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161.
The potential energy surfaces of the S(0) and S(1)(pi(*)<--pi) states of the 2-naphthol(H(2)O)(n), n is an element of {1,2} clusters were explored at the level of coupled cluster (CC2) response theory. In the electronic ground state two different types of hydrogen-bonding networks coexist for n=2, (i) a cyclic one [similar to those of the water trimer and phenol(H(2)O)(2)] where the hydroxy group of the aryl alcohol acts simultaneously as H donor for the first, and as H acceptor for the second water molecule, and (ii) a hydrogen-bonding arrangement where the aromatic pi system is taking over the role as H acceptor. In the S(1) state, on the other hand, the cyclic conformers are unstable. Consequently, the first group of cyclic ground state conformers gives rise to broad unstructured band shapes in the absorption spectrum, whereas the second group of conformers involving the aromatic pi system gives rise to nicely structured band shapes. Based on these results the puzzling absorption spectrum of the n=2 cluster can properly be interpreted. 相似文献
162.
Structural Design Principle of Small‐Molecule Organic Semiconductors for Metal‐Free,Visible‐Light‐Promoted Photocatalysis 下载免费PDF全文
Lei Wang Wei Huang Run Li Dr. Dominik Gehrig Prof. Paul W. M. Blom Prof. Katharina Landfester Dr. Kai A. I. Zhang 《Angewandte Chemie (International ed. in English)》2016,55(33):9783-9787
Herein, we report on the structural design principle of small‐molecule organic semiconductors as metal‐free, pure organic and visible light‐active photocatalysts. Two series of electron‐donor and acceptor‐type organic semiconductor molecules were synthesized to meet crucial requirements, such as 1) absorption range in the visible region, 2) sufficient photoredox potential, and 3) long lifetime of photogenerated excitons. The photocatalytic activity was demonstrated in the intermolecular C?H functionalization of electron‐rich heteroaromates with malonate derivatives. A mechanistic study of the light‐induced electron transport between the organic photocatalyst, substrate, and the sacrificial agent are described. With their tunable absorption range and defined energy‐band structure, the small‐molecule organic semiconductors could offer a new class of metal‐free and visible light‐active photocatalysts for chemical reactions. 相似文献
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Dr. Dominik Munz Dr. Jiaxiang Chu Dr. Mohand Melaimi Prof. Dr. Guy Bertrand 《Angewandte Chemie (International ed. in English)》2016,55(41):12886-12890
The synthesis of N‐heterocyclic carbene (NHC)–cyclic (alkyl)(amino) carbene (CAAC) heterodimers is presented. As the free carbenes do not react together in solution, the synthetic approach involves the addition of a free NHC to a cyclic iminium salt, which results in the formation of the protonated heterodimer. Subsequent deprotonation leads to the isolation of the corresponding mixed Wanzlick dimers. One‐ and two‐electron oxidations of these triazaolefins result in the formation of stable cationic radicals and bis(cations), respectively, which have been isolated and fully characterized. Cyclic voltammetry, UV/Vis spectroscopy, spin density, and DFT calculations suggest that these heterodimers feature complementary electronic properties to tetrathiafulvalenes (TTFs). 相似文献
165.
Dr. Roland Frach Patrick Kibies Saraphina Böttcher Tim Pongratz Steven Strohfeldt Simon Kurrmann Dr. Joerg Koehler Martin Hofmann Prof. Dr. Werner Kremer Prof. Dr. Hans Robert Kalbitzer Prof. Dr. Oliver Reiser Prof. Dr. Dominik Horinek Prof. Dr. Stefan M. Kast 《Angewandte Chemie (International ed. in English)》2016,55(39):11713-11713
166.
Dominik Lungerich David Reger Helen Hölzel René Riedel Max M. J. C. Martin Dr. Frank Hampel Prof. Dr. Norbert Jux 《Angewandte Chemie (International ed. in English)》2016,55(18):5602-5605
A novel rational synthetic pathway—the “functionalization of para‐nitroaniline” (FpNA)—provides substituted hexaarylbenzenes (HABs) with uncommon symmetries that bear up to five different substituents, fully avoiding regioisomeric product distributions during the reactions. 4‐Nitroaniline is functionalized by a cascade of electrophilic halogenations, Sandmeyer brominations, and Suzuki cross‐coupling reactions, leading to 26 substitution geometries, of which 18 structures are not available by the current established techniques. Furthermore, we demonstrate that this method is applicable to the bulk production of such systems on a multigram scale. Regarding optoelectronic properties, we demonstrate how highly functionalized HABs can show strong luminescent behavior, making these molecules very attractive to organic electronic devices. 相似文献
167.
We construct a family of shift spaces with almost specification and multiple measures of maximal entropy. This answers a question from Climenhaga and Thompson [Israel J. Math. 192 (2012), 785–817]. Elaborating on our examples we prove that sufficient conditions for every shift factor of a shift space to be intrinsically ergodic given by Climenhaga and Thompson are in some sense best possible; moreover, the weak specification property neither implies intrinsic ergodicity, nor follows from almost specification. We also construct a dynamical system with the weak specification property, which does not have the almost specification property. We prove that the minimal points are dense in the support of any invariant measure of a system with the almost specification property. Furthermore, if a system with almost specification has an invariant measure with non-trivial support, then it also has uniform positive entropy over the support of any invariant measure and cannot be minimal. 相似文献
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