Chiral selective tunneling induced graphene nanoribbon switch

An armchair graphene nanoribbon switch has been designed based on the principle of the Klein paradox. The resulting switch displays an excellent on-off ratio performance. An anomalous tunneling phenomenon, in which electrons do not pass through the graphene nanoribbon junction even when the conventional resonance condition is satisfied, is observed in our numerical simulations. A selective tunneling rule is proposed to explain this interesting transport behavior based on our analytical results. Based on this selective rule, our switch design can also achieve the confinement of an electron to form a quantum qubit.      

Monoterpenoid Indole Alkaloids with Promoting Neurite Growth from Tabernaemontana divaricata

Main observation and conclusion Phytochemical investigations on Tabernaemontana divaricata led to the isolation of seven undescribed monoterpenoid indole alka-l...     

微腔内气体抽离的多尺度模拟与分析

基于适用于整个克努森数范围的流动理论,建立了去除惯性约束聚变实验中靶丸内空气的理论模型,并设计实验验证了此模型的可靠性。物理实验要求靶丸内空气浓度低于10×10⁻⁶,数值模拟了去除靶丸内空气的过程,重点分析了靶丸内空气浓度、压力与除气时间的关系。计算并比较了单管路一次抽气法、单管路循环抽气法与双管路流洗法三种去除靶丸内空气方法的时间成本。数值计算结果表明：单管路一次抽气法中,靶丸上的微通道的存在对去除靶丸内空气所需时间的影响不可忽略,在考虑靶丸上微通道与充气管的情况下,需要1961.77 h才能使靶丸内的空气浓度达到标准。单管路循环抽气法中,抽气次数与单次抽气程度会影响去除靶丸内空气所需总时间,在单次抽气程度值取最优的情况下,采用充三次,抽四次的方案可使达标总时间减少至1 h左右,此方案下单次充气和抽气时间分别为6 min和10 min。而采用双管路流洗法则仅需11 min便可使靶丸内空气浓度达标。     

NⅡ离子2p4f—2p3d辐射跃迁概率的理论研究

在全相对论理论框架下，利用多组态Dirac-Fock(MCDF)方法，系统计算了NⅡ离子2p4f—2p3d的辐射跃迁概率，得到的结果与已有实验值符合很好.具体计算中，详细分析了相对论效应、电子关联、弛豫效应、Breit相互作用和量子电动力学(QED)效应对能级精细结构及辐射跃迁概率的影响.结果表明：相对论效应、电子关联和弛豫效应对NⅡ 2p4f-2p3d辐射跃迁概率有很重要的影响,考虑了这些效应后计算值得到明显改善.     

PH, PD和PT分子常数理论研究

采用内收缩多参考组态相互作用(MRCI)方法和包含Davidson修正(+Q) 的MRCI方法结合相关一致基aug-cc-pV5Z研究了PH (X³Σ^-, a¹Δ和A³∏)分子的势能曲线. 在同位素质量识别的基础上对势能曲线进行拟合, 得到PH, PD和PT分子各个电子态的光谱常数(T_e, R_e, ω_e, ω_ex_e, α_e和 B_e). 通过与已有实验数据的比较发现, 本文的结果与实验结果非常一致. 对于PH, PD和PT分子的Σ^-电子态, 计算得到了J = 0时的前12个振动态. 对于每一个振动态, 还分别计算了它的振动能级、惯性转动常数和离心畸变常数. 与其他理论结果和实验数据进行比较可知, 本文的结果更精确、更完整. 文中PD和PT分子的光谱常数和分子常数均属首次报导.     

激光调频连续波测距的精度评定方法研究

基于双光纤光路等光频重采样原理,提出了一种距离精度的评定方法.通过推导噪声背景下等光频重采样信号中距离参量的克拉美-罗下边界,得到了影响系统测距精度的两个重要因素:信噪比和扫描带宽,并进行了实验验证.实验表明,该评价方法并不会受到任何距离估算方法的影响,根据此方法可以选择一个最优的距离估算方法.通过对两个影响精度的因素进行仿真分析可知,在扫描带宽为2.2 nm时,若将测量光路的信噪比提升至70 dB以上,系统可获得低于10μm的测距精度.该精度评定方法可为后续改善调频连续波测距系统性能提供理论参考.     

Surface anchoring energy and the first order Fréedericksz transition of a NLC cell

Many authors have suggested new forms to describe the surface anchoring energy of the liquid crystal-wall interface, replacing the Rapini-Papoular (RP) formula g s = (1/2) A sin2 theta. If the RP function is considered as the primary approximation, and a lowest order modification is included, then the surface anchoring energy can be represented by g s = (1/2) A sin2 theta(1 + zeta sin2 theta). zeta characterizes the modification to the RP formula and varies for the different energy forms. It is well known that the RP formula predicts a second order Freedericksz transition. This paper points out that the transition can be first order if the modification is taken into account, in which case at the threshold point the tilt angle of the director at the middle layer of the cell, thetam, is finite. The conditions for the existence of the first order transition are obtained; zeta < 0 is required for a first order transition. The approximate expression of the threshold field is also given.     

SYNTHESIS OF CeO2 NANOPARTICLES IN W/ O MICROEMULSION

The phase composition and properties of microemulsion system of Titron N-101 / n-pentanol/ n-octane/ water (ammonia solution) were studied. CeO₂ nanopaticles were prepared by the reaction of cerous nitrate.     

两种测定果汁中钾磷含量方法的比较与分析

采用微波消解-等离子体发射光谱法同时测定果汁中K、P含量,优化了实验所需的各种条件。与国家标准方法湿法消解-分光光度法的测定结果作了实验比较,结果表明本实验方法更简单、高效,节省了样品的前处理时间,减小了最终结果的误差。该法灵敏度高、线性范围宽、加标回收率高,结果令人满意。     

Open‐cage fullerenes as tailor‐made container for a single water molecule

Water is the most important liquid on earth. Clusters of water have been investigated extensively in an effort to understand the bulk property of water. But the behavior of single water molecule without H‐bond has been rarely studied. Open‐cage [60]fullerenes have been shown to trap a single water molecule selectively over molecules with comparable size and act as the smallest “water bottle”. Copyright © 2013 John Wiley & Sons, Ltd.