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排序方式: 共有380条查询结果,搜索用时 546 毫秒
31.
S.?VielEmail author D.?Capitani N.?Proietti F.?Ziarelli A.L.?Segre 《Applied Physics A: Materials Science & Processing》2004,79(2):357-361
High and low resolution solid state NMR methods have been applied to characterise a few samples of ancient wood. In an ancient larch wood sample, by applying 1H low resolution NMR methods as a function of the temperature, the average pore size and its distribution have been determined. In addition, high resolution NMR techniques have allowed addressing of the question of the proximity of water pools to cellulose and lignin. In particular, a model can be hypothesized in which water pools are surrounded by thin layers of amorphous cellulose and/or lignin while the crystalline domains of cellulose surround the layers of amorphous cellulose. Preliminary results obtained using a fully non invasive and portable NMR unilateral relaxometer, the Eureka-Mouse10 (EM10), are reported. This instrumentation is shown to be perfectly suitable for characterizing degradation in ancient wood samples. PACS 76.60 k 相似文献
32.
De Santis F Zona D Bellagotti R Vichi F Allegrini I 《Analytical and bioanalytical chemistry》2004,380(5-6):818-823
Ambient ozone was measured in a forest in Castelporziano (Italy) characterised by the prevailing presence of Holm-oak trees (Quercus ilex L.) from June to November 2003. Two methods for measuring ozone were used: long-term monitoring using diffusive samplers at three heights within the canopy, and continuous monitoring at two heights using the UV method. Results for one week mean ozone levels above and below the canopy from the diffusive samplers were compared to those obtained using the automatic analyser at the same levels. A good correlation between the two sampling techniques was found. Continuous monitoring showed a daily cycle with a midday maximum and a nocturnal minimum. While the forest floor consistently had the lowest ozone concentration, there were no differences during most daytime hours. The midday maximum is clearly due to downward mixing with O3-rich air from above. The night-time ozone decay within the canopy is the result of dry deposition of O3 and most likely due to reaction with biogenically produced NO. AOT40 within and above the canopy mostly exceeded the critical levels. 相似文献
33.
Carnosine (beta-alanyl-L-histidine) is a dipeptide regarded as an important molecular marker of the presence of processed animal proteins including meat and bone meal in animal feed. For its identification and quantification a sensitive and selective method by high-performance anion-exchange chromatography coupled with integrated pulsed amperometric detection (HPAEC-IPAD) was developed. The assay is based on isocratic elution with 100 mM NaOH as the mobile phase. Interferences of real matrices were efficiently removed; carnosine could be determined at the concentration ranges 0.1-100 microM with a rather low detection limit of 0.23 ng. Unlike feeds for dogs and cats, no carnosine peak was observed in all examined feeds for ruminants. The good analytical characteristics allowed camosine determination down to 5 microg/g of feed. 相似文献
34.
Battaglieri M Brunoldi M De Vita R Laget JM Osipenko M Ripani M Taiuti M Adams G Amaryan MJ Anciant E Anghinolfi M Armstrong DS Asavapibhop B Asryan G Audit G Auger T Avakian H Barrow S Beard K Bektasoglu M Berman BL Bersani A Bianchi N Biselli AS Boiarinov S Bouchigny S Bradford R Branford D Briscoe WJ Brooks WK Burkert VD Calarco JR Capitani GP Carman DS Carnahan B Cazes A Cetina C Cole PL Coleman A Cords D Corvisiero P Crabb D Crannell H Cummings JP DeSanctis E Degtyarenko PV Demirchyan R 《Physical review letters》2003,90(2):022002
The differential cross section, dsigma/dt, for omega meson exclusive photoproduction on the proton above the resonance region (2.6相似文献
35.
Thompson R Dytman S Kim KY Mueller J Adams GS Amaryan MJ Anciant E Anghinolfi M Asavapibhop B Auger T Audit G Avakian H Barrow S Battaglieri M Beard K Bektasoglu M Bertozzi W Bianchi N Biselli A Boiarinov S Bonner BE Briscoe WJ Brooks W Burkert VD Calarco JR Capitani G Carman DS Carnahan B Cole PL Coleman A Connelly J Cords D Corvisiero P Crabb D Crannell H Cummings J Day D Degtyarenko PV Demirchyan RA Dennis LC Deppman A De Sanctis E De Vita R Dhuga KS Djalali C Dodge GE Doughty D 《Physical review letters》2001,86(9):1702-1706
New cross sections for the reaction e p-->e p eta are reported for total center of mass energy W = 1.5--1.86 GeV and invariant momentum transfer Q2 = 0.25--1.5 (GeV/c)(2). This large kinematic range allows extraction of important new information about response functions, photocouplings, and eta N coupling strengths of baryon resonances. Newly observed structure at W approximately 1.65 GeV is shown to come from interference between S and P waves and can be interpreted with known resonances. Improved values are derived for the photon coupling amplitude for the S11(1535) resonance. 相似文献
36.
