Synthesis and study of high-temperature heat capacity of erbium orthovanadate

Orthovanadate ErVO₄ has been prepared by solid-phase synthesis from a stoichiometric mixture of high pure V₂O₅ and chemically pure Er₂O₃ by multistage calcination in air in the temperature range 873–1273 K. The effect of temperature (380–1000 K) on the heat capacity of orthovanadate ErVO₄ was studied by hightemperature calorimetry. Thermodynamic properties of erbium orthovanadate (enthalpy change H°(T)–H°(380 K), entropy change S°(T)–S°(380 K), and reduced Gibbs energy Φ°(T)) have been calculated from the experimental C_p = f(T) data. It has been shown that the specific heat varies in a row of oxides and orthovanadates of Gd-Lu naturally depending on the radius of the R³⁺ ion within the third and fourth tetrads.     

The multidipole effect in reactions of polyfunctional peroxy radicals

Conclusions The rate constant of the reaction of peroxide radicals of acrylic and methacrylic esters of polyols with nonpolar cumene is not dependent on the number of ester groups, and with polar 2,4,6-tri-tert-butylphenol decreases with an increase in the number of ester groups in the peroxide radical. Both findings are in agreement with the model of a dipole-dipole interaction in reactions of polyfunctional compounds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 778–781, April, 1985.     

Modeling of Solute-Solvent Interactions Using an External Electric Field—From Tautomeric Equilibrium in Nonpolar Solvents to the Dissociation of Alkali Metal Halides

An implicit account of the solvent effect can be carried out using traditional static quantum chemistry calculations by applying an external electric field to the studied molecular system. This approach allows one to distinguish between the effects of the macroscopic reaction field of the solvent and specific solute–solvent interactions. In this study, we report on the dependence of the simulation results on the use of the polarizable continuum approximation and on the importance of the solvent effect in nonpolar solvents. The latter was demonstrated using experimental data on tautomeric equilibria between the pyridone and hydroxypyridine forms of 2,6-di-tert-butyl-4-hydroxy-pyridine in cyclohexane and chloroform.     

On the distribution of the number of customers in the symmetric M/G/1 queue

We consider an M/G/1 queue with symmetric service discipline. The class of symmetric service disciplines contains, in particular, the preemptive last-come-first-served discipline and the processor-sharing discipline. It has been conjectured in Kella et al. [1] that the marginal distribution of the queue length at any time is identical for all symmetric disciplines if the queue starts empty. In this paper we show that this conjecture is true if service requirements have an Erlang distribution. We also show by a counterexample, involving the hyperexponential distribution, that the conjecture is generally not true. AMS Subject Classifications Primary—60K25; Secondary—90B22     

Uniqueness and nonuniqueness of the solution to the problem of determining the source in the heat equation

An initial–boundary value problem for the two-dimensional heat equation with a source is considered. The source is the sum of two unknown functions of spatial variables multiplied by exponentially decaying functions of time. The inverse problem is stated of determining two unknown functions of spatial variables from additional information on the solution of the initial–boundary value problem, which is a function of time and one of the spatial variables. It is shown that, in the general case, this inverse problem has an infinite set of solutions. It is proved that the solution of the inverse problem is unique in the class of sufficiently smooth compactly supported functions such that the supports of the unknown functions do not intersect. This result is extended to the case of a source involving an arbitrary finite number of unknown functions of spatial variables multiplied by exponentially decaying functions of time.     

System of nonlinear integral equations for the unknown functions in a functional-differential hyperbolic equation

We consider the inverse problem for a functional-differential equation in which the delay function and a function occurring in the source are unknown. The values of the solution and its derivative at x = 0 are given as additional information. We derive a system of nonlinear integral equations for the unknown functions. This system is used to prove a uniqueness theorem for the inverse problem.     

New ideas regarding the geometry of space-time and gravitation

In the present survey on the basis of an analysis of the problem of the energy-momentum of the gravitational field in the general theory of relativity it is shown that this theory is unsatisfactory as a concrete realization of Einstein's idea of the connection of the geometry of space-time with matter. A new theory of gravitation is proposed which alters established ideas of space-time, makes it possible to describe all present gravitational experiments, and predicts a number of fundamental consequences.Translated from Itogi Nauki i Tekhniki, Seriya Sovremennye Problemy Matematiki, Vol. 21, pp. 3–215, 1982.