The electrical and dielectrical behavior of n-conducting perylene tetracarboxylic diimide derivatives

A comparison of the electrical characteristics of organic field-effect transistors (OFETs) based on derivatives of the electron-conductor perylene tetracarboxylic diimide (PTCDI) in top-contact configuration is presented. The derivatives used are N,N′-dimethyl-3,4,9,10-perylene-tetracarboxylic-diimide (DiMe-PTCDI), N,N′-diphenyl-3,4,9,10-perylene-tetracarboxylic-diimide (DiPhenyl-PTCDI), N,N′-dimethoxyethyl-3,4,9,10-perylene-tetracarboxylic-diimide (DiMethoxyethyl-PTCDI), N,N′-di(3-pentyl)-3,4,9,10-perylene-tetracarboxylic-diimide (Di3Pentyl-PTCDI), and N,N′-diheptyl-3,4,9,10-perylene-tetracarboxylic-diimide (DiHeptyl-PTCDI). Current/voltage measurements were first performed in situ and later ex situ. Additionally, the effect of annealing and bias stress was probed in situ. A strong influence of the different side groups on the order of magnitude of the electron mobility is revealed, ranging from 4×10⁻⁶ cm²/V s for DiMethoxyethyl-PTCDI to 5×10⁻² cm²/V s for DiHeptyl-PTCDI. While none of the devices was stable in air after exposition to air, only the DiMe-PTCDI one resumed its functionality after restoring vacuum conditions. The dielectric functions of the derivatives was derived, additionally revealing optical isotropy for all films and varying surface roughness. While DiHeptyl-PTCDI and Di3Pentyl-PTCDI, yielding also the highest electron mobilities, form smooth layers with negligible surface roughness, strong island formation was be observed for DiPhenyl-PTCDI and DiMethoxyethyl-PTCDI, yielding low mobilities. This island growth was also confirmed by atomic force microscopy measurements. Ageing of the samples for several months under ambient conditions leads to increased roughness for the very rough samples. Layers with smooth surface, on the other hand, showed no significant change in the dielectric behavior of the sample.     

Phase transitions and ordering of confined dipolar fluids

We apply a modified mean-field density functional theory to determine the phase behavior of Stockmayer fluids in slit-like pores formed by two walls with identical substrate potentials. Based on the Carnahan-Starling equation of state, a fundamental-measure theory is employed to incorporate the effects of short-ranged hard-sphere-like correlations while the long-ranged contributions to the fluid interaction potential are treated perturbatively. The liquid-vapor, ferromagnetic-liquid-vapor, and ferromagnetic-liquid-isotropic-liquid first-order phase separations are investigated. The local orientational structure of the anisotropic and inhomogeneous ferromagnetic liquid phase is also studied. We discuss how the phase diagrams are shifted and distorted upon varying the pore width.     

Emerging molecular diversity from the intra-molecular Ugi reaction: iterative efficiency in medicinal chemistry

This review details a now established area within the isonitrile multi-component reaction (IMCR) field of study, namely employing bi-functional reagents in the Ugi reaction for the construction of screening sets with the additional element or even possibly ‘metric’ of enhanced ‘iterative efficiency potential’ The concept of ‘iterative efficiency’ will be briefly introduced, coupled with discussion on new synthetic routes to select bi-functional IMCR precursors and their use in the generation of pharmacologically relevant ‘molecular diversity’     

Vision of a fully laser-driven ${\sf n\gamma}{-}{\sf m\gamma}$ collider

The use is suggested of a laser-accelerated dense electron sheet with an energy of (E=[(g)\tilde] mc²E=\tilde{\gamma} mc^2) as a relativistic mirror to reflect coherently a second laser with photon energy ħω, generating by the Doppler boost high-energy γ photons with $ \hbar \omega ' = 4\tilde \gamma ^2 \hbar \omega $ \hbar \omega ' = 4\tilde \gamma ^2 \hbar \omega and short duration [A. Einstein, Annalen der Physik 17, 891 (1905); D. Habs et al., Appl. Phys. B 93, 349 (2008)]. Two of these counter-propagating γ beams are focused by the parabolically shaped electron sheets into the interaction region with small, close to diffraction-limited, spot size. Comparing the new nγ-mγ collider with former proposed γγ collider schemes we achieve the conversion of many photon-pairs in a small space-time volume to matter-antimatter particles, while in the other discussed setups only two isolated, much more high-energetic photons will be converted, reaching in the new approach much higher energy densities and temperatures. With a γ-field strength somewhat below the Schwinger limit we can reach this complete conversion of the γ bunch energy into e⁺e^- or quark-antiquark q[`(q)]q\bar{q}-plasmas. For a Bose-Einstein condensate (BEC) [A. Einstein, Physikalisch-mathematische Klasse (Berlin) 22, 261 (1924); A. Einstein, Physikalisch-mathematische Klasse (Berlin) 22, 3 (1925); A. Griffin, D.W. Snoke, S. Stringari, Bose-Einstein Condensation (Cambridge University Press, 1995)] final state or for the Cooper pair ground state at higher densities [A.J. Leggett, Quantum Liquids, Oxford Graduate Texts (Oxford University Press, 2006)] the strong induced transition into this coherent state is of special interest for single-cycle γ pulses. Due to annihilation these cold coherent states are very short-lived. For γ beams with photon energies of 1–10 keV the rather cold e<sup>+</sup>e<sup>-</sup>-plasma or e<sup>+</sup>e<sup>-</sup>-BEC expands to a cold dense aggregate of positronium (Ps) atoms, where the production of Ps molecules is discussed. For photon energies of 1–10 MeV we discuss the production of a cold induced π<sup>0</sup>-BEC followed by the formation of molecules. For the direct population of higher q[`(q)]q\bar{q} densities we can study condensates of color-neutral mesons with enhanced population. For a γγ collider with several-cycle laser pulses the following cycles heat up the fermion-antifermion f[`(f)]f\bar{f} system to a certain temperature. Thus we can reach high energy densities and temperatures of an e⁺e^-γ plasma, where the production of hadrons in general or the quark-gluon phase transition can be observed. Within the long-term goal of very high photon energies of about 1 GeV in the nγ-mγ-collider, even the electro-weak phase transition or SUSY phase transition could be reached.     

