氧气氛低温退火Pt/Ba0.8Sr0.2TiO3Pt引起的低频介电弛豫效应

研究了在不同温度区间氧气氛和氮气氛退火后处理对PtBa0.8Sr0.2TiO3Pt介电特性的影响.经过高温550℃氮气退火处理后,再放入350℃的氧气中退火,发现样品的介电特性出现了非常明显的低频弛豫现象,并且这种低频弛豫现象在350℃的氮气中退火后将会消失.通过在出现低频弛豫现象的样品的上下电极加一偏压,可以发现低频弛豫现象更加明显,并且在撤消偏压后这种增强将会逐渐减弱,直至最终恢复到偏压前的弛豫状态 关键词： 脉冲激光沉积 介电弛豫 动态随机存储器     

电子商务中人类活动的标度行为实证研究

应用去趋势波动分析法,对电子商务中人类网上购物行为进行研究,首次探讨了人类浏览及购买行为时间序列(数量波动)标度律.首先,研究发现人类网上购物行为呈现出明显的周期性,其时间序列的概率密度函数具有显著的双模态特征.其次,利用傅里叶变换方法分析浏览以及购买行为时间序列的功率谱,发现其演化过程不同于无关联的泊松过程.最后,基于功率谱过滤周期性趋势的影响,对去除周期趋势后的浏览和购买行为时间序列进行去趋势波动分析,发现其标度行为表明其具有较强的长程关联特性,且平均标度值近似为1,表明其具有自组织临界性.实证研究结果与其他领域如因特网交通流和金融市场价格波动的标度行为相似,有助于理解人类活动如何影响电子商务系统演化和提高在线商务活动效率,对分析电子商务中人类行为活动的机制和预测其波动趋势具有重要的启示作用.     

Why to synthesize vaterite polymorph of calcium carbonate on the cellulose matrix via sonochemistry process?

Vaterite is an important biomedical material due to its features such as high specific surface area, high solubility, high dispersion, and small specific gravity. The purposes of this article were to explore the growth mechanism of vaterite on the cellulose matrix via sonochmistry process. In the work reported herein, the influences of experimental parameters on the polymorph of calcium carbonate were investigated in detail. The calcium carbonate crystals on the cellulose matrix were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Experimental results revealed that all the reactants, solvent, and synthesis method played an important role in the polymorph of calcium carbonate. The pure phase of vaterite polymorph was obtained using Na₂CO₃ as reactant in ethylene glycol on the cellulose matrix via sonochmistry process. Based on the experimental results, one can conclude that the synthesis of vaterite polymorph is a system process.     

ZnO–SnO2 branch–stem nanowires based on a two-step process: Synthesis and sensing capability

ZnO–SnO₂ branch–stem nanostructures were realized on a basis of a two-step process. In step 1, SnO₂-stem nanowires were synthesized. In step 2, ZnO-branch nanowires were successfully grown on the SnO₂-stem nanowires through a simple evaporation technique. We have pre-deposited thin Au layers on the surface of SnO₂ nanowire stems and subsequently evaporated Zn powders on the nanowires. The ZnO branches, which sprouted from the SnO₂ stems, had diameters in a range of 30–35 nm. As-synthesized branches were of single crystalline hexagonal ZnO structures. Since the branch tips were comprised of Au-containing nanoparticles, the Au-catalyzed vapor–liquid–solid growth mechanism was more likely to control the growth process of the ZnO branches. To test a potential use of ZnO–SnO₂ branch–stem nanostructures in chemical gas sensors, their sensing performances with respect to NO₂ gas were investigated, showing the promising potential in chemical gas sensors.     

平均折射率为零的光子晶体中缺陷模频率特性的实验研究

利用传输线技术制备了左手材料,将左手材料与正常材料交替排列组合成平均折射率为零的一维光子晶体.该光子晶体在特定频段具有光子带隙,带隙不随晶格尺度和入射角的变化而改变.通过掺杂技术破坏光子晶体的周期性,可在禁带中引入缺陷模,这种结构的光子晶体可用于实现滤波器小型化和超强耦合.研究表明,通过调节缺陷的厚度可以控制缺陷模的频率,这为调节频率提供了一种方法.实验与仿真结果相符. 关键词： 左手材料 复合左右手传输线 光子晶体     

碳水混合物相互作用势及混合法则的实验研究和理论探索

 利用二级轻气炮加载技术研究了碳水混合物的冲击压缩特性。研究发现：冲击压力p低于19.0 GPa时,石墨与水混合物冲击压缩特性明显不同于金刚石与水混合物的冲击压缩特性;p大于23 GPa后,它们的特性十分接近;当p为52.9 GPa时,石墨与水混合物表现出反常的冲击压缩特性,压力增加而体积出现膨胀,这与高压下碳与水发生化学反应产生气体相关。还对碳水混合物的相互作用势及混合法则的选取进行了讨论。     

Effect of heat treatment on electronic phase in underdoped La2-xSrxCuO4 single crystal

Superconducting La1.937Sr0.063CuO4 crystals grown by the travelling-solvent floating-zone technique were thermally treated under various temperatures and oxygen pressures for moderately adjusting the oxygen content. The response of intrinsic electronic property of the crystals to the change of hole density in La2-xSrxCuO4 in the vicinity of the magic doping of x= 1/16 （= 0.0625） is studied in detail by magnetic measurements under various fields up to 1 T. It is found that when the superconducting critical temperature （Tc） increases with the oxygen content, there appears also a new subtle electronic state that can be detected from the differential curves of diamagnetic susceptibility dx/dT of the crystal sample. In contrast with the intrinsic state, the new subtle electronic state is very fragile under the magnetic fields. Our results indicate that a moderate change in oxygen doping does not significantly modify the intrinsic electronic state originally existing at the magic doping level.     

Size-refinement enhanced flexibility and electrochemical performance of MXene electrodes for flexible waterproof supercapacitors

Increasing mechanical flexibility without sacrificing electrochemical performance of the electrode mate-rial is highly desired in the design of flexible electro...