首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   23995篇
  免费   2724篇
  国内免费   1908篇
化学   14764篇
晶体学   408篇
力学   1480篇
综合类   98篇
数学   2370篇
物理学   9507篇
  2024年   29篇
  2023年   305篇
  2022年   543篇
  2021年   603篇
  2020年   714篇
  2019年   738篇
  2018年   676篇
  2017年   559篇
  2016年   902篇
  2015年   822篇
  2014年   1059篇
  2013年   1570篇
  2012年   1907篇
  2011年   1999篇
  2010年   1445篇
  2009年   1445篇
  2008年   1576篇
  2007年   1416篇
  2006年   1340篇
  2005年   1107篇
  2004年   953篇
  2003年   799篇
  2002年   795篇
  2001年   823篇
  2000年   639篇
  1999年   535篇
  1998年   424篇
  1997年   380篇
  1996年   359篇
  1995年   291篇
  1994年   255篇
  1993年   191篇
  1992年   198篇
  1991年   200篇
  1990年   156篇
  1989年   127篇
  1988年   92篇
  1987年   66篇
  1986年   66篇
  1985年   76篇
  1984年   55篇
  1983年   37篇
  1982年   45篇
  1981年   47篇
  1980年   34篇
  1979年   22篇
  1978年   27篇
  1976年   22篇
  1975年   25篇
  1974年   22篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
With the advances in pulsed laser systems, microscopic imaging techniques such as multiphoton and pump-probe fluorescence microscopy have developed into effective tools for investigating intensity and time-resolved phenomena inside biological systems. However, pulsed lasers used in these techniques usually are commercial systems with repetition frequencies of around 80 MHz. While these systems have proven to be adequate for multiphoton and pump-probe microscopic imaging applications, the temporal separation of the laser pulse train (around 12.5 ns) is long compared to the fluorescence lifetimes of many common fluorescence species. In this work, we present the designs of repetition rate multipliers based on passive optical components that can be used to increase the efficiency in multiphoton and pump-probe fluorescence microscopy. Depending on the lifetime of fluorescence molecules under investigation, the passive repetition rate multiplier can increase the duty cycle of multiphoton or pump-probe microscopy up to fourfold.  相似文献   
102.
A New Annonaceous acetogenin,squamostolide(1),was isolated from the seeds of Annona squamosa.Its structure was elucidated based on spectroscopic methods and comparison with known compounds.It is the first example of Annonaceous acetogenin with each of the two ends of the aliphatic chain bearing a γ-lactone.Thenew compound exhibited cytotoxic activity in vitro against bel-7402 and CNE2 human tumor cell lines.  相似文献   
103.
A convenient synthetic route was developed for the synthesis of the novel glycolipids: 1,2-di-O-acyl-3-O-(2‘-acylamide-2‘-denxy-ct-D-glucopyranosyl)-sn-glycerols. 10 new compounds of glycolipids with different acyl groups were obtained.  相似文献   
104.
傅里叶变换近红外光谱分析技术用于酒醅中水分、酸度、淀粉和残糖的分析,方法分析速度快、操作简单,其分析的准确度满足酿酒工业的要求,是值得推广的一种实用技术。  相似文献   
105.
采用微波吸收法,测量了ZnS:Mn,Cu粉末材料受到超短脉冲激光激发后,其光生电子和浅束缚态电子的衰减过程.发现Mn,Cu的浓度对导带电子的寿命有明显的影响,提高掺杂浓度会使光生电子的寿命大大缩短,还研究了掺杂浓度对光致发光强度的影响. 关键词: 发光材料 硫化锌 光电子 微波吸收技术  相似文献   
106.
An analytical approach and exact solutions for the torsional vibration of a multi-step non-uniform rod carrying an arbitrary number of concentrated elements such as rigid disks and with classical or non-classical boundary conditions is presented. The exact solutions for the free torsional vibration of non-uniform rods whose variations of cross-section are described by exponential functions and power functions are obtained. Then, the exact solutions for more general cases, non-uniform rods with arbitrary cross-section, are derived for the first time. In order to simplify the analysis for the title problem, the fundamental solutions and recurrence formulas are developed. The advantage of the proposed method is that the resulting frequency equation for torsional vibration of multi-step non-uniform rods with arbitrary number of concentrated elements can be conveniently determined from a homogeneous algebraic equation. As a consequence, the computational time required by the proposed method can be reduced significantly as compared with previously developed analytical procedures. A numerical example shows that the results obtained from the proposed method are in good agreement with those determined from the finite element method (FEM), but the proposed method takes less computational time than FEM, illustrating the present methods are efficient, convenient and accurate.  相似文献   
107.
This work is devoted to near-optimal controls of large-scale discrete-time nonlinear dynamic systems driven by Markov chains; the underlying problem is to minimize an expected cost function. Our main goal is to reduce the complexity of the underlying systems. To achieve this goal, discrete-time control models under singularly-perturbed Markov chains are introduced. Using a relaxed control representation, our effort is devoted to finding near-optimal controls. Lumping the states in each irreducible class into a single state gives rise to a limit system. Applying near-optimal controls of the limit system to the original system, near-optimal controls of the original system are derived.  相似文献   
108.
时间分辨红外发射光谱法对自由基反应的研究   总被引:2,自引:0,他引:2  
在过去的 15年中 ,傅立叶变换红外发射光谱法广泛应用于研究气相自由基反应 .Sloan首先研究了O(1D)的反应 ,随后Leone和Hancock研究了O(3 P)的反应 .此后 ,孔繁敖和朱起鹤等研究了小自由基 ,包括CH、CH2 、CH3 、C2 H3 、C2 H5、C2 H、C3 H3 和C3 H5与O2 、NO、N2 O、NO2 等分子的反应。在红外光谱中观察到各个反应的初生产物和初步反应通道 ,和从头算的理论研究结合起来 ,这些反应的机理已基本弄清 .  相似文献   
109.
Yao  Dong  HUANG  Xiao  Jie  ZHANG 《中国化学快报》2003,14(1):29-31
A convenient and large-scale preparation of retinoic acid 1 from β-ionone in five steps with 38% overall yield is described.The key steps are the epoxidization of 2 with a new methylated agent and the condensation 4 with tetraethyl methylenediphophonate in one-pot procedure to prepare 6.  相似文献   
110.
考虑到量子相干效应和界面散射效应 ,利用 L ambert理论模型 ,计算正常金属 /绝缘层 /超导 /绝缘层 /正常金属双垒隧道结中的准粒子输运系数和隧道谱。研究表明 :( 1)所有的准粒子输运系数和电导谱在超导能隙之上都随能量作周期性振荡 ,其振荡周期依赖于超导层的厚度 ;( 2 )在超导能隙之上 Andreev反射系数随能量呈现周期性消失现象 ;( 3)在绝缘层势垒强度取很大的隧道极限下 ,超导层中会形成一系列的准粒子束缚态 ,其位置由量子化条件决定 ;( 4)界面散射效应不仅能压低各子能隙电导峰 ,还能使子能隙电导峰劈裂为两个峰。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号