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11.
Uzun O Sanyal A Nakade H Thibault RJ Rotello VM 《Journal of the American Chemical Society》2004,126(45):14773-14777
Polystyrene functionalized with diamidopyridine (DAP) recognition units self-assembles in nonpolar media to form thermally reversible micrometer-scale spherical aggregates. The size and the thermal stability of these microspheres can be controlled by the molecular weight of the polymer. The addition of thymine-functionalized polymer to these self-assembled microspheres converted them into vesicular aggregates with a controlled size. The morphology change was reversible: the addition of DAP-functionalized polymer converted the vesicles back to microspheres. 相似文献
12.
Simultaneous quantification of atenolol and chlorthalidone in human plasma by ultra‐performance liquid chromatography–tandem mass spectrometry
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Jaivik V. Shah Daxesh P. Patel Priyanka A. Shah Mallika Sanyal Pranav S. Shrivastav 《Biomedical chromatography : BMC》2016,30(2):208-216
A simple, sensitive and reproducible ultra‐performance liquid chromatography–tandem mass spectrometry method has been developed for the simultaneous determination of atenolol, a β‐adrenergic receptor‐blocker and chlorthalidone, a monosulfonamyl diuretic in human plasma, using atenolol‐d7 and chlorthalidone‐d4 as the internal standards (ISs). Following solid‐phase extraction on Phenomenex Strata‐X cartridges using 100 μL human plasma sample, the analytes and ISs were separated on an Acquity UPLC BEH C18 (50 mm × 2.1 mm, 1.7 µm) column using a mobile phase consisting of 0.1% formic acid–acetonitrile (25:75, v/v). A tandem mass spectrometer equipped with electrospray ionization was used as a detector in the positive ionization mode for both analytes. The linear concentration range was established as 0.50–500 ng/mL for atenolol and 0.25–150 ng/mL for chlorthalidone. Extraction recoveries were within 95–103% and ion suppression/enhancement, expressed as IS‐normalized matrix factors, ranged from 0.95 to 1.06 for both the analytes. Intra‐batch and inter‐batch precision (CV) and accuracy values were 2.37–5.91 and 96.1–103.2%, respectively. Stability of analytes in plasma was evaluated under different conditions, such as bench‐top, freeze–thaw, dry and wet extract and long‐term. The developed method was superior to the existing methods for the simultaneous determination of atenolol and chlorthalidone in human plasma with respect to the sensitivity, chromatographic analysis time and plasma volume for processing. Further, it was successfully applied to support a bioequivalence study of 50 mg atenolol + 12.5 mg chlorthalidone in 28 healthy Indian subjects. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
13.
Nejal M. Bhatt Vijay D. Chavada Mallika Sanyal Pranav S. Shrivastav 《Biomedical chromatography : BMC》2019,33(10)
The present work describes novel methods using densitometry and indirect or off‐line high performance thin‐layer chromatography–mass spectrometry (HPTLC–MS) for the simultaneous detection and quantification of asenapine, propranolol and telmisartan and their phase II glucuronide metabolites. After chromatographic separation of the drugs and their metabolites the analytes were scraped, extracted in methanol and concentrated prior to mass spectrometric analysis. Different combinations of toluene and methanol–ethanol–n‐butanol–iso‐propanol were tested for analyte separation and the best results were obtained using toluene–methanol–ammonia (6.9:3.0:0.1, v/v/v) as the elution solvent. All of the drug–metabolite pairs were separated with a homologous retardation factor difference of ≥22. The conventional densitometric approach was also studied and the method performances were compared. Both of the approaches were validated following the International Conference on Harmonization guidelines, and applied to spiked human plasma samples. The major advantage of the TLC–MS approach is that it can provide much lower limits of detection (1.98–5.83 pg/band) and limit of quantitation (5.97–17.63 pg/band) with good precision (?3.0% coefficient of variation) compared with TLC–densitometry. The proposed indirect HPTLC–MS method is simple yet effective and has tremendous potential in the separation and quantitation of drugs and their metabolites from biological samples, especially for clinical studies. 相似文献
14.
Phonon anomalies in two intermediate valence compounds (IVC), SmS and Sm0·75Y0·25S have been investigated using breathing shell model (BSM). The BSM includes breathing motion of electron shells of the rare
earth atom due tof−d hybridization. The phonon dispersion curves of IVC, calculated from the present model, agree well with the measured data.
One-phonon density of states calculated from the present model compares well with the Raman spectra. 相似文献
15.
Sankar P. Sanyal 《Journal of Physics and Chemistry of Solids》1981,42(5):429-432
A detailed investigation of the phonon dispersion and static and anharmonic properties has been carried out for ND4I using an extended three-body force shell model (ETSM) developed by Singh and Chandra. The ETSM results for phonon dispersion show better agreement with the experimental data than those obtained from the deformation dipole and rigid shell models. Calculated values have also been obtained for some other properties. 相似文献
16.
Hydromagnetic turbulent shear flow of viscous, incompressible, electrically conducting fluid between two infinite uniformly porous moving parallel planes in the presence of axial and transverse magnetic field has been studied by the semi-empirical method. The expressions for the mean distributions for velocity and magnetic field for turbulent shear flow have been obtained for both the cases. As particular cases, the results have been obtained if the planes are fixed. The solutions obtained when the magnetic field is axial have been shown graphically for turbulent and laminar flows. 相似文献
17.
Anthracene anions bound to a liquid-liquid interface and charged by photochemically reduced Keggin ions when exposed to aqueous chloroaurate ions result in the formation of high concentration of thin, gold nanosheets at the interface. 相似文献
18.
Q. Md. Alfred T. Chakravarty G. Singh S. K. Sanyal 《International Journal of Infrared and Millimeter Waves》2007,28(10):881-887
In radar, planar phased array antenna plays vital role in electronic scanning in the azimuth and elevation direction to the
horizon. In most operations using planar phased array both the coordinates of azimuth and elevation, are steered electronically.
In this paper a conceptual schematic of a phased array antenna with programmable time delay units has been presented. It is
shown that by suitably exploiting the time delay matrix one can have electronic beam rotation around the target axis as required
in conical scan. Thus both the elevation and azimuth motors in conical scan system are replaced by electronic scanning. Heuristically,
we have selected eight consecutive points for beam rotation in a polygon shape and can also be extended almost circular shape
by increasing number of array elements and phase shifter (delays) in the delay matrix. The array requires dual control of
phase gradient and individual phase values. The whole array is controlled by micro-controller. This presents exciting possibilities
in radar operation. 相似文献
19.
20.
Mitali Banerjee A.K. Majumdar Biplab Sanyal 《Journal of magnetism and magnetic materials》2010,322(21):3558-3564
We report here an experimental study of magnetization of FeNiW alloys at different compositions. We have studied variation of magnetization with temperature (at low external fields) and magnetic field (at low temperatures). The alloy shows para to ferromagnetic transitions across the composition range. We do not find any indication of the spin-glass phase. We have supplemented the experimental work with theoretical analysis using the first-principles tight-binding linear muffin-tin orbitals based augmented space recursion method. Our theoretical estimates of magnetic moment and Curie temperatures agree well with experiment. Our mean-field phase analysis also does not indicate the possibility of a spin-glass phase. 相似文献