Step-induced canting of magnetization in Fe/Ag superlattices

We have investigated the reorientation of the easy axis of magnetization in (0 0 1) Fe/Ag superlattices using vibrating sample magnetometry, Mössbauer spectroscopy and nuclear resonance scattering of synchrotron radiation. Clear evidence is found that the Fe-layer magnetization can be oriented considerably out of the plane of the sample at room temperature, even for Fe-layer thicker than 6 ML at which the spin-reorientation transition usually occurs in Fe/Ag. The spin canting is attributed to frustration and a strong contribution of a step-induced anisotropy.     

Flame spreading over liquid ethanol

Flame spreading over liquid ethanol has been experimentally characterized for ethanol for subflash temperatures, in two different channels. Three different spreading regimes have been observed. A uniform region (with flame velocities close to 10 cm/s) appears for values of the initial surface liquid temperature above a critical value . For values an oscillatory regime occurs. For very low temperatures, , a new uniform regime appears with slow propagation velocities (close to 1 cm/s). The critical point has been described as a Hopf bifurcation, while resembles a homoclinic connection. Received 16 October 1998 and Received in final form 23 June 1999     

The Kalimantacin Polyketide Antibiotics Inhibit Fatty Acid Biosynthesis in Staphylococcus aureus by Targeting the Enoyl‐Acyl Carrier Protein Binding Site of FabI

The enoyl‐acyl carrier protein reductase enzyme FabI is essential for fatty acid biosynthesis in Staphylococcus aureus and represents a promising target for the development of novel, urgently needed anti‐staphylococcal agents. Here, we elucidate the mode of action of the kalimantacin antibiotics, a novel class of FabI inhibitors with clinically‐relevant activity against multidrug‐resistant S. aureus. By combining X‐ray crystallography with molecular dynamics simulations, in vitro kinetic studies and chemical derivatization experiments, we characterize the interaction between the antibiotics and their target, and we demonstrate that the kalimantacins bind in a unique conformation that differs significantly from the binding mode of other known FabI inhibitors. We also investigate mechanisms of acquired resistance in S. aureus and identify key residues in FabI that stabilize the binding of the antibiotics. Our findings provide intriguing insights into the mode of action of a novel class of FabI inhibitors that will inspire future anti‐staphylococcal drug development.     

Coarsening of antiferromagnetic domains in multilayers: the key role of magnetocrystalline anisotropy

The domain structure of an antiferromagnetic superlattice is studied. Synchrotron M?ssbauer and polarized neutron reflectometric maps show micrometer-size primary domain formation as the external field decreases from saturation to remanence. A secondary domain state consisting mainly of at least 1 order of magnitude larger domains is created when a small field along the layer magnetizations induces a bulk-spin-flop transition. The domain-size distribution is reproducibly dependent on the magnetic prehistory. The condition for domain coarsening is shown to be the equilibrium of the external field energy with the anisotropy energy.     

Mössbauer spectroscopy investigation of body centered cubic Co in Co/Fe superlattices prepared with MBE

A new spectrum component is observed in Mössbauer spectra of thin body centered cubic Co layers prepared in Fe/Co superlattices doped with⁵⁷Co. It is characterized by a large magnetic hyperfine field (31.2 T) and an isomer shift nearly equal to that of -Fe. The decrease of the isomer shift in bcc Co with respect to hcp Co is consistent with smaller s to d charge transfer in bcc Co as compared to hcp Co. The cubic structure of the CoFe superlattices is evidenced with X-ray diffraction and ion-channeling measurements. The Fe/Co interface is investigated with conversion electron Mössbauer spectroscopy. It is shown that the interface alloy thickness is about six monolayers for growth temperatures up to 450 K and that increasing alloying occurs for higher growth temperatures.     

Flame propagation over liquid alcohols

The different spreading regimes above liquid fuels have been experimentally characterized for surface temperatures close to the flash-point temperature. Two different spreading regimes are observed: for temperatures larger than some critical value, flame spreading velocity is well described by the De Ris solid fuel-like model. For temperature values lower than the critical one, a preheating thermocapillary region has been observed in the fuel, which can be described by a purely thermodynamic non-reactive model. The critical transition temperature has shown to present common characteristics for the four alcohols used in the experiments.     

POD-identification reduced order model of linear transport equations for control purposes

Intrusive reduced order modeling techniques require access to the solver's discretization and solution algorithm, which are not available for most computational fluid dynamics codes. Therefore, a nonintrusive reduction method that identifies the system matrix of linear fluid dynamical problems with a least-squares technique is presented. The methodology is applied to the linear scalar transport convection-diffusion equation for a 2D square cavity problem with a heated lid. The (time-dependent) boundary conditions are enforced in the obtained reduced order model (ROM) with a penalty method. The results are compared and the accuracy of the ROMs is assessed against the full order solutions and it is shown that the ROM can be used for sensitivity analysis by controlling the nonhomogeneous Dirichlet boundary conditions.     

Bubble simulations with an interface tracking technique based on a partitioned fluid-structure interaction algorithm

Numerical techniques frequently used for the simulation of one bubble can be classified as interface tracking techniques and interface capturing techniques. Most of these techniques calculate both the flow around the bubble and the shape of the interface between the gas and the liquid with one code. In this paper, a rising axisymmetric bubble is simulated with an interface tracking technique that uses separate codes to determine the position of the gas-liquid interface and to calculate the flow around the bubble. The grid converged results correspond well with the experimental data.The gas-liquid interface is conceived as a zero-mass, zero-thickness structure whose position is determined by the liquid forces, a uniform gas pressure and surface tension. Iterations between the two codes are necessary to obtain the coupled solution of both problems and these iterations are stabilized with a fluid-structure interaction (FSI) algorithm. The flow around the bubble is calculated on a moving mesh in a reference frame that rises at the same speed as the bubble. The flow solver first updates the mesh throughout the liquid domain given a position of the gas-liquid interface and then calculates the flow around the bubble. It is considered as a black box with the position of the gas-liquid interface as input and the liquid forces on the interface as output. During the iterations, a reduced-order model of the flow solver is generated from the inputs and outputs of the solver. The solver that calculates the interface position uses this model to adapt the liquid forces on the gas-liquid interface during the calculation of the interface position.