37.
Donatella Merlini 《Discrete Applied Mathematics》2008,156(5):627-646
We find the generating function counting the total internal path length of any proper generating tree. This function is expressed in terms of the functions (d(t),h(t)) defining the associated proper Riordan array. This result is important in the theory of Riordan arrays and has several combinatorial interpretations. 相似文献
38.
Nancy M. Edwards Donatella Peressini James E. Dexter Steven J. Mulvaney 《Rheologica Acta》2001,40(2):142-153
Linear viscoelastic properties (LVP) were determined for five durum wheat doughs and five common wheat doughs (representing
four different classes of Canadian common wheat) of different strength using creep testing. A creep time of 10,000 s was sufficient
to reach a state of steady state flow for all of the doughs. Creep compliances were analyzed in terms of a Burgers model.
For the durum doughs, the entire elastic compliance curve was shifted to higher values as the strength of the dough (as measured
by extensigraph) decreased, while the steady state viscosity increased with strength. For common wheat doughs, the elastic
compliance curves were steeper and the steady state viscosities were lower than for durum doughs of comparable extensigraph
strength. The retardation strengths associated with a maximum in the retardation spectra were lower for the stronger durum
doughs than for common wheat doughs of comparable strength. Differences in the LVP between durum and common wheat doughs of
similar extensigraph strength were interpreted in the context of physical gels with crosslinks and entanglements, whose contributions
to material properties are difficult to distinguish in short-time creep or dynamic measurements. The increased extensibility
of common wheat doughs relative to durum doughs of comparable extensigraph strength was attributed to a higher molecular weight
fraction in the polypeptide chains, similar in some respects to end-linked bimodal polymer networks. The idea of considering
these doughs as physical gels was supported by their stress relaxation behavior.
Received: 6 February 2000 Accepted: 22 August 2000 相似文献
39.
The metabolic profiling of kiwifruit (Actinidia deliciosa, Hayward cultivar) aqueous extracts and the water status of entire kiwifruits were monitored over the season (June-December) using nuclear magnetic resonance (NMR) methodologies. The metabolic profiling of aqueous kiwifruit extracts was investigated by means of high field NMR spectroscopy. A large number of water-soluble metabolites were assigned by means of 1D and 2D NMR experiments. The change in the metabolic profiles monitored over the season allowed the kiwifruit development to be investigated. Specific temporal trends of aminoacids, sugars, organic acids and other metabolites were observed.The water status of kiwifruits was monitored directly on the intact fruit measuring the T2 spin-spin relaxation time by means of a portable unilateral NMR instrument, fully non-invasive. Again, clear trends of the relaxation time were observed during the monitoring period.The results show that the monitoring of the metabolic profiling and the monitoring of the water status are two complementary means suitable to have a complete view of the investigated fruit. 相似文献
40.
Donatella Diana Dr. Barbara Ziaco Dr. Guido Scarabelli Dr. Carlo Pedone Prof. Giorgio Colombo Dr. Luca D. D'Andrea Dr. Roberto Fattorusso Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(18):5400-5407
The analysis of the folding mechanism in peptides adopting well‐defined secondary structure is fundamental to understand protein folding. Herein, we describe the thermal unfolding of a 15‐mer vascular endothelial growth factor mimicking α‐helical peptide (QKL10A) through the combination of spectroscopic and computational analyses. In particular, on the basis of the temperature dependencies of QKL10A Hα chemical shifts we show that the first phase of the thermal helix unfolding, ending at around 320 K, involves mainly the terminal regions. A second phase of the transition, ending at around 333 K, comprises the central helical region of the peptide. The determination of high‐resolution QKL10A conformational preferences in water at 313 K allowed us to identify, at atomic resolution, one intermediate of the folding–unfolding pathway. Molecular dynamics simulations corroborate experimental observations detecting a stable central helical turn, which represents the most probable site for the helix nucleation in the folding direction. The data presented herein allows us to draw a folding–unfolding picture for the small peptide QKL10A compatible with the nucleation–propagation model. This study, besides contributing to the basic field of peptide helix folding, is useful to gain an insight into the design of stable helical peptides, which could find applications as molecular scaffolds to target protein–protein interactions. 相似文献