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991.
Two neutral group 15-pentaazides dmap-As(N(3))(5) (1) and dmap-Sb(N(3))(5) (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides. 相似文献
992.
Herbert Meier Michael Schmidt Axel Mayer Dieter Schollmeyer Bernhard Beile 《Journal of heterocyclic chemistry》2012,49(3):516-520
The reaction of benzothiete ( 1 ) and the bicyclic alkenes 5 , 7 , 9 , or 12 shows a very high π side selectivity (de > 95%) in the formation of the polycyclic thiopyrans 6 , 8 , 10 , 11 , 13 , and 14 . 相似文献
993.
Based on the new binuclear gold(I) complex [(AuCl)2(L1)] (1) (L1?=?2,3-bis(diphenylphosphino)maleic anhydride) four new polynuclear compounds were synthesized by reactions of 1 with E(SiMe3)2 (E?=?S, Se). During the formation of these new compounds the initial ligand L1 undergoes various transformations (e.g. substitution, hydration or hydrogenation) leading to the new ligands: trans-2,3-bis(diphenylphosphino)succinic anhydride (L2), 2-diphenylphosphino-3-mercapto-maleic anhydride anion (L3), 2-diphenylphosphino-3-selenolato-maleic anhydride anion (L4) and 2,3-bis(diphenylphosphino)succinic acid (L5). In case of using the sulfur species S(SiMe3)2 a pentanuclear cluster, [Au5(PPh2)3(L3)2] (2), and a 24-nuclear cluster, [Au24S6(PPh2)4(L3)8] (3), could be obtained. With Se(SiMe3)2 the binuclear complex, [(AuCl)2(L2)] (4), and the dodecanuclear cluster, [Au12Se4(L4)4(L5)2] (5), were yielded. 相似文献
994.
The existing combinatorial methods for iso-surface computation are efficient for pure visualization purposes, but it is known that the resulting iso-surfaces can have holes, and topological problems like missing or wrong connectivity can appear. To avoid such problems, we introduce a graph-theoretical method for the computation of iso-surfaces on cuboid meshes in ℝ3. (© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
995.
Alexander V. Virovets Irina V. Kalinina Vladimir P. Fedin Dieter Fenske 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(12):e589-e590
During an investigation of the W/Te/Br2 system, we prepared crystals of the title compound, C20H40N4S8Te, from acetonitrile solution by slow addition of diethyl ether. It appeared to be a new tetragonal modification. The calculated density of the tetragonal modification (1.513 Mg m?3) is slightly greater than found for the known orthorhombic modification (1.46 Mg m?3). The bond distances and angles are practically the same. 相似文献
996.
997.
In the present paper measured and simulated vibrations of viscoplastic plates under impulsive loadings are compared to each other. The aim is to determine how accurately the measured deformations can be calculated by the chosen constitutive and structural theories. The damage growth in the plate specimens until failure is predicted by finite element simulations and compared to shock tube experiments. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
998.
999.
Dietmar Appelhans Hartmut Komber Ralf Kirchner Jürgen Seidel Chih‐Feng Huang Dieter Voigt Dirk Kuckling Feng‐Chih Chang Brigitte Voit 《Macromolecular rapid communications》2005,26(8):586-591
Summary: Polypeptide‐shelled poly(propylene imine) dendrimers were realized by ring‐opening polymerization of α‐amino acid N‐carboxyanhydrides, initiated by dendrimers as core molecules. Polypeptides with 2nd generation core were used as model compounds to investigate interior complexes between metal ion and surface‐modified dendrimers. Micro‐calorimetric measurements outlined the formation of approximate 1:1 complexes between CuII and polypeptide‐shelled dendrimers and the influence of polypeptide chain compositions on differential molar heats of complexation.
1000.
This paper provides definitions for the evolutionary stability of sets of strategies based on simple fitness comparisons in the spirit of the definition of an evolutionarily stable strategy (ESS) by Taylor and Jonker (1978). It compares these with the set-valued notions of Thomas (1985d) and Swinkels (1992). Provided
only that the fitness function is analytic, our approach yields an alternative characterization of Thomas' evolutionarily stable sets (ES Sets) which does not rely on the structure or topology of the underlying strategy space. Moreover, these sets are shown to have
a very special geometric structure and to be finite in number. For bimatrix games ES Sets are shown to be more uniformly robust
against mutations than apparent from the definition and hence to be equilibrium evolutionarily stable sets in the sense of Swinkels (1992).
Received November 1995/Final version December 2000 相似文献