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981.
The spin-label method was used to study the structure and molecular motion of poly(ethylene oxide) (PEO) chains adsorbed on a silica-tethered poly(methyl methacrylate) (PMMA). Spin-labelled PEO with a narrow molecular weight distribution, having number averaged molecular weight (M N)=6.0×103, was adsorbed on the surface of the silica-tethered PMMA with various grafting ratios in carbon tetrachloride solution at 35?°C. ESR spectra were measured at various temperatures after the samples were completely dried. The ESR spectra are composed of two spectra arising from spin-labels attached to “train” and “tail” segments, which are strongly and weakly interacted with the silica surface, respectively. The fractional amount of the “tail” segments increases extremely with the grafting ratio of PMMA. Molecular mobility of the PEO chains estimated from the temperature dependence of the ESR spectra also decreases significantly with the grafting ratio of PMMA. Structure and molecular motion of the PMMA chains tethered on the silica were also studied using the spin-labelled PMMA. Consequently, parts of the PEO segments penetrate into the PMMA chains and is adsorbed on the silica surface (“train” segments), whereas parts of the PMMA segments protrude from the surface. The other PEO segments are entangled with the tethered PMMA chains (“tail” segments). 相似文献
982.
Let f be a function, continuous and real valued on the segment Δ, Δ ⊂ (−∞, ∞) and {Rn} be the sequence of the rational functions of best uniform approximation to f on Δ of order (n, n). In the present work,
the convergence of {Rn} in the complex plane is considered for the special caseswhen the poles (or the zeros, respectively) of {Rn} accumulate in the terms of weak convergence of measures to acompact set of zero capacity.
As a consequence, sufficient conditions for the holomorphic and the meromorphic continuability of f are given.
The work is supported by Project 69 with Ministry of Science and Education, Bulgaria. 相似文献
983.
D. Abbaneo P. Antilogus T. Behnke S.C. Blyth M. Elsing R. Faccini R.W.L. Jones K. Mönig S. Petzold R. Tenchini 《The European Physical Journal C - Particles and Fields》1998,4(2):185-191
Measurements of the forward-backward production asymmetry of heavy quarks in Z decays provide a precise determination of
. The asymmetries are sensitive to QCD effects, in particular hard gluon radiation. In this paper QCD corrections for and are discussed. The interplay between the experimental techniques used to measure the asymmetries and the QCD effects is
investigated using simulated events. A procedure to estimate the correction needed for experimental measurements is proposed,
and some specific examples are given.
Received: 26 February 1998 / Published online: 2 June 1998 相似文献
984.
Anupama Chaurasia Krishna K. Verma 《Fresenius' Journal of Analytical Chemistry》1995,351(2-3):335-337
2,4-Dinitrophenylhydrazine has been suggested as a new reagent for the flow-injection spectrophotometric determination of residual chlorine based on its oxidation to 2,4-dinitrophenyldiazonium ion. The measurement of the decrease in colour intensity under reversed flow-injection (reagent injection) conditions has been used for the determination of 0.1–10 mg/l Cl present as free or combined chlorine, and for its speciation. The limit of detection was 0.05 mg/l Cl. Copper (II), iron (III) and many other ions have been found not to vitiate the results. 相似文献
985.
986.
Summary For the numerical solution of non-stiff semi-explicit differentialalgebraic equations (DAEs) of index 1 half-explicit Runge-Kutta methods (HERK) are considered that combine an explicit Runge-Kutta method for the differential part with a simplified Newton method for the (approximate) solution of the algebraic part of the DAE. Two principles for the choice of the initial guesses and the number of Newton steps at each stage are given that allow to construct HERK of the same order as the underlying explicit Runge-Kutta method. Numerical tests illustrate the efficiency of these methods. 相似文献
987.
