Synthesis and antimycobacterial activity of purine conjugates with (S)-lysine and (S)-ornithine

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Synthesis and characterization of oxidized cellulose

Samples of oxidized cellulose (OC) with various carboxyl contents and degrees of crystallinity were obtained by the oxidation of native and mercerized cellulose with a solution of nitrogen(IV) oxide in CCl₄. A detailed characterization of these OC samples was performed. The effect of oxidation conditions (concentration of N₂O₄ in the solution and oxidation time) and starting cellulose material on OC characteristics (carboxyl, carbonyl and nitrogen content, degree of crystallinity and polymerization, surface area and swelling, and acidic properties) was investigated. Reactivity in the oxidation process was higher in mercerized cellulose than in native cellulose. The action of dilute solutions (10–15%) of N₂O₄ did not affect the degree of crystallinity of cellulose samples. Under these conditions, the oxidation took place mainly in amorphous regions and on the surface of crystallites. Oxidation in a concentrated (40%) N₂O₄ solution led to the destruction of crystallites, which increased the surface area and swelling of cellulose in water. The surface area and the swelling of OC samples increased with a decrease in the index of crystallinity. The acidic properties of OC were shown to increase with an increase of swelling in water. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4785–4791, 2004     

Branched Star-Type Polysilyllithium Compounds: The Effects of beta-Silyl Substitution and of Complexation on Their Molecular Structure

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Morphology-dependent photonic circuit elements

We theoretically propose and experimentally demonstrate the design of a novel one-dimensional ringlike macroscopic optical circuit element. The similarity between morphologies of an optical planar waveguide and a whispering-gallery axially symmetric solid-state resonator is used.     

Solitons in a medium with linear dissipation and localized gain

We present a variety of dissipative solitons and breathing modes in a medium with localized gain and homogeneous linear dissipation. The system possesses a number of unusual properties, like exponentially localized modes in both focusing and defocusing media, existence of modes in focusing media at negative propagation constant values, simultaneous existence of stable symmetric and antisymmetric localized modes when the gain landscape possesses two local maxima, as well as the existence of stable breathing solutions.     

Finite jet determination of local analytic CR automorphisms and their parametrization by 2-jets in the finite type case

We show that germs of local real-analytic CR automorphisms of a real-analytic hypersurface M in $\mathbb{C}$² at a point p M are uniquelydetermined by their jets of some finite order at p if and only if M is not Levi-flat near p. This seems to be the first necessary and sufficient result on finite jet determination and the first result of this kind in the infinite type case.If M is of finite type at p, we prove a stronger assertion: the local real-analytic CR automorphisms of M fixing p are analytically parametrized (and hence uniquely determined) by their 2-jets at p. This result is optimal since the automorphisms of the unit sphere are not determined by their 1-jets at a point of the sphere. The finite type condition is necessary since otherwise the needed jet order can be arbitrarily high [Kow1,2], [Z2]. Moreover, we show, by an example, that determination by 2-jets fails for finite type hypersurfaces already in $\mathbb{C)$³.We also give an application to the dynamics of germs of local biholomorphisms of $\mathbb{C)$².     

A Law of Large Numbers for the Zeroes of Heine–Stieltjes Polynomials

We determine the limiting density of the zeroes of Heine–Stieltjes polynomials (or of any set of points satisfying the conclusion of Heine–Stieltjes Theorem) in the thermodynamic limit and use this to prove a strong law of large numbers for the zeroes.     

Friction and diffusion of matter-wave bright solitons

We consider the motion of a matter-wave bright soliton under the influence of a cloud of thermal particles. In the ideal one-dimensional system, the scattering process of the quasiparticles with the soliton is reflectionless; however, the quasiparticles acquire a phase shift. In the realistic system of a Bose-Einstein condensate confined in a tight waveguide trap, the transverse degrees of freedom generate an extra nonlinearity in the system which gives rise to finite reflection and leads to dissipative motion of the soliton. We calculate the velocity and temperature-dependent frictional force and diffusion coefficient of a matter-wave bright soliton immersed in a thermal cloud.     

Time-dependent and outflow boundary conditions for Dissipative Particle Dynamics

We propose a simple method to impose both no-slip boundary conditions at fluid-wall interfaces and at outflow boundaries in fully developed regions for Dissipative Particle Dynamics (DPD) fluid systems. The procedure to enforce the no-slip condition is based on a velocity-dependent shear force, which is a generalized force to represent the presence of the solid-wall particles and to maintain locally thermodynamic consistency. We show that this method can be implemented in both steady and time-dependent fluid systems and compare the DPD results with the continuum limit (Navier-Stokes) results. We also develop a force-adaptive method to impose the outflow boundary conditions for fully developed flow with unspecified outflow velocity profile or pressure value. We study flows over the backward-facing step and in idealized arterial bifurcations using a combination of the two new boundary methods with different flow rates. Finally, we explore the applicability of the outflow method in time-dependent flow systems. The outflow boundary method works well for systems with Womersley number of O(1), i.e., when the pressure and flowrate at the outflow are approximately in-phase.