Inner-shell ionization of rotating linear molecules in the presence of spin-dependent interactions: Entanglement between a photoelectron and an auger electron

The complex dynamical behavior of the electron sheath in laser driven ion acceleration leads to variations in ion beam pointing and ion energy modulation. These processes are derived from high resolution particle spectroscopy and 2D-PIC simulations. The phenomena arise from ion source movement if laser irradiation occurs at oblique incidence. Different laser absorption processes act in dependence on laser parameter which determines the ion acceleration.     

"Ionic carbenes": synthesis, structural characterization, and reactivity of rare-Earth metal methylidene complexes

Treatment of mixed chloride tetramethylaluminate polynuclear clusters {Cp*Y[(mu-Me)2AlMe2](mu-Cl)}2 and {Cp*6La6[(mu-Me)3AlMe]4(mu3-Cl)2(mu2-Cl)6} with toluene/THF solutions produces "aluminum-free" methylidene complexes [Cp*3Ln3(mu-Cl)3(mu3-Cl)(mu3-CH2)(THF)3] (Ln = Y, La). The trinuclear methylidene complexes are isostructural in the solid state and feature a sterically well-shielded Schrock-type nucleophilic CH22- unit, which is prone to Tebbe-like methylenation reactions with ketones and aldehydes. The rapid polymerization of gamma-valerolactone reveals intrinsic rare-earth metal reactivity.     

Synthesis of thin Cr3Se4 films from modulated elemental reactants via two amorphous intermediates: a detailed examination of the reaction mechanism

The reaction of Cr/Se multilayers when they are annealed occurs in two steps: interdiffusion of the single layers to an amorphous Cr-Se alloy and crystallization of Cr3Se4. Both reaction steps were characterized using various techniques. At approximately 300 degrees C the layers have interdiffused completely to form a homogeneous amorphous Cr-Se alloy. Short-range order in the alloy was probed with X-ray absorption spectroscopy (XAS) and, according to the results of this, is already very similar to Cr3Se4, which crystallizes around 500 degrees C. Crystallization occurs at a well-defined temperature, whereas crystallite growth proceeds in the whole temperature interval above the crystallization temperature and is not finished at 660 degrees C. The reaction yields a polycrystalline thin film of Cr3Se4 in a preferred orientation exhibiting a (00l) texture. In Cr-rich samples amorphous Cr is present as a by-product. A Cr-Se/Se multilayer was observed as an intermediate in the interdiffusion of some Cr-rich samples which is stable between 200 and 250 degrees C.     

Forces between chemically structured substrates mediated by critical fluids

We consider binary liquid mixtures close to their critical points confined by two parallel, geometrically flat, and chemically structured substrates. Universal order parameter profiles are calculated within mean field theory for periodic patterns of stripes with alternating preferences for the two species of the mixture and with different relative positions of the two substrates. From the order parameter profiles the effective forces between the two plates are derived. The tuning of Casimir amplitudes is discussed.     

Relative Difference Sets and Hadamard Matrices from Perfect Quaternionic Arrays

Let \(G=\mathbf{C}_{n_1}\times \cdots \times \mathbf{C}_{n_m}\) be an abelian group of order \(n=n_1\dots n_m\), where each \(\mathbf{C}_{n_t}\) is cyclic of order \(n_t\). We present a correspondence between the (4n, 2, 4n, 2n)-relative difference sets in \(G\times Q_8\) relative to the centre \(Z(Q_8)\) and the perfect arrays of size \(n_1\times \dots \times n_m\) over the quaternionic alphabet \(Q_8\cup qQ_8\), where \(q=(1+i+j+k)/2\). In view of this connection, for \(m=2\) we introduce new families of relative difference sets in \(G\times Q_8\), as well as new families of Williamson and Ito Hadamard matrices with G-invariant components.     

High-intensity and high-brightness source of moderated positrons using a brilliant γ beam

Presently, large efforts are conducted toward the development of highly brilliant γ beams via Compton back scattering of photons from a high-brilliance electron beam, either on the basis of a normal-conducting electron linac or a (super-conducting) Energy Recovery Linac (ERL). Particularly, ERLs provide an extremely brilliant electron beam, thus enabling the generation of highest-quality γ beams. A 2.5 MeV γ beam with an envisaged intensity of 10¹⁵ photons s⁻¹, as ultimately envisaged for an ERL-based γ-beam facility, narrow band width (10⁻³), and extremely low emittance (10⁻⁴ mm² mrad²) offers the possibility to produce a high-intensity bright polarized positron beam. Pair production in a face-on irradiated W converter foil (200 μm thick, 10 mm long) would lead to the emission of 2×10¹³ (fast) positrons per second, which is four orders of magnitude higher compared to strong radioactive ²²Na sources conventionally used in the laboratory. Using a stack of converter foils and subsequent positron moderation, a high-intensity low-energy beam of moderated positrons can be produced. Two different source setups are presented: a high-brightness positron beam with a diameter as low as 0.2 mm, and a high-intensity beam of 3×10¹¹ moderated positrons per second. Hence, profiting from an improved moderation efficiency, the envisaged positron intensity would exceed that of present high-intensity positron sources by a factor of 100.