Cr content-dependent modification of structural,magnetic properties and bandgap in green synthesized Co–Cr nano-ferrites

Abstract

Honey green synthesis of CoCr_xFe_2?xO₄ (x?=?0.0???1.0) ferrites with increasing Cr content was done by sol-gel auto-combustion method, without any post-preparation thermal treatment. Nanocrystalline nature (grain diameter range between 12.2?nm and 27.9?nm) of the studied samples is confirmed by X-ray diffraction (XRD) data. Observed modification of magnetic properties can be understood in terms of Cr addition induced changes in degree of inversion, modification of disorder affecting A–A, A–B, B–B interaction, re-distribution of cations on A, B sites in the spinel lattice. Grain size (D)-dependent coercivity (H_c) shows that the studied samples lie in the region with overlap between single- and multi-domain regions. Achieved magnetic properties in the studied honey green synthesized samples have significance for self-regulating hyperthermia applications. Results as well reveal modification of bandgap, and would be of use for applications, where minor bandgap tuning is required. Antistructure modeling provides information on the types of surface-active centers.     

Quantitation of Oleanolic Acid in Oldenlandia corymbosa L. Whole-Plant Powder by High-Performance Thin-Layer Chromatography

JPC – Journal of Planar Chromatography – Modern TLC - A sensitive, simple, and accurate high-performance thin-layer chro-matographic method has been established for determination of...     

Synthesis and physical characterization of superconductivity-magnetism crossover compound RuSr2EuCeCu2O10−δ

We carefully studied the nonsuperconducting sample of the magneto-superconducting RuSr₂(Eu_1−xCe_x)Cu₂O_10−δ series with composition RuSr₂EuCeCu₂O_10−δ. This compound seems to exhibit a complex magnetic state as revealed by host of techniques like resistivity, thermopower, magnetic susceptibility, and MR measurements. The studied compound exhibited ferromagnetic like M(H) loops at 5, 20, and 50 K, and semiconductor like electrical conduction down to 5 K, with −MR^7 T of up to 4% at low temperatures. The −MR^7 T decreases fast above 150 K and monotonically becomes close to zero above say 230 K. Below, 150 K −MR^7 T decreases to around 3% monotonically down to 75 K, with further increase to 4% at around 30 K and lastly having a slight decrease below this temperature. The thermopower S(T) behavior closely followed the −MR^7 T steps in terms of d(S/T)/dT slopes. Further, both MR^7 T steps and d(S/T)/dT slopes are found in close vicinity to various magnetic ordering temperatures (T_mag) of this compound.     

Spin physics at RHIC: Present and future

In 2001–2002 the relativistic heavy-ion collider (RHIC) at the Brookhaven National Laboratory (BNL) was first commissioned for polarized proton collisions. Polarized protons were injected into the RHIC, accelerated to 100 GeV, stored and the two beams were made to collide in four interaction regions. I will review the progress made by the RHIC spin program, followed by the physics goals for the next few years. After that I will present a brief overview of a proposal to build a high intensity polarized electron/positron beam facility at BNL which would enable deep inelastic scattering (DIS) experiments to be pursued at BNL by its collisions with the RHIC hadron beams.     

Enhanced optoelectronic properties of UV-light-induced photodegraded TPD

We report UV-light-induced photodegradation of N,N’-diphenyl-N,N’-bis(3-methylphenyl)-1,1’-biphenyl-4,4’ diamine (TPD) dye. When a halomethane solution of TPD is exposed to UV light it first oxidizes TPD and subsequently with further exposure leads to irreversible transformation of TPD to an acridine derivative as photoproduct. Exclusive use of halomethane solvents like chloroform and dichloromethane suggests solvent radical initiated photochemical transformation of TPD to a stable acridine-based photoproduct. The resultant photoproduct of TPD showed broad-band dual (both blue and green) emissions in various solvents and also from the sublimed thin film. Based on solvent- and concentration-dependent photoluminescence (PL) of the photoproduct, PL excitation and lifetimes of blue and green bands, the origin of emission in the green region is due to an intermolecular excimer/aggregate of acridine-based photoproduct. A film of acridine-based photoproduct dispersed in polystyrene also showed substantial improvement in electrical conductivity compared to the parent compound TPD. The technique of UV-light-induced molecule structure transformation and material processing under specific environmental conditions may be considered as an efficient means of obtaining materials with enhanced optoelectronic properties. PACS 61.82.Pv; 72.80.Le; 82.50.-m; 82.30.Lp; 33.50.-j     

The $Z \rightarrow \gamma \gamma,\;gg$ decays in the non-commutative standard model

On non-commutative spacetime, the standard model (SM) allows new, usually SM forbidden, triple gauge boson interactions to occur. In this letter we propose the SM strictly forbidden and decay modes coming from the gauge sector of the non-commutative standard model (NCSM) as a place where non-commutativity could be experimentally discovered. Received: 2 July 2002, Revised: 28 February 2003, Published online: 18 June 2003     

Phase effects in the diffraction of light: beyond the grating equation

Diffraction gratings affect the absolute phase of light in a way that is not obvious from the usual derivation of optical paths using the grating equation. For example, consider light which encounters first one and then the second of two parallel gratings. If one grating is moved parallel to its surface, the phase of the light diffracted from the grating pair is shifted by 2pi each time the grating is moved by one grating constant, even though the geometric path length is not altered by the motion. This additional phase shift must be included when incorporating diffraction gratings in interferometers.     

Yield and enrichment studies of C-13 isotope by multi-photon dissociation of Freon-22 at low temperatures

Multi-photon dissociation of Freon-22 (CF₂HC1) at low temperatures has been carried out to separate the C-13 isotope using a TEA CO₂ laser. Yield and enrichment of C-13 isotope in the product C₂F₄ are studied at 9P(22) laser line as a function of temperature (−50°C to 30°C). It is observed that at a given fluence when the temperature is lowered the yield decreases and the enrichment factor of C-13 increases. Room temperature irradiation of CF₂HC1 towards the blue edge of C-13 absorption (i.e. at 9P(20) laser line) gives low yield of the product (C₂F₄) at a fluence, which produces the desired enrichment factor of 100. An increase in fluence gives very high yield of C₂F₄ but the enrichment factor is very low. Irradiating CF₂HC1 at a temperature of −10°C enhances the enrichment factor to 100 and the yield obtained is comparable to that towards the red edge of C-13 absorption (i.e. at 9P(26) laser line). At a given enrichment factor higher enrichment efficiency is achieved when CF₂HC1 is irradiated at lower temperature.