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11.
    
In this study, surface enhanced Raman spectroscopy (SERS) was used to investigate the spectral characteristics of blood serum for the purpose of diagnosing stomach diseases. SERS spectral data was collected from patients with atrophic gastritis, both pre‐operation and post‐operation gastric cancer, and from healthy individuals. Visual differences in the SERS spectra were observed between the four groups which indicate corresponding biomolecule concentration changes in blood. To further investigate the diagnostic ability of human serum, the spectral data was analyzed with three chemometric processes. These three methods extracted features and classified from the spectral data. Principal component analysis (PCA) was first performed to reduce the dimensionality of the original spectral data. Then, the classification methods support vector machine (SVM), linear discriminant analysis (LDA) and classification and regression tree (CART) were used for the evaluation of diagnostic ability. Accuracies of 96.5%, 88.8% and 87.1% were obtained for PCA‐SVM, PCA‐LDA and PCA‐CART, respectively. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
12.
    
The service performance of the machine tool bearing is closely related to the tribological behavior of the bearing’s each component. At present, the precision life of precision machine tool bearings is concerned. Micro-pitting is a typical damage on the raceway surface when the bearing precision life expires. Rare earth resources are very rich in our country and widely used in bearing steel. Its inclusion in steel has a role in purifying liquid steel, microalloying and metamorphic inclusions. In this paper, the rolling contact fatigue test between rare earth/common GCr15 bearing steel and Si3N4 ceramic ball was carried out by using the ball-type rolling contact fatigue testing machine under the condition of oil lubrication. After different cycles of tests, the distribution, size and depth of the micro-pitting corrosion on the surface of the wear marks of the test bearing steel rod were characterized and analyzed, and the effect of the addition of rare earth on the micro-pitting behavior of GCr15 bearing steel during rolling contact fatigue was discussed. At the same time, in addition to the contact fatigue test of the ball rod, the bench test of the bearing was also carried out, and the micro-pitting corrosion of the bearing ring surface was studied after the test. The results showed that the micro-pitting amount increased with the increase of rolling contact cycles, whether it was rare earth GCr15 bearing steel or common GCr15 bearing steel. The difference was that the micro pittings of rare earth GCr15 bearing steel were not only shallower but also smaller and round, while the micro-pittings of common GCr15 bearing steel were not only deeper but also easier to appear in pieces. Also, the bearing bench test was carried out. The same micro-pitting behavior difference was found between rare earth bearing and common bearing. The effect of rare earth addition on micro-pitting behavior was discussed from the aspect of microstructure and carbide of bearing steel. In the microstructure of ordinary GCr15 bearing steel, mesh carbides and liquid evolution carbides were easy to appear, and there were carbides with uneven distribution and large size. The addition of rare earth made the carbides in GCr15 bearing steel more uniformly distribute in the matrix, effectively reduced the precipitation of liquid precipitation carbides and the appearance of a large number of networks carbides, and thus reduced micro-pitting failure of GCr15 bearing steel in rolling contact fatigue. Finally, using the finite element analysis, the formation mechanism of micro-pitting was discussed. In the process of experiment, the micro convex body contact and the uneven distribution of carbide under the effect of the contact stress leaded to the maximum shear stress concentration. As a result, micro cracks nucleated under the micro convex body and carbide, as the test progressed, the micro cracks extended slowly. When the test was stopped, the micro convex body and carbide fell off and formed micro-pitting.  相似文献   
13.
Cucurbitaxanthin A (=(all‐E,3S,5R,6R,3′R)‐3,6‐epoxy‐5,6‐dihydro‐β,β‐carotene‐5,3′‐diol; 1 ) was submitted to thermal isomerization and to I2‐catalysed photoisomerization. The structure of the main reaction products (9Z)‐ ( 2 ), (9′Z)‐ ( 3 ), (13Z)‐ ( 4 ), and (13′Z)‐cucurbitaxanthin A ( 5 ) was determined by their UV/VIS, CD, 1H‐NMR, and mass spectra.  相似文献   
14.
L. Renson  G. Deliége  G. Kerschen 《Meccanica》2014,49(8):1901-1916
This paper addresses the numerical computation of nonlinear normal modes defined as two-dimensional invariant manifolds in phase space. A novel finite-element-based algorithm, combining the streamline upwind Petrov–Galerkin method with mesh moving and domain prediction–correction techniques, is proposed to solve the manifold-governing partial differential equations. It is first validated using conservative examples through the comparison with a reference solution given by numerical continuation. The algorithm is then demonstrated on nonconservative examples.  相似文献   
15.
Let be a sequence of real-valued i.i.d. random variables with E(X)=0 and E(X2)=1, and set , n?1. This paper studies the precise asymptotics in the law of the iterated logarithm. For example, using a result on convergence rates for probabilities of moderate deviations for obtained by Li et al. [Internat. J. Math. Math. Sci. 15 (1992) 481-497], we prove that, for every b∈(−1/2,1],
  相似文献   
16.
17.
设{X_n:n≥1}是在某可分Banach空间B上取值的独立随机变量序列,S_n=X_1+…+X_n,n≥1,对某00和>1,定义P_n(ε)=P(‖S_n‖/n~(1/p)≥ε)。本文的目的是研究当n→+∞时,P(ε)→0的速度,在Banach空间上推广了Heyde和Rohatgi的结果;同时,本文还讨论了P_n(ε)→0的速度与S_n/n~(1/p)→0 a.s.的关系问题。  相似文献   
18.
Latoxanthin was isolated as a minor carotenoid from the ripe fruits of yellow tomato shaped paprika (Capsicum annuum var. lycopersiciforme flavum) and identified as (all-E,3S,5R,6R,3′S,5′R,6′S)-5′,6′-epoxy-5,6,5′,6′-tetrahydro-β,β-carotene-3,5,6,3′-tetrol based on spectral data.  相似文献   
19.
In this work, we have successfully synthesised ZnO crystal thin film with a high quality from hydrothermal reaction on sapphire substrate. The growth mechanism is clarified based on an extensive XTEM study. In addition, electrical and optical properties of the crystal thin film, which can be controlled by impurities, are characterized. The synthesis technique provides fairly high quality and cost-effective substrates for optoelectronic and renewable energy applications.  相似文献   
20.
    
Polycyclic aromatic hydrocarbon (PAH) compounds are prospective materials for highly efficient narrowband organic light-emitting diodes. Specifically, boron-nitrogen doped PAHs exhibit multiple resonance (MR) effect toward thermally activated delayed fluorescence (TADF) and narrow full width at half-maximum (FWHM). Currently, the molecular design strategy for bathochromic-shifted narrowband MR-TADF emitters is a hotspot and challenging puzzle. Herein, a carbonyl is fused in the boron-nitrogen doped PAH for constructing a boron/nitrogen/carbonyl MR-TADF emitter. Benefiting from the carbonyl, the developed emitter exhibits enhanced intramolecular charge transfer and decreased reorganization energy, which displays bathochromic-shifted narrowband emission pertinently. As a consequence, the proof-of-concept compound TCZBAO achieves an emission peak at 522 nm and narrow FWHM of 39 nm, while the carbonyl-free TCZBAC exhibits an emission peak at 502 nm and FWHM of 46 nm. Maximum external quantum efficiencies of 36.1 % and 32.4 % are realized for the devices based on TCZBAO and TCZBAC, respectively, indicating the guiding significance of the proposed design strategy for developing bathochromic-shifted narrowband MR-TADF emitters.  相似文献   
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