A multistate switchable [3]rotacatenane

Rotacatenanes are exotic molecular compounds that can be visualized as a unique combination of a [2]catenane and a [2]rotaxane, thereby combining both the circumrotation of the ring component (rotary motion) and the shuttling of the dumbbell component (translational motion) in one structure. Herein, we describe a strategy for the synthesis of a new switchable [3]rotacatenane and the investigation of its switching properties, which rely on the formation of tetrathiafulvalene (TTF) radical π-dimer interactions-namely, the mixed-valence state (TTF(2) )(+.) and the radical-cation dimer state (TTF(+.) )(2) -under ambient conditions. A template-directed approach, based on donor-acceptor interactions, has been developed, resulting in an improved yield of the key precursor [2]catenane, prior to rotacatenation. The nature of the binding between the [2]catenane and selected π-electron-rich templates has been elucidated by using X-ray crystallography and UV/Vis spectroscopy as well as isothermal titration microcalorimetry. The multistate switching mechanism of the [3]rotacatenane has been demonstrated by cyclic voltammetry and EPR spectroscopy. Most notably, the radical-cation dimer state (TTF(+.) )(2) has been shown to enter into an equilibrium by forming the co-conformation in which the two 1,5-dioxynaphthalene (DNP) units co-occupy the cavity of tetracationic cyclophane, thus enforcing the separation of TTF radical-cation dimer (TTF(+.) )(2) . The population ratio of this equilibrium state was found to be 1:1. We believe that this research demonstrates the power of constructing complex molecular machines using template-directed protocols, enabling us to make the transition from simple molecular switches to their multistate variants for enhancing information storage in molecular electronic devices.     

Rational assembly of soluble copper(II) phosphonates: synthesis, structure and magnetism of molecular tetranuclear copper(II) phosphonates

The reactions of the dinuclear copper complexes [Cu(2)(L)(OAc)] [H(3)L = N,N'-(2-hydroxypropane-1,3-diyl)bis(salicylaldimine) or [Cu(2)(L')(OAc)] (H(3)L' = N,N'-(2-hydroxypropane-1,3-diyl)bis(4,5-dimethylsalicylaldimine)] with various phosphonic acids, RPO(3)H(2) (R = t-Bu, Ph, c-C(5)H(9), c-C(6)H(11) or 2,4,6-i-Pr(3)-C(6)H(2)), leads to the replacement of the acetate bridge affording tetranuclear copper(II) phosphonates, [Cu(4)(L)(2)(t-BuPO(3))](CH(3)OH)(2)(C(6)H(6)) (1), [Cu(4)(L)(2)(PhPO(3))(H(2)O)(2)(NMe(2)CHO)](H(2)O)(2) (2), [Cu(4)(L')(2)(C(5)H(9)PO(3))](CH(3)OH)(2) (3), [Cu(4)(L')(2)(C(6)H(11)PO(3)](MeOH)(4)(H(2)O)(2) (4) and [Cu(4)(L')(2)(C(30)H(46)P(2)O(5))](PhCH(3)) (5). The molecular structures of 1-4 reveal that a [RPO(3)](2-) ligand is involved in holding the four copper atoms together by a 4.211 coordination mode. In 5, an in situ formed [(RPO(2))(2)O](4-) ligand bridges two pairs of the dinuclear subunits. Magnetic studies on these complexes reveal that the phosphonate ligand is an effective conduit for magnetic interaction among the four copper centers present; a predominantly antiferromagnetic interaction is observed at low temperatures.     

A comparison of generalized multinomial logit and latent class approaches to studying consumer heterogeneity with some extensions of the generalized multinomial logit model

We calibrate and contrast the recent generalized multinomial logit model and the widely used latent class logit model approaches for studying heterogeneity in consumer purchases. We estimate the parameters of the models on panel data of household ketchup purchases, and find that the generalized multinomial logit model outperforms the best‐fitting latent class logit model in terms of the Bayesian information criterion. We compare the posterior estimates of coefficients for individual customers based on the two different models and discuss how the differences could affect marketing strategies (such as pricing), which could be affected by applying each of the models. We also describe extensions to the scale heterogeneity model that includes the effects of state dependence and purchase history. Copyright © 2011 John Wiley & Sons, Ltd.     

Genetic algorithm-tuned entropy-based fuzzy C-means algorithm for obtaining distinct and compact clusters

A modified approach had been developed in this study by combining two well-known algorithms of clustering, namely fuzzy c-means algorithm and entropy-based algorithm. Fuzzy c-means algorithm is one of the most popular algorithms for fuzzy clustering. It could yield compact clusters but might not be able to generate distinct clusters. On the other hand, entropy-based algorithm could obtain distinct clusters, which might not be compact. However, the clusters need to be both distinct as well as compact. The present paper proposes a modified approach of clustering by combining the above two algorithms. A genetic algorithm was utilized for tuning of all three clustering algorithms separately. The proposed approach was found to yield both distinct as well as compact clusters on two data sets.     

