White-light Detection for Nanoparticle Sizing with the TSI Ultrafine Condensation Particle Counter

Several of the most common methods for measuring nanoparticle size distributions employ the ultrafine condensation particle counter (UCPC) for detection purposes. Among these methods, the pulse height analysis (PHA) technique, in which the optical response of the UCPC detector is related to initial particle diameter in the 3–10nm range, prevails in applications where fast sampling is required or for which concentrations of nanoparticles are frequently very low. With the PHA technique, white light is required for particle illumination in order to obtain a monotonic relationship between initial particle diameter and optical response (pulse height). However, the popular, commercially available TSI Model 3025A UCPC employs a laser for particle detection. Here, we report on a novel white-light detection system developed for the 3025A UCPC that involves minimal alteration to the instrument and preserves normal counting operation. Performance is illustrated with pulse height spectra produced by differential mobility analyzer (DMA) – generated calibration aerosols in the 3–50nm range.     

A single crystal X-Ray diffraction analysis of 1,9-dihydro[1] benzothiopyrano[4,3-c] pyrazole 5,5-dioxide

The structure of 1,4-rlihydro[1 ]benzothiopyrano[4,3-c ]pyrazole 5,5-dioxide was determined by single crystal x-ray diffraction. The molecule crystallizes in space group P2₁/c with a = 13.4378(6), b = 5.5938(3), c = 12.9837(6)Å, and β = 103.831°. The final R value is 0.083. Surprisingly, the tautomer with N(2)-H exists in the crystal with the pyrazole ring being planar. The entire system is not planar as the benzene ring is rotated about C(9a) and C(9b) with respect to the pyrazole ring. In the crystal structure the pyrazole exists as hydrogen-bonded dimers with two molecules related by a center of symmetry.     

Liganden-Eigenschaften von Oberflächen-Silanol-gruppen. I. Oberflächen-Komplexbildung mit Fe3+, Cu2+, Cd2+ und Pb2+

Ohne Zusammenfassung     

A highly selective catalytic method for the oxidative functionalization of C-H bonds

This communication describes a new and highly practical Pd(II)-catalyzed method for the regio- and chemoselective oxidative functionalization of arenes and alkanes. Carbon-hydrogen bonds of substrates that contain a variety of directing groups (e.g., pyridine, azobenzene, pyrazole, and imine derivatives) are selectively transformed into esters, ethers, and aryl-halides under mild conditions. The scope of this reaction in terms of substrate, directing group, and oxidant is described, and a preliminary catalytic cycle is proposed.     

Direct wiring of cytochrome c's heme unit to an electrode: electrochemical studies

A novel strategy for the immobilization of cytochrome c on the surface of chemically modified electrodes is demonstrated and used to investigate the protein's electron-transfer kinetics. Mixed monolayer films of alkanethiols and omega-terminated alkanethiols (terminated with pyridine, imidazole, or nitrile groups that are able to ligate with the heme) are used to adsorb cytochrome c to the surface of gold electrodes. The use of mixed films, as opposed to pure films, allows the concentration of adsorbed cytochrome to remain dilute and ensures a higher degree of homogeneity in their environment. The adsorbed protein is studied using electrochemical methods and scanning tunneling microscopy.     

Precise Measurement of Muon Capture on the Proton

The aim of the μCap experiment is a 1% measurement of the singlet capture rate Λ _S for the basic electro-weak reaction μ + p → n + ν_μ. This observable is sensitive to the weak form-factors of the nucleon, in particular to the induced pseudoscalar coupling constant g _P . It will provide a rigorous test of theoretical predictions based on the Standard Model and effective theories of QCD. The present method is based on high precision lifetime measurements of μ⁻ in hydrogen gas and the comparison with the free μ⁺ lifetime. The μ⁻ experiment will be performed in ultra-clean, deuterium-depleted H₂ gas at 10 bar. Low density compared to liquid H₂ is chosen to avoid uncertainties due to ppμ formation. A time projection chamber acts as a pure hydrogen active target. It defines the muon stop position in 3D and detects rare background reactions. Decay electrons are tracked in cylindrical wire-chambers and a scintillator array covering 75% of 4π. This revised version was published online in August 2006 with corrections to the Cover Date.     

Smolyak algorithms based on digital (t, α, d)-sequences for multivariate integration

We use so-called (t, α, d)-sequences and Smolyak's algorithm to construct d × l -dimensional integration rules with optimal convergence rates in a suitable function space. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)