of systematic errors was found to occur in the 6th significant figure of 13C' chemical shifts of doublets obtained by MaxEnt reconstruction. We show that this error stems from slight line shape perturbations and predict it should be encountered in other nonlinear spectral estimation algorithms. In the case of MaxEnt reconstruction, the error can easily be rendered systematic by straightforward optimization of MaxEnt reconstruction parameters and self-cancels in obtaining RDCs from nonuniformly sampled, MaxEnt reconstructed spectra.     

罗布泊遥感影像"耳纹"特征分析及其环境意义

研究典型干旱区的罗布泊,对揭示区域环境演变特征和全球变化具有重要意义.从遥感影像上的"耳纹"特征入手,通过光谱、土壤和地表参数等分析,认为:地表全盐含量和结构差异是形成罗布泊遥感影像"耳纹"特征的直接原因;光谱、全盐含量和土壤粒径的分析结果具有很好的一致性."耳纹"记录下了罗布泊地区的环境演变特征,这些特征表明:受全球环境影响,湖水在气候不断干旱的过程中逐渐干涸,干涸过程的气候调整,使罗布泊地区经历了两次相对湿润的气候环境,前一次较长,后一次很短.     

The effects of hydrogen plasma pretreatment on the formation of vertically aligned carbon nanotubes

The effects of H₂ plasma pretreatment on the growth of vertically aligned carbon nanotubes (CNTs) by varying the flow rate of the precursor gas mixture during microwave plasma chemical vapor deposition (MPCVD) have been investigated in this study. Gas mixture of H₂ and CH₄ with a ratio of 9:1 was used as the precursor for synthesizing CNTs on Ni-coated TiN/Si(1 0 0) substrates. The structure and composition of Ni catalyst nanoparticles were investigated by using scanning electron microscopy (SEM) and cross-sectional transmission electron microscopy (XTEM). Results indicated that, by manipulating the morphology and density of the Ni catalyst nanoparticles via changing the flow rate of the precursor gas mixture, the vertically aligned CNTs could be effectively controlled. The Raman results also indicated that the intensity ratio of the G and D bands (I_D/I_G) is decreased with increasing gas flow rate. TEM results suggest H₂ plasma pretreatment can effectively reduce the amorphous carbon and carbonaceous particles and, thus, is playing a crucial role in modifying the obtained CNTs structures.