Structural-acoustic modeling for three-dimensional freefield and littoral environments with verification and validation

This paper describes a high-order, finite-element-based, three-dimensional time-harmonic model for large-scale exterior structural-acoustics problems. It is applicable to both freefield and littoral environments. For the freefield case, the infinite exterior is treated as a homogeneous linear acoustic medium. For littoral applications, the water or air and the sediment domains are each treated as linear homogeneous, semi-infinite half-spaces with piecewise-constant properties. Both domains admit complex-valued wave speeds to enable the inclusion of damping. The finite element formulation uses a variational statement which naturally incorporates the transmission-condition at the water or air-sediment interface. The truncation of the infinite exterior is realized using an infinite-element for the freefield case, and the perfectly-matched-layer approximation for littoral applications. Computation of the farfield quantities is done based on an integral representation which, for the littoral cases, uses efficient approximations for the appropriate Green's function. Numerical computations are presented for a series of progressively more complex problems, and are used to verify the model against analytic and other numerical solutions and validate it based on the experimental data for scattering from elastic scatterers as measured in freefield and sediment pool laboratory facilities.     

Catalytic activity of an iron(III) Schiff base complex bound in a polymer resin

An iron(III)–ferrocene complex and its heterogeneous analogue bound in a polymer resin have been prepared and employed as catalysts for the oxidation of various organic substrates. Characterization of the heterogeneous and homogeneous complexes was done by SEM, EDAX, TGA, FT-IR, DRS-UV, and spectroscopy. The catalyst’s activity, stability, and reusability were investigated through industrially relevant oxidation reactions. The solid iron(III)–ferrocene Schiff base complex gave more effective results than the solid-supported ferrocene Schiff base ligand. The antimicrobial activities of the molecular complex and free ligand were studied for Gram-positive and Gram-negative bacteria.     

POM‐Catalyzed In Situ Ligand Synthesis for the Construction of Metal Complexes and Their Use in the Formation of Coordination Polymers

Six organic–inorganic hybrid materials were synthesized by the in situ oxidation of neocuproine by using MoO₃/Na₂MoO₄ as the catalyst in the presence of Cu(NO₃)₂. The crystal structures of Mo8‐Cu4‐PHEN and Mo8‐Cu2‐5(2PIC) are composed of [Mo₈O₂₆]^4? polyoxometalate (POM) units, whereas the crystal structure of Mo6‐Cu‐COPHEN is composed of a [Mo₆O₁₉]^2? POM unit; both POM units could be considered as the active form of the catalyst. Reaction of the hybrid materials with 1,3,5‐benzenetricarboxylic acid (BTC) resulted in the formation of two different coordination polymers (CPs) under different reaction conditions. These CPs, depending on their structural attributes, exhibit distinct differences in the adsorption of H₂, CO₂, and water. The use of 2‐methylpyridine instead of neocuproine does not give any oxidation products under the same reaction conditions due to the incorrect positioning of the methyl group with respect to the Cu^II center.     

Surface plasmon enhanced ultra-low threshold second harmonic generation in periodically poled whispering gallery resonator

The surface plasmon enhanced ultra-low threshold second harmonic generation is observed, designed and simulated in whispering gallery resonator made of MgO doped periodically poled LiNbO₃. Here the electric field associated with incident optical radiation of picowatt level is amplified to milliwatt level through surface plasmon resonance in Kretschmann geometry which is formed by a BK₇ prism plane, 29 nm thin gold layer and 20 nm thin GaAs layer. This enhanced electric field then coupled to a whispering gallery resonator, which facilitated the generation of second harmonic for an incident laser radiation of picowatt level. In this proposed configuration with an incident optical power of 94.6 pW, generated second harmonic through whispering gallery resonator is found to be 14.6 mW.     

Exclusive Detection of Sub‐Nanomolar Levels of Palladium(II) in Water: An Excellent Probe for Multiple Applications

A new colorimetric probe has been developed for the detection and estimation of Pd^II at sub‐nanomolar concentrations. The probe consisted of rhodamine (signaling unit), which was linked with a bis‐picolyl moiety (binding site) through a phenyl ring. Pd^II induced opening of the spirolactam ring of the probe with the generation of a prominent pink color. The excellent selectivity of the probe towards Pd^II over Pd⁰ or Rh^II ensured its potential utility for the detection of residual palladium contamination in pharmaceutical drugs and in Pd‐catalyzed reactions. The probe showed a “turn‐on” (bright yellow) fluorescence upon the addition of Pd^II, which made it suitable for the detection of Pd contaminants in mammalian cells.