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41.
J. M. Criado L. A. Pérez-Maqueda M. J. Diánez P. E. Sánchez-Jiménez 《Journal of Thermal Analysis and Calorimetry》2007,87(1):297-300
The SCTA method implies to control the temperature in such a way that
the reaction rate changes with the time according to a function previously
defined by the user. Constant Rate Thermal Analysis (CRTA) is one of the most
commonly used SCTA methods and implies achieving a temperature profile at
which the reaction rate remains constant all over the process at a value previously
selected by the user. This method permits to minimize the influence of heat
and mass transfer phenomena on the forward reaction. The scope of this work
is to develop a universal CRTA temperature controller that could be adapted
to any thermoanalytical device. The thermoanalytical signal is programmed
to follow a preset linear trend by means of a conventional controller that
at the time controls a second conventional temperature programmer that forces
the temperature to change for achieving the trend programmed for the thermoanalytical
signal. Examples of the performance of this control system with a Thermobalance
and a Thermomechanical Analyser (TMA) are given. 相似文献
42.
In this paper we present several results about local MV-algebras, extending existing results given for MV-chains. The role
of local MV-algebras in sheaf representation and weak boolean product is stressed and the relationship of local MV-algebras
with varieties of MV-algebras is analyzed.
Presented by S. Pulmannova.
Received November 11, 2005; accepted in final form December 20, 2005. 相似文献
43.
In this paper we study a Ginzburg–Landau model which describes the behaviour of a superconducting material including thermal effects. We extend the traditional formulation of the problem, by introducing the temperature as an additional state variable. Accordingly, together with the Gor’kov–Eliashberg system, we introduce an evolution equation for the absolute temperature. We examine in detail the case which allows only variations of the concentration of superconducting electrons and of the temperature, neglecting the electromagnetic field. For this problem existence and uniqueness of the solution are shown. Finally we analyze the asymptotic behaviour of the solutions, proving that the system possesses a global attractor. 相似文献
44.
45.
Supply Chain Management (SCM) is an important activity in all producing facilities and in many organizations to enable vendors,
manufacturers and suppliers to interact gainfully and plan optimally their flow of goods and services. To realize this, a
dynamic modelling approach for characterizing supply chain activities is opportune, so as to plan efficiently the set of activities
over a distributed network in a formal and scientific way. The dynamical system will result so complex that it is not generally
possible to specify the functional forms and the parameters of interest, relating outputs to inputs, states and stochastic
terms by experiential specification methods. Thus the algorithm that will presented is Data Driven, determining simultaneously
the functional forms, the parameters and the optimal control policy from the data available for the supply chain. The aim
of this paper is to present this methodology, by considering dynamical aspects of the system, the presence of nonlinear relationships
and unbiased estimation procedures to quantify these relations, leading to a nonlinear and stochastic dynamical system representation
of the SCM problem. Moreover, the convergence of the algorithm will be proved and the satisfaction of the required statistical
conditions demonstrated. Thus SCM problems may be formulated as formal scientific procedures, with well defined algorithms
and a precise calculation sequence to determine the best alternative to enact. A “Certainty equivalent principle” will be
indicated to ensure that the effects of the inevitable uncertainties will not lead to indeterminate results, allowing the
formulation of demonstrably asymptotically optimal management plans. 相似文献
46.
We introduce a general scheme to realize perfect storage of quantum information in systems of interacting qubits. This novel approach is based on global external controls of the Hamiltonian that yield time-periodic inversions in the dynamical evolution allowing a perfect periodic quantum state reconstruction. We illustrate the method in the particularly interesting and simple case of spin systems affected by XY residual interactions with or without static imperfections. The global control is achieved by step time inversions of an overall topological phase of the Aharonov-Bohm type. Such a scheme holds both at finite size and in the thermodynamic limit, thus enabling the massive storage of arbitrarily large numbers of local states, and is stable against several realistic sources of noise and imperfections. 相似文献
47.
Debora Di Caprio 《Topology and its Applications》2006,153(14):2680-2702
We introduce and study some completeness properties for systems of open coverings of a given topological space. A Hausdorff space admitting a system of cardinality κ satisfying one of these properties is of type Gκ. Hence, we define several new variants of the ?ech number and use elementary submodels to determine further results. We introduce M-hulls and M-networks, for M elementary submodel. As an application, we give estimates for both the tightness and the Lindelöf number of a generic upper hyperspace. Two recent results of Costantini, Holá and Vitolo on the tightness of co-compact hyperspaces follow from ours as corollaries. 相似文献
48.
M. A. Macrì C. Del Gratta L. Di Donato S. Di Luzio G. L. Romani S. Della Penna A. Pasquarelli 《Il Nuovo Cimento D》1994,16(5):425-432
Summary A preliminary study is here reported on a new potential marker for biomagnetic measurements. The marker consists of superparamagnetic
polymer microspheres which were detected in the presence of external steady magnetic fields by means of an r.f.-SQUID magnetometer.
The particles were prepared in samples differing in the concentration value and immersed in a homogeneous magnetic field of
variable intensity. A simple model was taken into account for the distribution of the microspheres in the samples, so that
the theoretical values were compared to the marker field values measured by the biomagnetic sensor. The overall sensitivity
of the experimental apparatus and the minimum concentration value of the marker were then estimated. 相似文献
49.
Summary Differential scanning calorimetric measurements in the early stage of isothermal crystal growth of polyethylene oxide are
analysed in the light of irreversible thermodynamics. An accurate evaluation of the equilibrium melting temperature is done
by fitting the thermograms obtained at different undercoolings and referring to the activation energy values already known
from the literature.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献
50.
Summary The role of chemical reactions in the selection of patterns in phase-separating mixtures is presented. Linearized theory and
computer simulation show that the initial long-wavelength instability characteristic of spinodal decomposition is suppressed
by chemical reactions, which restrict domain growth to intermediate length scales even in the late stages of phase separation.
Our findings suggest that chemical reactions may provide a novel way to stabilize and tune the steady-state morphology of
phase-separating materials.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献