Summary Analysis of the in plane lateral collapse of square and rectangular cross-section tubes is presented by considering the out-of-straightness of horizontal and vertical arms, corner radius, friction between the platens and the deforming specimen and instability of vertical arms. Results of collapse load for tubes of aluminium and mild steel, thus computed, are presented for some typical tube geometrics, and influence thereon of various parameters considered is discussed. Experiments were conducted wherein tubes of square and rectangular cross-sections of both the materials were laterally compressed between two parallel platens in an Instron machine. The observed collapse loads compare very well with the corresponding computed values.
Kollaps von vertikal belasteten Rohren mit quadratischem und rechteckigem Querschmitt
Übersicht Der Kollaps von Rohren mit quadratischem und rechteckigem Querschnitt, welche senkrecht zur Achse belastet werden, wird untersucht, wobei schiefe Vertikal- und Horizontalstege, gerundete Profilecken, Reibung zwischen Belastungsplatten und Rohr sowie die Stabilität der Vertikalstege brücksichtigt werden. Die Kollapslast wird für Aluminium und Weichstahl und einige typische Rohrgeometrien ermittelt und der Einfluß verschiedener Parameter wird untersucht. Die Experimente wurden auf einer Instron-Maschine durchgeführt, wobei Rohre mit quadratischem und rechteckigem Querschnitt aus beiden Werkstoffen zwischen zwei parallelen Platten quer zur Achse komprimiert wurden. Es konnte eine gute Übereinstimmung zwischen den Resultaten aus Experiment und Rechnung festgestellt werden.相似文献
988.
989.
J. Telser H. -I. Lee E. T. Smith H. Huang P. Brereton M. W. W. Adams R. C. Conover M. K. Johnson B. M. Hoffman 《Applied magnetic resonance》1998,14(2-3):305-321
The hyperthermophilic archaeonPyrococcus furiosus contains a four-Fe ferredoxin (Pf- Fd) that differs from most other 4Fe-Fd’s in that its [Fe4S4] cluster is anchored to protein by only three cysteinyl residues.Pf- Fd also is of interest because in its reduced form, [Fe4S4]+, the cluster exhibits bothS = 1/2 andS = 3/2 spin states. Addition of excess cyanide ion converts the cluster exclusively to anS = 1/2 state (g1 = 2.09, g2 = 1.95, g3 = 1.92), however dialysis restores the EPR signal of native reduced protein indicating that the cluster is not irreversibly altered by cyanide. Both the native protein and protein in the presence of excess cyanide ion (Pf- Fd 4Fe-CN) were investigated here using the techniques of electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) spectroscopy. In particular,Pf- Fd 4Fe-CN was investigated using13CN? and C15N? ligands.13C and15N ENDOR indicated that a single cyanide ion bound directly, with the cluster showing an unusually small contact interaction (aiso(13C)~ ?3 MHz, aiso(15N) ~ 0). This is in contrast to cyanide bound to monomeric low-spin Fe(III)-containing proteins such as transferrin and myoglobin, for which the13C hyperfine coupling has a large isotropic component (aiso(13C) ≈ ?30 MHz). This small contact interaction is not due to low spin density of Fe, as57Fe ENDOR of the singly and triply labeledPf- Fd 4FeCN isotopologs, [57FeFe3S4]+ and [Fe57Fe3S4]+, show hyperfine coupling characteristic for [Fe4S4]+ clusters, particularly for the Fe to which cyanide binds. Thus, the low spin density on13C is not due to low spin density on the Fe ion to which it binds. Further theoretical work is needed to explain the contrast between the strong electronic effect of cyanide ion binding with the low spin density on the ligand. 相似文献
990.
Polyethers, which are produced by alcoholysis of oxiranes, are often used as solvents in chemical plants. The spectra of the products can be influenced by the choice of the catalyst (acid or base). The results of the base-catalyzed ethanolysis of 1,2-epoxybutane are displayed. The reaction was investigated calorimetrically by varying the molar ratio between ethanol and 1,2-epoxybutane, the starting temperature and the concentration of the catalyst sodium hydroxide. Additionally, the influence of the used alcohol will be shown in one example. To determine the activation parameters, the experiments were evaluated by the nonlinear software package TA-kin v3.3. 相似文献