Imidazolriazole and oxazolotriazole analogs of midafltir |4-amino-2,2,5,5, -tetrakis(trifluoromethyl)-3-imidazolin|

Imidazotriazole (5) and oxazolotriazole (10) analogs of CNS depressant 4-amitio-2,2,5,5-tetrakis(trifluoromethyl)-3-imidazoline (miduflur) were prepared and found to he much less active.     

Brillouin spectra of liquid mixtures of phytol in carbontetrachloride and toluene

Measurements of Ar ion laser excited Rayleigh-Brillouin spectra of liquid phytol-carbontetrachloride and phytoltoluene mixtures were performed and used to calculate the hypersonic velocities. Therefrom it seems that the behaviour of the solutions is close to “ideal”.     

Total synthesis of acosamine and daunosamine utilizing a diastereoselective intramolecular [3+2] cycloaddition

A total synthesis of daunosamine (3) and acosamine (4) has been accomplished via a diastereoselective intramolecular nitrone-olefin cyclization. In the key step the chiral nitrone 12a cyclized to give two isoxazolidines 13a and 14a in an 82:18 ratio. Further elaboration of 13a led to daunosamine and acosamine. The effects of olefin substitution on the diastereoselectivity of the cycloaddition was also examined.     

Difference equations in statistical mechanics. I. Cluster statistics models

A review and some new results are presented for several cluster statistics models, solutions of which can be reduced to difference equations. Mathematical techniques suitable for solving these equations are surveyed.     

Some regularities within the Stark widths and shifts of resonance ion lines from Li to Ca

A periodic dependence of the Stark widths and shifts of resonance lines, for singly- and doubly-ionized elements, has been found on nuclear charge number Z. These periodicities were found for Griem's theoretical values of the Stark parameters of resonance lines of some singly charged ions from Li to Ca; for other singly- and doubly- charged ions, this parameter was calculated from Griem's semiempirical formula. The dependence of the Stark parameters of the resonance lines on atomic polarizability X has been determined and used to estimate Stark widths and shifts for other singly-charged ions. These values are compared with estimates derived form Griem's semiempirical formula for the Gaunt factor g = 0.2.     

Baryon poles in proton decay amplitudes

The decay rate of the p→π⁰e⁺ mode is calculated in SU(5) grand unified theory using a pole model with proton and $\text{1}\text{2}{}^{\mathrm{?}}$ baryon poles. Baryon-to-vacuum amplitudes are calculated in the framework of the MIT bag model. It is found that the partial decay rate [～(5×10³¹ yr)^?)] is close to the partial decay rates calculated by different methods.     

Beiträge zur Ringofenmethodik. V

Zusammenfassung Nach Abtrennung von Cu(II)-Ionen mit Hilfe der Ringofentechnik ist es möglich, Ultramikromengen Kupfer(II) mit 0,001-m ÄDTA gegen PAN als Indikator zu titrieren. Eine dazu geeignete Arbeitsweise wird angegeben.

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Contributions to the ring furnace methodology. V

Summary Following separation of the Cu(II) ions with the aid of the ring furnace technique, it is possible to titrate ultramicro amounts of copper(II) with 0.001M EDTA in the presence of PAN as indicator. A suitable procedure is given.

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IV. Teil: Mikrochim. Acta [Wien]1969, 25.     

Non-conservation of quasiparticles

An adequate canonical transformation of the hamiltonian permitted the full observance of the specific Pauli commutation relations and the elimination of the main quasiparticle non-conservative term. This will allow a correct treatment of the kinematic part of the interaction in many problems.