全文获取类型
收费全文 | 83308篇 |
免费 | 12460篇 |
国内免费 | 8300篇 |
专业分类
化学 | 56864篇 |
晶体学 | 820篇 |
力学 | 5377篇 |
综合类 | 610篇 |
数学 | 9776篇 |
物理学 | 30621篇 |
出版年
2024年 | 269篇 |
2023年 | 1615篇 |
2022年 | 2715篇 |
2021年 | 2814篇 |
2020年 | 3043篇 |
2019年 | 2952篇 |
2018年 | 2669篇 |
2017年 | 2353篇 |
2016年 | 3611篇 |
2015年 | 3692篇 |
2014年 | 4379篇 |
2013年 | 5892篇 |
2012年 | 7049篇 |
2011年 | 7174篇 |
2010年 | 4875篇 |
2009年 | 4819篇 |
2008年 | 5135篇 |
2007年 | 4637篇 |
2006年 | 4316篇 |
2005年 | 3763篇 |
2004年 | 3033篇 |
2003年 | 2368篇 |
2002年 | 2212篇 |
2001年 | 1893篇 |
2000年 | 1693篇 |
1999年 | 1850篇 |
1998年 | 1563篇 |
1997年 | 1364篇 |
1996年 | 1409篇 |
1995年 | 1227篇 |
1994年 | 1132篇 |
1993年 | 967篇 |
1992年 | 867篇 |
1991年 | 763篇 |
1990年 | 614篇 |
1989年 | 528篇 |
1988年 | 402篇 |
1987年 | 378篇 |
1986年 | 330篇 |
1985年 | 330篇 |
1984年 | 222篇 |
1983年 | 192篇 |
1982年 | 159篇 |
1981年 | 128篇 |
1980年 | 90篇 |
1978年 | 58篇 |
1976年 | 54篇 |
1975年 | 63篇 |
1974年 | 55篇 |
1973年 | 62篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
171.
Shen-shui Lü 《高分子科学》2006,(5):441-447
Two kinds of water-soluble metallophthalocyanines, binuclear cobalt phthalocyanine (Co2Pc2) and binuclear ferric phthalocyanine (Fe2Pc2), were synthesized through phenylanhydride-urea route and characterized by elemental analysis and FT-IR spectra. Binuclear metallophthalocyanine derivatives (Mt2Pc2) were immobilized on silk fibers and modified viscose fibers to construct bioactive fibers of mimic enzyme. Mt2Pc2 was used as the active center of bioactive fibers, viscose and silk fibers as the microenvironments. The catalytic oxidation ability of bioactive fibers on the malodors of methanthiol and hydrogen sulfide was investigated at room temperature. The experimental results indicated that the catalytic activity of such bioactive fibers was closely correlative to the types ofbioactive fibers and substrates. 相似文献
172.
室温下,通过双核配合物[Cu(dppm)(NO3)]2(dppm=双二苯基膦甲烷)与四苯基硼钠在甲醇和二氯甲烷混合溶剂中反应制备了三核铜(I)配合物[Cu3(dppm)3(NO3)(OH)](NO3),经过红外光谱、热重分析、核磁和ES-MS等现代分析手段表征了配合物的物理化学性质,并进一步研究了配合物在室温下的荧光光谱特征。 相似文献
173.
D. Liu N.Q. Ngo X.Y. Dong S.C. Tjin P. Shum 《Applied physics. B, Lasers and optics》2005,81(6):807-811
We propose and experimentally demonstrate a stable dual-wavelength erbium-doped polarization-maintaining (PM) fiber laser
with tunable wavelength spacing using an all-PM linear cavity that makes use of two reflection peaks from the PM fiber Bragg
grating (PM-FBG). Experimental results show stable dual lasing lines with a wavelength separation of ∼0.22 nm and a large
optical signal-to-noise ratio (OSNR) of over 40 dB under room temperature. By applying axial strain to the PM-FBG, the center
wavelengths of the two lasing lines can be tuned over several nanometers and the wavelength separation between the lasing
lines can also be tuned to as small as 0.05 nm, which, to our knowledge, is the smallest wavelength spacing ever obtained
from a stable room-temperature dual-wavelength fiber laser. The proposed laser configuration has the advantages of simple
structure, low loss, stable dual-wavelength operation and a very small lasing linewidth of ∼5 kHz .
PACS 42.55.Wd; 42.81.-i; 42.81.Gs 相似文献
174.
Sungyong Kim Lingxin Chen Sangyeop Lee Gi Hun Seong Jaebum Choo Eun Kyu Lee Chil-Hwan Oh Sanghoon Lee 《Analytical sciences》2007,23(4):401-405
A rapid DNA analysis has been developed based on a fluorescence intensity change of a molecular beacon in a PDMS microfluidic channel. Recently, we reported a new analytical method of DNA hybridization involving a PDMS microfluidic sensor using fluorescence energy transfer (FRET). However, there are some limitations in its application to real DNA samples because the target DNA must be labelled with a suitable fluorescent dye. To resolve this problem, we have developed a new DNA microfluidic sensor using a molecular beacon. By monitoring the change in the restored fluorescence intensity along the channel length, it is possible to rapidly detect any hybridization of the molecular beacon to the target DNA. In this case, the target DNA does not need to be labelled. Our experimental results demonstrate that this microfluidic sensor using a molecular beacon is a promising diagnostic tool for rapid DNA hybridization analysis. 相似文献
175.
Xinjiang Chen Goh Matsuo Bunsho Ohtani Kaoru Tsujii 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4891-4900
A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H2O2 is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H2O2 is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H2O2 is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007 相似文献
176.
177.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007 相似文献
178.
Gujie Qian S. Baccaro M. Falconieri Jiafang Bei A. Cecilia Guorong Chen 《Journal of Non》2008,354(40-41):4626-4629
Glasses in SiO2–ZnO–BaO system with the different ZnO/BaO ratio were studied. In some cases, BaF2 was introduced to substitute for BaO on the equal base. Photoluminescent spectra showed that ZnO in glass matrices behaved somewhat differently from ZnO crystals. Especially, the introduction of fluorine ions led to dramatic shift of UV emission band of glasses closer to that of ZnO crystals. Raman spectral analysis provided consistent results. In particular, Raman bands in the high frequency region are sensitive to effects of different ZnO/BaO or BaF2/BaO ratio on structure of glasses. 相似文献
179.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
180.
Anti-BZ-Structure in Effect Algebras 总被引:1,自引:0,他引:1
The definitions of sharply approximating effect algebras, anti-BZ-effect algebras, central approximating effect algebras, and S-anti-BZ-effect algebras are given, the relationships between sharply approximating effect algebras and anti-BZ-effect algebras, between central approximating effect algebras and anti-BZ-effect algebras are established, and the set of anti-BZ-sharp elements in S-anti-BZ-effect algebras is proved to be an orthomodular lattice. 相似文献