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61.
Dimitri Chikhladze 《Journal of Pure and Applied Algebra》2011,215(9):2148-2153
We generalize Barr’s embedding theorem for regular categories to the context of enriched categories. 相似文献
62.
Ono RJ Suzuki Y Khramov DM Ueda M Sessler JL Bielawski CW 《The Journal of organic chemistry》2011,76(9):3239-3245
Coupling of various 4-substituted phenyl azides with two distinct quinone-containing N-heterocyclic carbenes (NHCs) afforded the respective mono- and ditopic 1,3-disubstituted acyclic triazenes in moderate to excellent yields (38-92%). Depending on their pendant substituents (derived from the azides), the acyclic triazenes exhibited intense absorptions in the visible spectrum (359-428 nm), which were bathochromically shifted by up to Δλ=68 nm upon reduction of the quinone moiety on the component derived from the NHC. Cyclic voltammetry confirmed that the aforementioned redox processes were reversible, and a related set of UV-vis spectroelectrochemical experiments revealed that bulk electrolysis may also be used to switch reversibly the colors exhibited by these triazenes. 相似文献
63.
64.
Polykarpos Porfyrakis Nikolaos L. Tsitsas Dimitri J. Frantzeskakis 《Mathematical Methods in the Applied Sciences》2019,42(18):7326-7334
A nonlinear (Kerr‐type) electromagnetic metamaterial, characterized by a double‐Lorentz model of its frequency‐dependent linear effective dielectric permittivity and magnetic permeability, is considered. The formation of gap solitons in the low‐ and high‐frequency band gaps of this metamaterial is investigated analytically. Evolution equations governing the gap solitons, of the form of a nonlinear Klein‐Gordon and a nonlinear Schrödinger equation, are obtained, and the structure of their solutions is discussed. 相似文献
65.
Ana Amić Zoran Marković Jasmina M. Dimitrić Marković Dejan Milenković Bono Lučić 《Molecular physics》2013,111(2):207-217
ABSTRACTParticipation of guaiacyl moiety of 3,5-dihydroxy-4-methoxybenzyl alcohol (DHMBA) in inactivation of free radicals was investigated using the DFT method. The thermodynamics of triple (3H+/3e?) free radical scavenging mechanisms was investigated. The Gibbs free energies of reactions of inactivation of selected 10 free radicals indicate DHMBA as a potent scavenger. Obtained results allow us to suggest that the contribution of guaiacyl moiety to antioxidant activity of phenolic compounds should be taken into account, what has been scarcely considered until now. 相似文献
66.
Jasmina M. Dimitrić Marković Dragan S. Veselinović Jelisaveta M. Baranac Tanja P. Brdarić 《光谱学快报》2013,46(3):104-115
Complexation of aluminum (III) with cyanidin, a natural anthocyanidin molecule, has been investigated in methanol and buffered solutions of pH 3.0 and 4.0. Electronic absorption spectroscopy was performed to characterize the stoichiometry and stability of the complexes formed. In investigated solvents, aluminum bonded moderately to cyanidin requiring large mole ratios of the components (up to 200) for the access of complexation. Molar ratio plots showed the formation of only one complex with stoichiometry aluminum (III):cyanidin of 1∶1 in both investigated media. Semiempirical calculations, performed in the Austin Model 1 parameterization, enabled the determination of the structural features of free compounds as well as complex structural modifications caused by chelation of Al(III). 相似文献
67.
Amir Omidvarnia Raphaël Ligeois Enrico Amico Maria Giulia Preti Andrew Zalesky Dimitri Van De Ville 《Entropy (Basel, Switzerland)》2022,24(8)
Measuring the temporal complexity of functional MRI (fMRI) time series is one approach to assess how brain activity changes over time. In fact, hemodynamic response of the brain is known to exhibit critical behaviour at the edge between order and disorder. In this study, we aimed to revisit the spatial distribution of temporal complexity in resting state and task fMRI of 100 unrelated subjects from the Human Connectome Project (HCP). First, we compared two common choices of complexity measures, i.e., Hurst exponent and multiscale entropy, and observed a high spatial similarity between them. Second, we considered four tasks in the HCP dataset (Language, Motor, Social, and Working Memory) and found high task-specific complexity, even when the task design was regressed out. For the significance thresholding of brain complexity maps, we used a statistical framework based on graph signal processing that incorporates the structural connectome to develop the null distributions of fMRI complexity. The results suggest that the frontoparietal, dorsal attention, visual, and default mode networks represent stronger complex behaviour than the rest of the brain, irrespective of the task engagement. In sum, the findings support the hypothesis of fMRI temporal complexity as a marker of cognition. 相似文献
68.
69.
Dimitri Leemans 《Proceedings of the American Mathematical Society》2006,134(12):3649-3651
Let , with an odd power of two. For each almost simple group such that , we prove that is not a C-group and therefore is not the automorphism group of an abstract regular polytope. For , we show that there is always at least one abstract regular polytope such that . Moreover, if is an abstract regular polytope such that , then is a polyhedron.
70.
Adams N De Gans BJ Kozodaev D Sanchez C Bastiaansen CW Broer DJ Schubert US 《Journal of combinatorial chemistry》2006,8(2):184-191
A methodology for the rapid design, screening, and optimization of coating systems with surface relief structures, using a combination of statistical experimental design, high-throughput experimentation, data mining, and graphical and mathematical optimization routines was developed. The methodology was applied to photopolymers used in photoembossing applications. A library of 72 films was prepared by dispensing a given amount of sample onto a chemically patterned substrate consisting of hydrophilic areas separated by fluorinated hydrophobic barriers. Film composition and film processing conditions were determined using statistical experimental design. The surface topology of the films was characterized by automated AFM. Subsequently, models explaining the dependence of surface topologies on sample composition and processing parameters were developed and used for screening a virtual 4000-membered in silico library of photopolymer lacquers. Simple graphical optimization or Pareto algorithms were subsequently used to find an ensemble of formulations, which were optimal with respect to a predefined set of properties, such as aspect ratio and shape of the relief structures. 相似文献