Structural and optical properties of porous iron oxide

The structural and optical properties of the novel porous iron oxide fabricated by wood template have been investigated. The obtained porous iron oxide was characterized to be α- Fe₂O₃ by Fourier transform infrared and Raman spectroscopy. X-ray absorption fine structure measurement revealed that the bond length of Fe-O₁ of the porous iron oxide has good agreement with that reported for the α- Fe₂O₃ crystal structure while the bond lengths for Fe-O₂ and Fe-Fe deviate slightly from those of the α- Fe₂O₃ crystal structure. Photoluminescence from the porous iron oxide exhibited broad emission bands around 760 and 890 nm, which are believed to be due to the unique nanoscale structure of the porous iron oxide.     

N2第二正带系发射光谱的理论计算及实验研究

本文利用分子光谱理论系统的计算和分析N₂第二正带系(C³∏_u→B³∏_g)的发射光谱, 以研究光谱强度的分布规律与不同温度条件和气体条件的关系. 基于N₂的三重态能级结构特性, 重点计算和讨论了发射光谱的概个重要参数: 通过求解高、低电子态的哈密顿矩阵得到了振转能级特性; 利用r质心近似法求取了能级间跃迁的电偶极矩函数和爱因斯坦跃迁概率; 进而计算了不同振动和转动温度条件下谱线的强度分布. 进行了N₂和Ar的混合放电实验, 利用实验光谱数据同理论结果进行拟合分析, 确定了N₂分子的振动温度和转动温度分别约为4300 K和800 K. 另外由于潘宁离化效应, N₂浓度减小时谱线强度呈现先增强后减弱的趋势. 实验结果很好的验证了N₂第二正带系光谱理论计算的正确性.     

镍基合金－碳化铬复合涂层耐磨特性的研究

用真空熔烧法在４５＃钢表面制取了镍基合金－碳化铬复合涂层，用扫描电子显微镜和Ｘ射线衍射仪分析了这种涂层的微观结构、物相组成和性能，并对这种涂层的耐磨特性进行了试验研究．结果表明：镍基合金－碳化铬复合涂层与底材形成了牢固的冶金结合，同时还含有较高比例的硬质相；碳化铬的加入使涂层的耐磨性显著提高，在给定的试验条件下分别于干摩擦和２０＃机械油润滑时，镍基合金－碳化铬复合涂层的耐磨性比４５＃钢的分别高５倍和１０倍以上     

Influence of incident light polarization on photonic nanojet

Dielectric microspheres can confine light in a three-dimensional (3D) region called photonic nanojet is shown when they are illuminated by different polarized beams. The influence of incident light polarization on photonic nanojet using the finite-difference time-domain (FDTD) method is demostrated. The axial field intensity profiles of photonic nanojets for both the linear and circular polarization incident beams are very similar. Azimuthal polarization incident beam induces a doughnut beam along the optical axis, while the radial polarization incident beam permits one to reach an effective volume as small as 0.7(λ/n) 3 .     

Permeability-frequency spectra of (Fe1−xcox)73.5Cu1Nb3Si13.5B9 nanocrystalline alloys under different magnetic fields

Under various amplitude of AC magnetic fields domain wall motion is the main mechanism in the magnetization process. This includes domain wall bulging and domain wall displacing. In this paper complex permeability-frequency spectra of (Fe_1−xCo_x)_73.5Cu₁Nb₃Si_13.5B₉ (x=0,0.5$x=0,0.5$) nanocrystalline alloys were measured as a function of the AC magnetic field, ranging from 0.001 to 0.04 Oe. Obvious changes have been found in complex permeability spectra for alloy x=0$x=0$ with the change of the amplitude of AC magnetic field, but variation of AC magnetic field has little effect on complex permeability spectra for alloy x=0.5$x=0.5$. This is attributed to the increased pinning field after substitution of Fe with Co in Fe_73.5Cu₁Nb₃Si_13.5B₉ nanaocrystalline alloy.     

数值模拟飞秒激光加热金属的热电子发射

研究了超短超强激光脉冲与薄膜靶相互作用中产生的电子热发射.当超短激光脉冲与薄膜靶相互作用时,首先入射超短脉冲激光对吸收深度内的自由电子进行热激发,接下来热激发电子将能量传递到附近的晶格,再通过电子和晶格二体系的热传导,以及电子晶格间的热耦合,将能量传递到材料的内部.因此,电子在皮秒级甚至更短的时间内不能与晶格进行能量耦合,使电子温度超出晶格温度很多,电子热发射就变得非常明显了.用双温方程联合Richardson-Dushman方程的方法对飞秒脉冲激光照射金属靶的电子热发射进行了研究,结果发现电子热发射对飞     

Nonlinear singular traveling waves in a slightly compressible thermo-hyperelastic cylindrical shell

Nonlinear Dynamics - In this paper, we present a novel methodology for nonlinear dynamic analysis of chemical processes that are posed as differential–algebraic equations (DAE) systems. With...     

变压器典型工作环境对声功率测量结果的影响

变压器两侧常建有高大的防火墙,其从声学角度可视为刚性反射壁面,会改变变压器的辐射声场,进而影响变压器声功率测量结果。本文利用有限元、边界元等数值计算方法建立了变压器声辐射的仿真模型用以分析反射壁面对变压器声功率测量结果的影响,并通过实际测量验证了仿真计算所得结论。结果表明,反射壁面对变压器声功率测量结果的影响程度随反射壁面到变压器箱体距离增加而减弱,且当反射壁面距变压器箱体5 m以上时,其对变压器声功率基频及各谐波成份测量结果的影响均在2 dB以内。另外反射壁面对变压器噪声高频成份声功率测量结果的影响较大,而对100 Hz、200 Hz等低频成份测量结果影响较小,基本低于3 dB。     

Synthesis of Derivatives of Pyrido[4,3‐d]pyrimidin‐4(3H)‐one via an Iminophosphorane

A series of new, 2‐substituted 3‐aryl‐8,9,10,11‐tetrahydro‐5‐methyl[1]benzothieno[3′,2′ : 5,6]pyrido[4,3‐d]pyrimidin‐4(3H)‐ones, compounds 5a – q , were designed and synthesized via the aza‐Wittig reaction as the key step. The iminophosphorane 1 reacted with phenyl isocyanate (or 4‐chlorophenyl isocyanate) to the carbodiimide 4 , which was cyclized to 5 upon addition of different amines, EtOH, or phenols in the presence of a catalytic amount of EtONa or K₂CO₃ (Schemes 1 and 2). The structures of compounds 5 were confirmed by IR, ¹H‐ and ¹³C‐NMR, EI‐MS, elemental analyses, and, in the case of 5l , by single‐crystal X‐ray diffraction (Figure).     

Parameter determination from current–voltage characteristics of HgCdTe photodiodes in forward bias region

Current–voltage characteristics of HgCdTe photodiodes in the forward bias region have been modeled considering mechanisms including drift-diffusion current, recombination current, metal-semiconductor contact and constant series resistance. Moreover, a fitting method based on the genetic algorithm has been developed to obtain values of related physical parameters from the measured dynamic resistance–voltage curves. Fitting results of $n^+$ -on- $p$ planar devices with different cutoff wavelengths are presented to illustrate the model and method, which are available and promising in acquiring device parameter values and evaluating the electrode contact quality.